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| | 4-Bromobenzenesulfonyl chloride Basic information |
| | 4-Bromobenzenesulfonyl chloride Chemical Properties |
| Melting point | 73-75 °C (lit.) | | Boiling point | 153 °C/15 mmHg (lit.) | | density | 1.7910 (estimate) | | Fp | 152-154°C/26mm | | storage temp. | Refrigerator, Under Inert Atmosphere | | solubility | soluble in Chloroform, DMSO | | form | Crystals or Crystalline Powder | | color | White to beige | | Water Solubility | decomposes | | Sensitive | Moisture Sensitive | | Merck | 14,1407 | | BRN | 743518 | | CAS DataBase Reference | 98-58-8(CAS DataBase Reference) | | EPA Substance Registry System | Benzenesulfonyl chloride, 4-bromo- (98-58-8) |
| Hazard Codes | C | | Risk Statements | 34 | | Safety Statements | 26-36/37/39-45-27 | | RIDADR | UN 3261 8/PG 2 | | WGK Germany | 3 | | Hazard Note | Irritant | | TSCA | Yes | | HazardClass | 8 | | PackingGroup | II | | HS Code | 29049020 |
| | 4-Bromobenzenesulfonyl chloride Usage And Synthesis |
| Chemical Properties | white to beige crystals or crystalline powder | | Uses | 4-Bromobenzenesulfonyl chloride is used for identification of amines, and also in the synthesis and inhibition studies of substituted N-L-histidinylphenylsulfonyl hydrazide. | | Uses | Identification of amines. | | Uses | 4-Bromobenzenesulfonyl chloride is used as activating agent in the synthesis of oligodeoxyribo- and oligoribo- nucleotides in solution. It also used in the synthesis of 4-(N-allylsulfamoyl)phenylboronic acid and in protection of amines as 4-bromobenzenesulfonamides. | | Synthesis Reference(s) | Synthesis, p. 1203, 1992 DOI: 10.1055/s-1992-26333 | | Purification Methods | Wash the sulfonyl chloride with cold water, dry and recrystallise it from pet ether, or from ethyl ether cooled in powdered Dry-Ice after the ether solution had been washed with 10% NaOH until colourless, then dry it with anhydrous Na2SO4. Alternatively dissolve it in CHCl3, wash it with H2O, dry (Na2SO4), evaporate and recrystallise it. [Huntress & Carten J Am Chem Soc 62 511 1940.] Test for the SO2Cl group by dissolving it in EtOH and boiling with NH4CNS whereby a yellow amorphous precipitate forms on cooling. [Beilstein 11 IV 162.] |
| | 4-Bromobenzenesulfonyl chloride Preparation Products And Raw materials |
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