ChemicalBook--->CAS DataBase List--->100-59-4

100-59-4

100-59-4 Structure

100-59-4 Structure
IdentificationMore
[Name]

PHENYLMAGNESIUM CHLORIDE
[CAS]

100-59-4
[Synonyms]

PHENYLMAGNESIUM CHLORIDE
chlorophenylmagnesium
PHENYLMAGNESIUM CHLORIDE SOLUTION &
PHENYLMAGNESIUM CHLORIDE SOLUTION, ~2.0 M IN THF
PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN
Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran
PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF
Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran
PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER
PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN
Phenylmagnesiumchloride,2-3MinTHF
PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN
Chlorphenylmagnesium
chlorophenyl-magnesiu
Magnesium, chlorophenyl-
Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)
Phenylmagnesium chloride25 wt% solution in tetrahydrofuranAcroSeal§3
Phenylchloromagnesium
[EINECS(EC#)]

202-868-8
[Molecular Formula]

C6H5ClMg
[MDL Number]

MFCD00000464
[Molecular Weight]

136.86
[MOL File]

100-59-4.mol
Chemical PropertiesBack Directory
[Appearance]

yellowish-brown to dark brown solution
[Melting point ]

89-90℃
[Boiling point ]

230℃ (8 Torr)
[density ]

0.98 g/mL at 20 °C
[Fp ]

1 °F
[storage temp. ]

water-free area
[form ]

solution
[Water Solubility ]

It reacts violently with water.
[Sensitive ]

Air & Moisture Sensitive
[Merck ]

7298
[BRN ]

3587900
[InChI]

InChI=1S/C6H5.ClH.Mg/c1-2-4-6-5-3-1;;/h1-5H;1H;/q;;+1/p-1
[InChIKey]

GQONLASZRVFGHI-UHFFFAOYSA-M
[SMILES]

C1([Mg]Cl)C=CC=CC=1
[CAS DataBase Reference]

100-59-4(CAS DataBase Reference)
[EPA Substance Registry System]

Magnesium, chlorophenyl- (100-59-4)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS05,GHS07,GHS08
[Signal word ]

Danger
[Hazard statements ]

H371-H372-H261-H312-H318-H333-H225-H302-H314-H335-H351
[Precautionary statements ]

P223-P303+P361+P353-P501a-P210-P260-P280-P305+P351+P338-P370+P378-P403+P235-P233-P240-P241+P242+P243-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P308+P311-P403+P233-P405-P501
[Hazard Codes ]

F,C
[Risk Statements ]

R14:Reacts violently with water.
R19:May form explosive peroxides.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R34:Causes burns.
R67:Vapors may cause drowsiness and dizziness.
R65:Harmful: May cause lung damage if swallowed.
R63:Possible risk of harm to the unborn child.
R48/20:Harmful: danger of serious damage to health by prolonged exposure through inhalation .
R11:Highly Flammable.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S62:If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label .
S33:Take precautionary measures against static discharges .
S16:Keep away from sources of ignition-No smoking .
[RIDADR ]

UN 2924 3/PG 2
[WGK Germany ]

2
[F ]

10
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29319090
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Carc. 2
Eye Dam. 1
Flam. Liq. 2
Skin Corr. 1B
STOT SE 3
[Hazardous Substances Data]

100-59-4(Hazardous Substances Data)
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Chlorobenzene-->Magnesium-->Toluene-->Tetrahydrofuran
[Preparation Products]

5-Methoxy-2-nitrophenylboronic acid-->5-Cyano-2-nitrophenylboronic acid-->5-(Bromomethyl)-2-nitrophenylboronic acid-->4-Bromo-2-nitrophenylboronic acid-->4-Methoxy-2-nitrophenylboronic acid-->5-Methyl-2-nitrophenylboronic acid-->4-Phenylpyridine-->4-Fluoro-2-nitrophenylboronic acid-->1-Phenylnonane-->1,1-Diphenylethanol-->(5-bromo-2-fluorophenyl)(phenyl)methanol-->Triphenylphosphine
Hazard InformationBack Directory
[Chemical Properties]

yellowish-brown to dark brown solution
[Uses]

In organic synthesis, especially in the production of hydrocarbons, alcohols, ketones, organic acids, amines, silicones, boranes.
[Definition]

ChEBI: Phenylmagnesium chloride is an arylmagnesium halide.
[General Description]

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[reaction suitability]

reaction type: Grignard Reaction
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran, AcroSeal?(100-59-4)
[Sigma Aldrich]

100-59-4(sigmaaldrich)
[TCI AMERICA]

Phenylmagnesium Chloride  (27% in Tetrahydrofuran, ca. 2mol/L)(100-59-4)
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