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1-Chloropropane

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CAS:540-54-5
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  • 2023-08-29
  • CAS:540-54-5
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1-Chloropropane Basic information
Product Name:1-Chloropropane
Synonyms:Propylchlorid;1-CHLOROPROPANE;PROPYL CHLORIDE;AKOS BBS-00004427;Chloropropane,99%;n-C3H7Cl;Propane,1-chloro-;1-CHLOROPROPANE, FOR GC
CAS:540-54-5
MF:C3H7Cl
MW:78.54
EINECS:208-749-7
Product Categories:API Intermediate;fine chemicals;Organics;Alkyl Chlorides;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes
Mol File:540-54-5.mol
1-Chloropropane Structure
1-Chloropropane Chemical Properties
Melting point -123 °C
Boiling point 46-47 °C(lit.)
density 0.892 g/mL at 25 °C(lit.)
vapor density 2.71 (vs air)
vapor pressure 5.51 psi ( 20 °C)
refractive index n20/D 1.388(lit.)
Fp −25 °F
storage temp. 2-8°C
solubility 2.7g/l
form Liquid
color Clear colorless
explosive limit2.6-11.1%(V)
Water Solubility 2.7 g/L (20 ºC)
Merck 14,7847
BRN 1730771
Dielectric constant8.5299999999999994
LogP2.04 at 20℃
CAS DataBase Reference540-54-5(CAS DataBase Reference)
NIST Chemistry ReferencePropane, 1-chloro-(540-54-5)
EPA Substance Registry System1-Chloropropane (540-54-5)
Safety Information
Hazard Codes F,Xn
Risk Statements 11-20/21/22
Safety Statements 9-29-2017/9/29
RIDADR UN 1278 3/PG 2
WGK Germany 3
RTECS TX4400000
Autoignition Temperature968 °F
HS Code 2903 19 00
HazardClass 3.1
PackingGroup II
Hazardous Substances Data540-54-5(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: > 2000 mg/kg
MSDS Information
ProviderLanguage
1-Chloropropane English
SigmaAldrich English
ACROS English
1-Chloropropane Usage And Synthesis
Chemical Properties1-Chloropropane is a clear colorless, flammable liquid. It has the chemical formula C3H7Cl and is prepared by reacting n-propyl alcohol with phosphorus trichloride in the presence of a zinc chloride catalyst.
UsesUsed in organic synthesis, pesticides, pharmaceutical intermediates.
General DescriptionA clear colorless liquid. Boiling point 46.6°C. Flash point below 0°F. Less dense than water and slightly soluble in water. Vapors are heavier than air. Irritant and narcotic.
Air & Water ReactionsHighly flammable. Slightly soluble in water.
Reactivity Profile1-Chloropropane presents a dangerous fire risk. May be incompatible with strong oxidizing and reducing agents. Incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
HazardHighly flammable, dangerous fire risk, explosive limits in air 2.5–11%. Irritant and narcotic.
Health HazardExposure can cause irritation of eyes, nose and throat. May cause nausea, headache, and vomiting. High concentrations may have a narcotic effect.
Safety ProfileA moderately poisonous irritant to skin, eyes, and mucous membranes. Narcotic in high concentrations. Flammable liquid and dangerous fire hazard when exposed to heat, flame, or oxiduers. Moderately explosive when exposed to flame. Keep away from heat and open flame; can react vigorously with oxilzing materials. To fight fire, use CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-.
Purification MethodsDry the chloride with MgSO4 and fractionally distil. It can be more extensively purified using extraction with H2SO4 as for n-propyl bromide. Alternatively, Chien and Willard [J Am Chem Soc 75 6160 1953] passed a stream of oxygen containing about 5% ozone through the n-propyl chloride for three times as long as was needed to cause the first coloration of starch iodide paper by the exit gas. After washing with aqueous NaHCO3 to hydrolyse ozonides and remove organic acids, the chloride was dried with MgSO4 and fractionally distilled. [Beilstein 1 IV 189.]
Tag:1-Chloropropane(540-54-5) Related Product Information
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