| Identification | More | [Name]
HOLMIUM CHLORIDE | [CAS]
10138-62-2 | [Synonyms]
HOLMIUM CHLORIDE
HOLMIUM CHLORIDE HEXAHYDRATE
HOLMIUM CHLORIDE, HYDROUS
HOLMIUM(III) CHLORIDE
HOLMIUM(III) CHLORIDE HEXAHYDRATE
HOLMIUM(III) CHLORIDE HYDRATE
HOLMIUM TRICHLORIDE
HoCl3
Holmium chloride (HoCl3)
holmiumchloride(hocl3)
Holmium (III) chloride, anhydrous
HOLMIUM(III) CHLORIDE, ANHYDROUS, POWDER , 99.9%
HOLMIUM(III) CHLORIDE, 99.9%
Holmium chloride anhydrous, 99.99%
Holmiumchlorideanhydrous
HOLMIUM CHLORIDE, ANHYDROUS, 99.9%
Holmium(III)chloride,anhydrous(99.9%-Ho)(REO)
HOLMIUM(III) CHLORIDE, ANHYDROUS: 99.99% (METAL BASIS)
Holmium(III) chloride, anhydrous, 99.9% (metals basis)
HOLMIUM(III) CHLORIDE, 99.90% | [EINECS(EC#)]
233-387-1 | [Molecular Formula]
Cl3Ho | [MDL Number]
MFCD00011051 | [Molecular Weight]
271.29 | [MOL File]
10138-62-2.mol |
| Chemical Properties | Back Directory | [Appearance]
Off-white powder | [Melting point ]
718 °C(lit.)
| [Boiling point ]
1500°C | [density ]
3,7 g/cm3 | [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
soluble in H2O | [form ]
powder
| [color ]
Off-white to pink | [Water Solubility ]
Soluble in water. | [Specific Heat Capacity]
Cp(crystal):0.324376J/(g·K),at 25℃ | [Crystal Structure]
AlCl3 type | [Sensitive ]
Hygroscopic | [crystal system]
Monoclinic | [Merck ]
14,4727 | [Space group]
C2/m | [Lattice constant]
| a/nm | b/nm | c/nm | α/o | β/o | γ/o | V/nm3 | | 0.685 | 1.185 | 0.639 | 90 | 110.8 | 90 | 0.485 |
| [Stability:]
hygroscopic | [InChI]
1S/3ClH.Ho/h3*1H;/q;;;+3/p-3 | [InChIKey]
PYOOBRULIYNHJR-UHFFFAOYSA-K | [SMILES]
Cl[Ho](Cl)Cl | [CAS DataBase Reference]
10138-62-2(CAS DataBase Reference) | [EPA Substance Registry System]
Holmium chloride (HoCl3) (10138-62-2) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
| [RTECS ]
MS7350000
| [TSCA ]
Yes | [HS Code ]
28469000 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 | [Toxicity]
mouse,LD50,intraperitoneal,312mg/kg (312mg/kg),BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)BEHAVIORAL: FOOD INTAKE (ANIMAL)LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES,Archives of Environmental Health. Vol. 5, Pg. 437, 1962. |
| Hazard Information | Back Directory | [Chemical Properties]
Yellow monoclinic crystals; hygroscopic; density 3.7 g/cm3 ; melts at 718°C; vaporizes at 1,500°C; readily dissolves in water.
| [Physical properties]
Yellow monoclinic crystals; hygroscopic; density 3.7 g/cm3; melts at 718°C;vaporizes at 1,500°C; readily dissolves in water. | [Uses]
Holmium chloride is an intermediate for preparing holmium metal. | [Preparation]
Holmium chloride is obtained from rare-earth minerals. Recovery steps are discussed above (see Holmium). The rare-earth mineral is cracked by acid attack by heating with hydrochloric acid. The water-soluble chloride salt is filtered and separated from insoluble residues. The hydrated chloride salt is heated at 350°C in a current of hydrogen chloride to yield anhydrous HoCl3 . Heating in air in the absence of hydrogen chloride yields holmium oxychloride, HoOCl. Holmium chloride may be purified by distillation or vacuum sublimation.
Holmium chloride also can be prepared by heating holmium oxide with ammonium chloride:
Ho2O3 + 6NH4Cl-->2HoCl3 + 6NH3 + 3H2O | [reaction suitability]
reagent type: catalyst
core: holmium |
|
|