クロロメチルメチルエーテル

クロロメチルメチルエーテル 化学構造式
107-30-2
CAS番号.
107-30-2
化学名:
クロロメチルメチルエーテル
别名:
クロロメチルメチルエーテル;クロロメチルラジカル;クロロジメチルエ-テル;クロロジメチルエーテル;クロロメチルメチルエテル;クロロメチルメチルエーテル(CMME)
英語名:
Chloromethyl methyl ether
英語别名:
CH3OCH2Cl;chloromethyl;METHOXYMETHYL CHLORIDE;chloromethoxymethane;CMME;METHYL CHLOROMETHYL ETHER;MOM chloride;Chloromethyl methyl;Methoxychloromethane;chlormethyl methyl ether chlorodimethyl ether
CBNumber:
CB2303754
化学式:
C2H5ClO
分子量:
80.51
MOL File:
107-30-2.mol

クロロメチルメチルエーテル 物理性質

融点 :
-103°C
沸点 :
55-57 °C(lit.)
比重(密度) :
1.06 g/mL at 25 °C(lit.)
蒸気圧:
3.55 psi ( 20 °C)
屈折率 :
n20/D 1.396(lit.)
闪点 :
60 °F
貯蔵温度 :
0-6°C
水溶解度 :
分解する
Merck :
13,2165
CAS データベース:
107-30-2(CAS DataBase Reference)
NISTの化学物質情報:
Methane, chloromethoxy-(107-30-2)

安全性情報

主な危険性  F,T
Rフレーズ  45-11-20/21/22
Sフレーズ  53-45
RIDADR  UN 1239 6.1/PG 1
WGK Germany  3
RTECS 番号 KN6650000
国連危険物分類  6.1
容器等級  I

クロロメチルメチルエーテル 化学特性,用途語,生産方法

化学的特性

Clear Colourless Oil

使用

A chloroalkyl ether that is an efficient alkylating agent. Used as an alcohol protecting group in the preparation of various organic compounds. A known human carcinogen.

一般的な説明

A clear colorless liquid. Flash point -4°F. Irritates the eyes and respiratory system. Very toxic by inhalation and may be toxic by ingestion or skin absorption. Vapors are heavier than air.

空気と水の反応

Highly flammable. Denser than water and is decomposed by water to yield hydrochloric acid, a corrosive material. With water the ether reacts to evolve formaldehyde and hydrogen chloride. The reaction is slow at ambient conditions.

反応プロフィール

Chloromethyl methyl ether Is a halogenated ether. Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Ethers can act as bases. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

健康ハザード

The principal effect is irritation. The liquid causes severe irritation of eyes and skin; and vapor exposure of 100 ppm is severely irritating to eyes and nose. This level is dangerous to life in 4 hours. Pulmonary edema or pneumonia may cause death. There was increased death rate from respiratory cancer among exposed victims and it is a regulated carcinogen.

火災危険

Flammable/combustible material; may be ignited by heat, sparks, or flames. Vapors may travel to a source of ignition and flash back. Container may explode in heat of fire. In addition to the risk of explosion, when air mixtures of ether vapors are heated or exposed to flame or sparks, they tend to form peroxides. Ethers containing peroxides can detonate when heated. Unburned material may form powerful tear gas. When wet, also forms irritating formaldehyde gas. Evolves formaldehyde and hydrogen chloride. When heated to decomposition, Chloromethyl methyl ether emits toxic fumes of chlorides. Avoid decomposing heat Hazardous polymerization may not occur.

クロロメチルメチルエーテル 上流と下流の製品情報

原材料

準備製品



107-30-2(クロロメチルメチルエーテル)キーワード:


  • Chlordimethylether
  • Chlormethyl methyl ether
  • chlorodimethylether(czech)
  • chloromethoxy-methan
  • Chloromethylradical
  • dimethylchloroether
  • Ether methylique monochlore
  • Ether, chloromethyl methyl
  • Ether, dimethyl chloro
  • ether,chloromethylmethyl
  • ether,dimethylchloro
  • ethermethyliquemonochlore
  • ethermethyliquemonochlore(french)
  • Methane,chloromethoxy-
  • Methyl chloromethyl ether, anhydrous
  • methylchloromethyl
  • methylchloromethylether,anhydrous(dot)
  • Monochlorodimethyl ether
  • monochlorodimethylether
  • Monochloromethyl methyl ether
  • Monochloromethylether
  • monochloromethylmethylether
  • Rcra waste number U046
  • rcrawastenumberu046
  • Chlorometoxymethane (as chlorine)
  • Methoxymethyl chloride, Methyl chloromethyl ether, MOM chloride
  • MonochlorodiMethylene Ether
  • Chlorodimethyl Ether Methoxymethyl Chloride
  • A chlorine
  • CHLOROMETHYIMETHYI
  • クロロメチルメチルエーテル
  • クロロメチルラジカル
  • クロロジメチルエ-テル
  • クロロジメチルエーテル
  • クロロメチルメチルエテル
  • クロロメチルメチルエーテル(CMME)
  • ハロゲン化反応
  • 保護 & 誘導体化試薬 (合成用)
  • 塩素化
  • 有機合成化学
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