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Aluminum nitrate

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CAS:13473-90-0

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Aluminum nitrate Basic information
Physical properties Uses Preparation Reactions
Product Name:Aluminum nitrate
Synonyms:Aluminum(III) nitrate (1:3);Trisnitric acid aluminum salt;Nitric acid, alumium salt;Nsc143017;ALUMINIUMTRINITRATE;Aluminiumnitrat8;aluminum trinitrate;nitrato de aluminio
CAS:13473-90-0
MF:AlN3O9
MW:213
EINECS:236-751-8
Product Categories:Industrial/Fine Chemicals;Inorganics
Mol File:13473-90-0.mol
Aluminum nitrate Structure
Aluminum nitrate Chemical Properties
Melting point 73°C
Boiling point 135℃[at 101 325 Pa]
density 1.4 g/cm3(Temp: 27 °C)
vapor pressure 0.01Pa at 25℃
solubility very soluble in ethanol; slightly soluble in acetone
form solid
color white hygroscopic solid
Water Solubility 42.99g/L at 25℃
InChIInChI=1S/Al.3NO3/c;3*2-1(3)4/q+3;3*-1
InChIKeyJLDSOYXADOWAKB-UHFFFAOYSA-N
SMILES[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[N+]([O-])([O-])=O.[Al+3]
LogP1.26 at 20℃
CAS DataBase Reference13473-90-0(CAS DataBase Reference)
EPA Substance Registry SystemAluminum nitrate (13473-90-0)
Safety Information
Hazard Codes O;Xi,Xi,O
Risk Statements 8-36/37/38
Safety Statements 17-26
RIDADR UN 1438
HazardClass 5.1
PackingGroup III
Hazardous Substances Data13473-90-0(Hazardous Substances Data)
MSDS Information
ProviderLanguage
Aluminum nitrate English
ALFA English
Aluminum nitrate Usage And Synthesis
Physical propertiesAluminum nitrate appears as a white or colorless crystalline solid (nonahydrate – rhombic crystal); deliquescent; refractive index 1.54; melts at 73.5°C; decomposes at 150°C; highly soluble in cold water (63.7% at 25°C), decomposes in hot water, soluble in polar organic solvents. It has an oxidizing effect on other substances. Though noncombustible, aluminum nitrate can be used to speed the burn of other combustible materials.
Aluminum nitrate
Aluminum nitrate is a salt composed of aluminum and nitric acid, belonging to a group of reactive chemicals - organic nitrate and nitrite compounds. The nitrate ion is polyatomic, meaning it is composed of two or more ions that are covalently bonded. This ion makes up the conjugate base of nitric acid.
UsesThe nonahydrate and other hydrated aluminum nitrates have many applications. These salts are used to produce alumina for preparation of insulating papers, in cathode tube heating elements, and on transformer core laminates. The hydrated salts are also used for extraction of actinide elements.
PreparationThe nonahydrate is prepared by treating aluminum, aluminum hydroxide, aluminum oxide, or aluminous mineral with nitric acid. The nitrate is crystallized from the solution.
ReactionsSince Al(NO3)3 or its salt hydrates dissociates to Al3+ and NO3 – ions in the aqueous solution, its reactions in solutions are those of Al3+ . It is partially hydrolyzed, producing H3O+ and thus accounting for the acidity of its solution in water. The products constitute a complex mixture of monoand polynuclear hydroxo species.
Aluminum nitrate is soluble in bases, forming aluminates, [Al(OH)4(H2O)2]–. It decomposes to Al2O3 when heated at elevated temperatures.
DescriptionAluminum nitrate, is a white, crystalline material that is soluble in cold water. It is a powerful oxidizing agent that decomposes at approximately 300°F. Aluminum nitrate should not be stored near combustible materials. The four-digit UN identification number is 1438. The primary uses are in textiles, leather tanning, as an anticorrosion agent, and as an antiperspirant.
Chemical PropertiesAluminum nitrate is an odorless, white crystalline solid, often in liquid solution,Soluble in cold water, alcohol and acetone; decomposes in hot water.
UsesTextiles (mordant), leather tanning, manufacture of incandescent filaments, catalyst in petroleum refining, nucleonics, anticorrosion agent, antiperspirant.
General DescriptionA white, crystalline solid. Noncombustible but can accelerate the burning of combustible materials. If large quantities are involved or the combustible material is finely divided, an explosion may result. Prolonged exposure to fire or heat may result in an explosion. Fires that involve Aluminum nitrate , produce oxides of nitrogen. Uses include, petroleum refining, dyeing, and leather tanning.
Air & Water ReactionsDeliquescent. Water soluble. Aqueous solutions are acidic.
Reactivity ProfileAluminum nitrate is an oxidizing agent. Mixtures with alkyl esters may explode. Mixtures with phosphorus, tin(II) chloride or other reducing agents may react explosively [Bretherick 1979 p. 108].
HazardPowerful oxidizing agent. Do not store near combustible materials.
Health HazardIngestion of large doses causes gastric irritation, nausea, vomiting, and purging. Contact with dust irritates eyes and skin.
Safety ProfileA poison. A severe eye and mdd skin irritant. A powerful oxidmer. When heated to decomposition it emits toxic NOx. See NITRATES and ALUMINUM COMPOUNDS. A nitrating agent. AHE250
Potential ExposureAluminum nitrate is used in tanning leather; as an antiperspirant, as a corrosion inhibitor, in the extraction of uranium and as a nitrating agent
ShippingUN1438 Aluminum nitrate, Hazard Class: 5.1; Labels: 5.1-Oxidizer.
Purification MethodsCrystallise the nitrate from dilute HNO3, and dry it by passing dry nitrogen through the crystals for several hours at 40o. After 2 recrystallisations of ACS grade, it had S, Na and Fe at 2.2, 0.01 and 0.02 ppm, respectively.
IncompatibilitiesAluminum nitrate is a strong oxidizer; avoid contact with flammable or combustible materials; and reducing agents, including chlorides. In solution this chemical is a strong acid; avoid contact with bases. Explosions may occur when aluminum nitrate is shocked or exposed to heat.
Waste DisposalSee Spill Handling above.
Aluminum nitrate Preparation Products And Raw materials
Raw materialsNitric acid-->Aluminum hydroxide-->Aluminum
Preparation ProductsIndole-->primary natural gas steam reforming catalysts-->Aluminium nitrate nonahydrate-->finishing agent ED for pernyl silk
Tag:Aluminum nitrate(13473-90-0) Related Product Information
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