| Identification | More | [Name]
Quizalofop-p-ethyl | [CAS]
100646-51-3 | [Synonyms]
DPX-Y6202-31
ETHYL (R)-2-[4-(6-CHLORO-2-QUINOXALYLOXY)PHENOXY]PROPIONATE
QUINOFOP-P-ETHYL
QUIZALOFOP-P-ETHYL
2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)-,ethylester,(r)-propanoicaci
assureii
ethyl(r)-2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)propanoate
nci-861094
Ethyl (R)-2-[4-(6-chloroquinoxalin-2-yloxy)phenoxy]propionate
Propanoic acid, 2-4-(6-chloro-2-quinoxalinyl)oxyphenoxy-, ethyl ester, (2R)-
QUIZALOFOP-PETHYLESTER
2-(4-((6-chloro-2-quinoxalinyl)oxy)phenoxy)-, ethyl ester, (r)-propanoic acid
DPX-Y6202
Ethyl (2R)-2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]propionate
EXP-3864
FBC-32197
Quizalofop ethyl ester
DPX-Y6202, Quinofop-ethyl, Ethyl (R)-2-[4-(6-chloro-2-quinoxalyloxy)phenoxy]propionate
ethyl-(RS)-2-[4-(6-chloro-2-quinoxalinyloxy) phenoxy] propanoate
Pilot Super | [Molecular Formula]
C19H17ClN2O4 | [MDL Number]
MFCD01697481 | [Molecular Weight]
372.8 | [MOL File]
100646-51-3.mol |
| Chemical Properties | Back Directory | [Melting point ]
76-77°C | [Boiling point ]
220 °C | [density ]
1.301±0.06 g/cm3(Predicted) | [Fp ]
>100 °C | [storage temp. ]
Store at 2-8°C | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
neat | [pka]
-1.39±0.48(Predicted) | [color ]
Light yellow to yellow | [Water Solubility ]
0.04 g/100 mL | [Henry's Law Constant]
4.8×103 mol/(m3Pa) at 25℃, Ebert et al. (2023) | [Major Application]
agriculture
environmental | [InChI]
InChI=1S/C19H17ClN2O4/c1-3-24-19(23)12(2)25-14-5-7-15(8-6-14)26-18-11-21-17-10-13(20)4-9-16(17)22-18/h4-12H,3H2,1-2H3/t12-/m1/s1 | [InChIKey]
OSUHJPCHFDQAIT-GFCCVEGCSA-N | [SMILES]
C(OCC)(=O)[C@H](OC1=CC=C(OC2C=NC3C(N=2)=CC=C(Cl)C=3)C=C1)C | [CAS DataBase Reference]
100646-51-3(CAS DataBase Reference) | [EPA Substance Registry System]
100646-51-3(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302+H312-H413 | [Precautionary statements ]
P264-P270-P273-P280-P301+P312-P302+P352+P312 | [Hazard Codes ]
Xn | [Risk Statements ]
R21/22:Harmful in contact with skin and if swallowed . | [Safety Statements ]
S36/37:Wear suitable protective clothing and gloves . | [RIDADR ]
UN3077 9/PG 3 | [WGK Germany ]
3 | [RTECS ]
UA2458257 | [HS Code ]
29333990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1 |
| Hazard Information | Back Directory | [Uses]
Post-emergence herbicide for control of grassy weeds in broad-leaved crops. Herbicide. | [Definition]
ChEBI: Quizalofop-P-ethyl is an ethyl 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoate that has R configuration. A proherbicide for quizalofop-P, it is used to control annual and perennial grass weeds in a variety of crops, including potatoes, sugar beet, peanuts, cotton and flax. It has a role as a proherbicide and an agrochemical. It is an ethyl 2-{4-[(6-chloroquinoxalin-2-yl)oxy]phenoxy}propanoate and a quinoxaline herbicide. It is functionally related to a quizalofop-P. It is an enantiomer of a (S)-quizalofop-ethyl. | [Production Methods]
Quizalofop-P-ethyl is commercially produced through a chiral synthesis starting with the etherification of 2,6-dichloroquinoxaline with hydroquinone under basic conditions to form 2-(6-chloroquinoxalin-2-yloxy)phenol, followed by stereoselective alkylation with ethyl (S)-2-bromopropionate (or resolution of the racemic ester via enzymatic or chiral crystallization methods) in the presence of potassium carbonate to yield the active compound. | [Mechanism of action]
Selective. Acetyl CoA carboxylase inhibitor (ACCase) - distrupts fatty acid biosynthesis and lipid formation. | [Purification Methods]
This (±)-herbicide forms white crystals from Me2CO/EtOH and sublimes in vacuo. Large quantities can be distilled at high vacuum. Its solubilities at 20o in g/10mL are 0.09 (EtOH), 1.1 (Me2CO), 1.2 (xylene), 2.9 (*C6H6), and is nearly insoluble in H2O (0.3mg/L). The (±)-acid has [95977-28-9]. The R-ester enantiomer has m 76-77o (pale brown crystals from EtOH), [ ] D 20 + 3 5 . 9o (EtOH). It is the more active fatty acid synthase inhibitor (designated DPX-Y6202) used to control grassy weeds in broadleaf crops. | [Pesticide Type]
Herbicide |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
China Langchem Inc.
|
| Telephone: |
0086-21-58956006 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
|