엠-아니시딘
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엠-아니시딘 속성
- 녹는점
- −1-1 °C(lit.)
- 끓는 점
- 251 °C(lit.)
- 밀도
- 1.096 g/mL at 25 °C(lit.)
- 굴절률
- n
20/D 1.581(lit.)
- 인화점
- >230 °F
- 저장 조건
- 2-8°C
- 용해도
- 18g/L
- 산도 계수 (pKa)
- 4.23(at 25℃)
- 물리적 상태
- 액체
- 색상
- 투명한 노란색에서 갈색까지
- 수용성
- 19ºC에서 <0.1g/100mL
- 감도
- Light Sensitive
- Merck
- 14,667
- BRN
- 386119
- InChIKey
- NCBZRJODKRCREW-UHFFFAOYSA-N
- LogP
- 0.930
- CAS 데이터베이스
- 536-90-3(CAS DataBase Reference)
안전
- 위험 및 안전 성명
- 위험 및 사전주의 사항 (GHS)
| 위험품 표기 | Xn,N,T+ | ||
|---|---|---|---|
| 위험 카페고리 넘버 | 22-36/37/38-50/53-51/53-33-26/27/28 | ||
| 안전지침서 | 26-60-61-45-36/37-28B | ||
| 유엔번호(UN No.) | UN 2431 6.1/PG 3 | ||
| WGK 독일 | 1 | ||
| RTECS 번호 | BZ5408000 | ||
| F 고인화성물질 | 8 | ||
| TSCA | Yes | ||
| 위험 등급 | 6.1 | ||
| 포장분류 | III | ||
| HS 번호 | 29222200 | ||
| 유해 물질 데이터 | 536-90-3(Hazardous Substances Data) | ||
| 독성 | cyt-ham:ovr 160 mg/L EMMUEG 10(Suppl 10),1,87 |
엠-아니시딘 C화학적 특성, 용도, 생산
화학적 성질
Light yellow oily liquid with have characteristic amine (fishy) odors. soluble in alcohol, ether, benzene and dilute acid, slightly soluble in water. Anisidine exists as ortho-, meta-, and paraisomers.용도
m-Anisidine is a highly poisonous monosubstituted aniline used as corrosion inhibitorsfor aluminum, copper and other metals in acidic solutions.주요 응용
m-Anisidine is used in:The synthesis of N-substituted-3-chloro-2-azetidinones, which are potential anthelmintic agents.
Rhodium-catalyzed synthesis of indoles and copper-catalyzed synthesis of benzimidazoles.
In the preparation of azocalix[4]arene dyes.
일반 설명
M-anisidine appears as pale yellow oily liquid or dark red liquid. (NTP, 1992)공기와 물의 반응
m-Anisidine may be sensitive to prolonged exposure to air and light. Insoluble in water.반응 프로필
m-Anisidine is incompatible with strong oxidizers. m-Anisidine is also incompatible with acids, acid chlorides, acid anhydrides and chloroformates.화재위험
m-Anisidine is probably combustible.Safety Profile
Moderately toxic by ingestion.Mutation data reported. When heated to decomposition itemits toxic vapors of NOx.잠재적 노출
Anisidines are used in the manufacture of azo dyes; pharmaceuticals; textile-processing chemicals Incompatibilities: Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine,bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Attacks some coatings and some forms of plastic and rubber.운송 방법
UN2431 Anisidines, Hazard Class: 6.1; Labels: 6.1-Poisonous materialsPurification Methods
o-Isomer impurity can be removed by steam distillation. Another possible impurity is the precursor 3-nitroanisole which can be removed as for the preceding o-isomer and fractionating using an efficient column. It is a yellow liquid. [Gilman & Kyle J Am Chem Soc 74 3027 1952, Bryson J Am Chem Soc 82 4858 1960, Kadaba & Massie J Org Chem 22 333 1957, Beilstein 13 IV 953.]폐기물 처리
Dissolve in combustible solvent (alcohols, benzene, etc.) and spray solution into furnace equipped with afterburner and scrubber, or burn spill residue on sand and soda ash absorbent in a furnace.엠-아니시딘 준비 용품 및 원자재
원자재
준비 용품
3-METHOXYPHENYL ISOCYANATE
N,N-BIS(2-HYDROXYETHYL)-3-METHOXYANILINE
1-(4-Methoxyphenyl)piperazine
3-METHOXY-N-METHYLANILINE
5-METHOXY-2-NITROPHENYLBORONIC ACID
3-METHOXYBENZENESULFONYL CHLORIDE
4-[Di(2-chloroethyl)amino]-2-methoxybenzaldehyde
1-(3-Methoxyphenyl)piperazine
3-Methoxyphenylhydrazine hydrochloride
7-Quinolinol, 1-ethyl-1,2-dihydro-2,2,4-trimethyl-
2-AMINO-4-METHOXY-BENZOIC ACID
7-hydroxyquinoline-3-carboxylic acid
Coumarin 334
3-(Diphenylamino)phenol
7-methoxy-4-methylquinoline
Coumarin 343
C.I. Disperse Black 27
엠-아니시딘 공급 업체
글로벌( 352)공급 업체
| 공급자 | 전화 | 이메일 | 국가 | 제품 수 | 이점 |
|---|---|---|---|---|---|
| Coresyn Pharmatech Co., Ltd. | +86-571-86626709 +86-18157142896 |
cbc@coresyn.com | China | 9991 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 |
sales@hbmojin.com | China | 12456 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 |
sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 |
info@tianfuchem.com | China | 21691 | 55 |
| career henan chemical co | +86-0371-86658258 |
sales@coreychem.com | China | 29914 | 58 |
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 |
sales@finerchem.com | China | 2967 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 |
alice@crovellbio.com | China | 8823 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 |
linda@hubeijusheng.com | CHINA | 22968 | 58 |
| Standardpharm Co. Ltd. | 86-714-3992388 |
overseasales1@yongstandards.com | United States | 14336 | 58 |
| Shanghai Longyu Biotechnology Co., Ltd. | +8615821988213 |
info@longyupharma.com | China | 2531 | 58 |