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CHLOROMETHYL METHYL SULFIDE

CAS No.
2373-51-5
Chemical Name:
CHLOROMETHYL METHYL SULFIDE
Synonyms
(chloroMethyl)(Methyl)sulfane;CH3SCH2Cl;Chloro(methylsulfanyl)methane;Methylthiomethyl chloride;MTMchloride;Clorodimetilsolfuro;CHLORODIMETHYL SULFIDE;chlorodimethylthioether;methylthiomethylchloride;Chlorodimethyl thioether
CBNumber:
CB9295856
Molecular Formula:
C2H5ClS
Molecular Weight:
96.58
MDL Number:
MFCD00000923
MOL File:
2373-51-5.mol
MSDS File:
SDS
Last updated:2024-04-24 17:21:45

CHLOROMETHYL METHYL SULFIDE Properties

Boiling point 105 °C (lit.)
Density 1.153 g/mL at 25 °C (lit.)
refractive index n20/D 1.498(lit.)
Flash point 63 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
Water Solubility Soluble in acetonitrile, ether and dichloromethane. Insoluble in water.
Sensitive Moisture Sensitive
BRN 1730851
CAS DataBase Reference 2373-51-5(CAS DataBase Reference)
EWG's Food Scores 1

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Danger
Hazard statements  H225
Precautionary statements  P210-P233-P240-P241-P242-P243
Hazard Codes  F,Xi
Risk Statements  11-37
Safety Statements  9-16-33
RIDADR  UN 1993 3/PG 2
WGK Germany  3
RTECS  WQ3700000
13
HazardClass  3
PackingGroup  II
HS Code  2930909899
NFPA 704
3
2 0

CHLOROMETHYL METHYL SULFIDE price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich C54007 Chloromethyl methyl sulfide 95% 2373-51-5 5g $80 2024-03-01 Buy
Sigma-Aldrich C54007 Chloromethyl methyl sulfide 95% 2373-51-5 25g $191 2024-03-01 Buy
TCI Chemical C0608 Chloromethyl Methyl Sulfide >97.0%(GC) 2373-51-5 25g $127 2024-03-01 Buy
TCI Chemical C0608 Chloromethyl Methyl Sulfide >97.0%(GC) 2373-51-5 100g $353 2024-03-01 Buy
Alfa Aesar L10858 Chloromethyl methyl sulfide, 95% 2373-51-5 10g $55.65 2024-03-01 Buy
Product number Packaging Price Buy
C54007 5g $80 Buy
C54007 25g $191 Buy
C0608 25g $127 Buy
C0608 100g $353 Buy
L10858 10g $55.65 Buy

CHLOROMETHYL METHYL SULFIDE Chemical Properties,Uses,Production

Chemical Properties

CLEAR YELLOW TO BROWN LIQUID

Uses

Methylthiomethylating reagent for carbonyl and aromatic compounds. Methylene transfer reagent for iron(II) mediated cyclopropanation.

Uses

Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.

Synthesis Reference(s)

Tetrahedron Letters, 35, p. 6127, 1994 DOI: 10.1016/0040-4039(94)88094-8

67-68-5
2373-51-5
541-05-9
556-67-2
541-02-6
Synthesis of CHLOROMETHYL METHYL SULFIDE from Dimethyl sulfoxide
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View Lastest Price from CHLOROMETHYL METHYL SULFIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Chloromethyl Methyl Sulfide pictures 2024-04-24 Chloromethyl Methyl Sulfide
2373-51-5
US $10.00 / kg 1kg 99.6% 100000 Ouhuang Engineering Materials (Hubei) Co., Ltd
Chloromethyl Methyl Sulfide pictures 2023-07-27 Chloromethyl Methyl Sulfide
2373-51-5
US $5.00-2.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
Chloromethyl Methyl Sulfide pictures 2019-07-11 Chloromethyl Methyl Sulfide
2373-51-5
US $3.00 / KG 1KG 99 100kg Career Henan Chemical Co
alpha-Chlorodimethyl sulfide alpha-chlorodimethylsulfide chloro(methylthio)-methan chloro(methylthio)methane Chlorodimethyl thioether chlorodimethylthioether Chloromethyl methyl thioether chloromethylmethylthioether Clorodimetilsolfuro Methane, chloro(methylthio)- methylthiomethylchloride Monochlorodimethyl sulfide monochlorodimethylsulfide Sulfide, chloromethyl methyl sulfide,chloromethylmethyl CHLORODIMETHYL SULFIDE CHLOROMETHYL METHYL SULFIDE CHLOROMETHYL METHYL SULPHIDE Chlorodimethyl sulphide~Methyl chloromethyl sulphide~Methylthiomethyl chloride~MTM chloride CHLOROMETHYL METHYL SULFIDE, ~80-85% Methylchloromethylsulfide MTMchloride (Methylthio)chloromethane Chloromethyl methyl sulfide,95% Chloro(methylsulphanyl)methane ChloroMethyl Methyl sulfide 95% Chloro(methylsulphanyl)methane, Chloro(methylthio)methane Chloromethyl Methyl Sulfide > CH3SCH2Cl Chloro(methylsulfanyl)methane (chloroMethyl)(Methyl)sulfane Methylthiomethyl chloride 2373-51-5 2375-51-5 Synthetic Reagents Others Protection and Derivatization Protecting and Derivatizing Reagents