| Identification | More | [Name]
Lithium sulfate monohydrate | [CAS]
10102-25-7 | [Synonyms]
LITHIUM SULFATE
LITHIUM SULFATE-1-HYDRATE
LITHIUM SULFATE HYDRATE
LITHIUM SULFATE, HYDROUS
LITHIUM SULFATE MONOHYDRATE
LITHIUM SULPHATE H2O
LITHIUM SULPHATE, MONOHYDRATE
LITHIUM SULFATE MONOHYDRATE SIGMAULTRA
LITHIUM SULFATE MONOHYDRATE 99+% &
LITHIUM SULFATE-1-HYDRATE EXTRA PURE
LITHIUM SULFATE MONOHYDRATE, 99+%, A.C.S . REAGENT
RESOLVE-AL GD 99+%
LITHIUM SULFATE MONOHYDRATE ACS REAGENT
LITHIUM SULFATE MONOHYDRATE, ACS
LithiumSulphateGr
Lithium sulfate monohydrate, 99.8%
Lithium sulfate monohydrate, ACS, 99+%
LITHIUM SULFATE H2O
LITHIUM SULFATE, MONOHYDRATE BIO-REFINED
LITHIUM SULFATE, MONOHYDRATE REAGENT (ACS) | [EINECS(EC#)]
233-820-4 | [Molecular Formula]
H2Li2O5S | [MDL Number]
MFCD00149766 | [Molecular Weight]
127.96 | [MOL File]
10102-25-7.mol |
| Chemical Properties | Back Directory | [Appearance]
White crystal | [Melting point ]
860 °C | [bulk density]
940kg/m3 | [density ]
2.22 | [storage temp. ]
Store at +15°C to +25°C. | [solubility ]
H2O: 1 M at 20 °C, clear, colorless
| [form ]
Granular | [color ]
White | [Specific Gravity]
2.06 (20℃) | [Odor]
Odorless | [PH]
4.5-6.0 (50g/l, H2O, 20℃) | [PH Range]
5 - 7 at 128 g/l at 25 °C | [Stability:]
Stable. | [Water Solubility ]
Soluble in water. Soluble in water. Insoluble in ethanol, acetone and pyridine. | [λmax]
λ: 260 nm Amax: ≤0.3
λ: 280 nm Amax: ≤0.1 | [Merck ]
14,5541 | [InChI]
1S/2Li.H2O4S.H2O/c;;1-5(2,3)4;/h;;(H2,1,2,3,4);1H2/q2*+1;;/p-2 | [InChIKey]
RKGLUDFWIKNKMX-UHFFFAOYSA-L | [SMILES]
[Li+].[Li+].O.[O-]S([O-])(=O)=O | [CAS DataBase Reference]
10102-25-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H319 | [Precautionary statements ]
P264-P270-P280-P301+P312-P305+P351+P338-P337+P313 | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
1
| [RTECS ]
OJ6419000
| [TSCA ]
Yes | [HS Code ]
28332990 | [Storage Class]
13 - Non Combustible Solids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Irrit. 2 | [Toxicity]
LD50 orally in Rabbit: 613 mg/kg |
| Hazard Information | Back Directory | [Description]
Lithium sulfate monohydrate is an inorganic lithium salt. It is relatively stable in atmospheric conditions. It is used in building blocks and chemical synthesis. | [Chemical Properties]
Colorless monoclinic or hexagonal crystals; transforms to cubic form at 500°C; refractive index 1.465; density 2.221 g/cm3; sublimes at 845°C; soluble in water, solubility decreases with an increase in temperature (26.1 and 23.2 g at 0 and 100°C, respectively); insoluble in absolute ethanol and acetone.
The monohydrate constitutes colorless monoclinic crystals; refractive index 1.465; density 2.06 g/cm3; loses water of crystallization at 130°C; soluble in water, (more soluble than the anhydrous salt (34.9 and 29.2 g/100g at 25 and 100°C), respectively; insoluble in acetone and pyridine.
| [Uses]
Lithium sulfate monohydrate is used in making a special type of high strength glass. It also is used in medicine as an antidepressant,used in preparation of lithium standard solutions.
|
| Questions and Answers (Q&A) | Back Directory | [Preparation]
Lithium sulfate is prepared by neutralization of lithium hydroxide or lithium carbonate with sulfuric acid followed by crystallization:
2LiOH + H2SO4 → Li2SO4 + H2O
Li2CO3 + H2SO4 → Li2SO4 + CO2 + H2O
The product obtained from crystallization in a concentrated solution is the monohydrate, Li2SO4•H2O. Anhydrous salt is obtained by heating the monohydrate in a vacuum.
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