ChemicalBook--->CAS DataBase List--->100-59-4

100-59-4

100-59-4 Structure

100-59-4 Structure
IdentificationMore
[Name]

PHENYLMAGNESIUM CHLORIDE
[CAS]

100-59-4
[Synonyms]

PHENYLMAGNESIUM CHLORIDE
chlorophenylmagnesium
PHENYLMAGNESIUM CHLORIDE SOLUTION &
PHENYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF
PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN
Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran
PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF
Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran
PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER
PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN
Phenylmagnesiumchloride,2-3MinTHF
PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN
Chlorphenylmagnesium
chlorophenyl-magnesiu
Magnesium, chlorophenyl-
Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)
Phenylmagnesium chloride25 wt% solution in tetrahydrofuranAcroSeal§3
Phenylchloromagnesium
[EINECS(EC#)]

202-868-8
[Molecular Formula]

C6H5ClMg
[MDL Number]

MFCD00000464
[Molecular Weight]

136.86
[MOL File]

100-59-4.mol
Chemical PropertiesBack Directory
[Appearance]

yellowish-brown to dark brown solution
[Melting point ]

89-90℃
[Boiling point ]

230℃ (8 Torr)
[density ]

0.98 g/mL at 20 °C
[Fp ]

1 °F
[storage temp. ]

water-free area
[Water Solubility ]

It reacts violently with water.
[Sensitive ]

Air & Moisture Sensitive
[Merck ]

7298
[BRN ]

3587900
[InChIKey]

GQONLASZRVFGHI-UHFFFAOYSA-M
[CAS DataBase Reference]

100-59-4(CAS DataBase Reference)
[EPA Substance Registry System]

Magnesium, chlorophenyl- (100-59-4)
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

R14:Reacts violently with water.
R19:May form explosive peroxides.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S33:Take precautionary measures against static discharges .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2924 3/PG 2
[WGK Germany ]

2
[F ]

10
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29319090
[Hazardous Substances Data]

100-59-4(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chlorobenzene-->Magnesium-->Toluene-->Tetrahydrofuran
[Preparation Products]

5-METHOXY-2-NITROPHENYLBORONIC ACID-->5-CYANO-2-NITROPHENYLBORONIC ACID-->5-(BROMOMETHYL)-2-NITROPHENYLBORONIC ACID-->4-BROMO-2-NITROPHENYLBORONIC ACID-->4-METHOXY-2-NITROPHENYLBORONIC ACID-->5-METHYL-2-NITROPHENYLBORONIC ACID-->4-Phenylpyridine-->4-FLUORO-2-NITROPHENYLBORONIC ACID-->1-Phenylnonane-->1,1-DIPHENYLETHANOL-->(5-bromo-2-fluorophenyl)(phenyl)methanol-->Triphenylphosphine
Hazard InformationBack Directory
[Chemical Properties]

yellowish-brown to dark brown solution
[Uses]

In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.
[Definition]

ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.
[General Description]

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Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran, AcroSeal?(100-59-4)
[Sigma Aldrich]

100-59-4(sigmaaldrich)
[TCI AMERICA]

Phenylmagnesium Chloride  (27% in Tetrahydrofuran, ca. 2mol/L)(100-59-4)
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