| Identification | More | [Name]
4,4'-DIMETHOXYDIPHENYLAMINE | [CAS]
101-70-2 | [Synonyms]
4,4'-DIMETHOXYDIPHENYLAMINE
BIS(4-METHOXYPHENYL)AMINE
BIS(P-ANISYL)AMINE
DI-P-ANISYLAMINE
4,4’-dimethoxy-4-biphenylamin
4-Biphenylamine, 4,4'-dimethoxy-
4-Methoxy-N-(4-methoxyphenyl)aniline
4-methoxy-n-(4-methoxyphenyl)-benzenamin
Benzenamine, 4-methoxy-N-(4-methoxyphenyl)-
Bis(4-methoxyphenyl)-amin
Bis(p-methoxyphenyl)amine
Di-p-methoxyphenylamine
p,p’-dimethoxydiphenylamine
p,p'-Dimethoxydiphenylamine
Termofleks A
N-(4-methoxyphenyl)-p-anisidine
4-Methoxy-N-(4-methoxyphenyl)benzamide
4,4''-DIMETHOXYDIPHENYLAMINE 98%
4-Methoxyphenyl(4-methoxyphenyl)amine | [EINECS(EC#)]
202-968-1 | [Molecular Formula]
C14H15NO2 | [MDL Number]
MFCD00014895 | [Molecular Weight]
229.27 | [MOL File]
101-70-2.mol |
| Chemical Properties | Back Directory | [Appearance]
silver-grey crystalline solid | [Melting point ]
101-102°C | [Boiling point ]
371.18°C (rough estimate) | [density ]
1.0955 (rough estimate) | [refractive index ]
1.5300 (estimate) | [storage temp. ]
Keep in dark place,Inert atmosphere,Room temperature | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
2.16±0.40(Predicted) | [color ]
Off-White to Light Brown | [Stability:]
Stability Combustible. Incompatible with strong oxidizing agents. | [Water Solubility ]
Soluble in methanol. Insoluble in water. | [Sensitive ]
Air Sensitive | [BRN ]
2214262 | [InChI]
1S/C14H15NO2/c1-16-13-7-3-11(4-8-13)15-12-5-9-14(17-2)10-6-12/h3-10,15H,1-2H3 | [InChIKey]
VCOONNWIINSFBA-UHFFFAOYSA-N | [SMILES]
COc1ccc(Nc2ccc(OC)cc2)cc1 | [CAS DataBase Reference]
101-70-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Di-(4-methoxy phenyl) amine(101-70-2) | [EPA Substance Registry System]
101-70-2(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS07,GHS08 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335-H351 | [Precautionary statements ]
P201-P302+P352-P305+P351+P338-P308+P313 | [Hazard Codes ]
Xn | [Risk Statements ]
R68:Possible risk of irreversible effects. | [Safety Statements ]
S22:Do not breathe dust .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [WGK Germany ]
3 | [RTECS ]
DU9085000 | [TSCA ]
Yes | [HS Code ]
29222990 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Carc. 2
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Toxicity]
mouse,LD50,oral,2500mg/kg (2500mg/kg),BEHAVIORAL: CHANGES IN MOTOR ACTIVITY (SPECIFIC ASSAY)BEHAVIORAL: TREMORLUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,Kauchuk i Rezina. Crude and Vulcanized Rubber. Vol. 26(9), Pg. 28, 1967. |
| Hazard Information | Back Directory | [General Description]
Fine very light gray to silver-gray crystalline solid. | [Reactivity Profile]
4,4'-DIMETHOXYDIPHENYLAMINE(101-70-2) neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides. | [Air & Water Reactions]
This chemical may be sensitive to prolonged exposure to air. Slowly oxidized. Insoluble in water. | [Health Hazard]
ACUTE/CHRONIC HAZARDS: This compound can produce extremely irritating fumes when exposed to air or fire. | [Fire Hazard]
Flash point data for this chemical are not available. 4,4'-DIMETHOXYDIPHENYLAMINE is probably combustible. | [Description]
4,4'-Dimethoxydiphenylamine is a diphenylamine containing electron-donating substituents that exhibits antioxidant activity. When present as an antioxidant, it is consumed to generate nitroso radicals, which in turn exert antioxidant effects [1]. It can also be used in the synthesis of 9,9′-bis(fluorenylidene) (KR216) hole-transporting materials. When applied in perovskite solar cells, it achieves a power conversion efficiency of 17.8% [2]. | [Chemical Properties]
silver-grey crystalline solid | [Uses]
4,4'-Dimethoxydiphenylamine is a diphenylamine derivative used as a chemical additive for cured rubber. 4,4'-Dimethoxydiphenylamine is highly toxic and may potentially induce chromosome abberation. | [References]
[1] Mareyuki Takahashi, E. N., J. Tsuchiya. (1989). Oxidation of lipids. XVI. Inhibition of autoxidation of methyl linoleate by diarylamines. Bulletin of the Chemical Society of Japan, 62 1, 1880–1884. https://doi.org/10.1246/bcsj.62.1880
[2] Kasparas Rakstys. (2016). Highly Efficient Perovskite Solar Cells Employing an Easily Attainable Bifluorenylidene-Based Hole-Transporting Material. Angewandte Chemie International Edition, 55 26, 7464–7468. https://doi.org/10.1002/anie.201602545
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