ChemicalBook--->CAS DataBase List--->13590-82-4

13590-82-4

13590-82-4 Structure

13590-82-4 Structure
IdentificationMore
[Name]

CERIC SULFATE
[CAS]

13590-82-4
[Synonyms]

CERIC SULFATE
CERIC SULPHATE
CERIUM(+4)SULFATE
CERIUM(IV) SULFATE
CERIUM(IV) SULFATE-4-HYDRATE
CERIUM(IV) SULFATE, COMPLEX WITH SULFURIC ACID
CERIUM (IV) SULPHATE
CERIUM SULFATE
TETRASULFATO-CERIC ACID
cericdisulfate
Cericsulfate,anhydrous
ceriumdisulfate
ceriumsulphate
Sulfuricacid,cerium(4+)salt(2:1)
sulfuricacid,cerium(4++)salt(2:1)
sulfuricacid,ceriumsalt(2:1)
cerium(4+) disulphate
Cerium(Ⅳ) sulfate tetrahydrate
CERIUM(IV) SULFATE SOLUTION 0,1 MOL/L, 0 ,1 N VOLUMETRIC SOLUTION
CERIC SULFATE STANDARD SOLUTION 0.1 MOL
[EINECS(EC#)]

237-029-5
[Molecular Formula]

CeO8S2
[MDL Number]

MFCD00148852
[Molecular Weight]

332.24
[MOL File]

13590-82-4.mol
Chemical PropertiesBack Directory
[Appearance]

yellow odourless solid
[density ]

3.01 g/mL at 25 °C(lit.)
[vapor pressure ]

0.001Pa at 20℃
[storage temp. ]

Inert atmosphere,Room Temperature
[form ]

Liquid
[color ]

Light yellow
[PH]

0.4 (20°C in H2O)
[Water Solubility ]

Soluble in water and dilute sulfuric acid.
[Sensitive ]

Hygroscopic
[Merck ]

14,1990
[InChI]

InChI=1S/Ce.H2O4S/c;1-5(2,3)4/h;(H2,1,2,3,4)
[InChIKey]

RWACICCRNCPMDT-UHFFFAOYSA-N
[SMILES]

S(O)(O)(=O)=O.[Ce]
[CAS DataBase Reference]

13590-82-4(CAS DataBase Reference)
[EPA Substance Registry System]

Sulfuric acid, cerium(4+) salt (2:1) (13590-82-4)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)Environment (GHS09)
GHS05,GHS09
[Signal word ]

Danger
[Hazard statements ]

H314-H410
[Precautionary statements ]

P260-P273-P280-P301+P330+P331-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

Xi,O
[Risk Statements ]

R8:Contact with combustible material may cause fire.
R36/38:Irritating to eyes and skin .
R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S17:Keep away from combustible material .
[RIDADR ]

UN 2796 8/PG 2
[WGK Germany ]

3
[RTECS ]

WS6960000
[TSCA ]

Yes
[REACH Registrations]

Active
[HazardClass ]

5.1
[PackingGroup ]

III
[HS Code ]

2846100090
[Storage Class]

8B - Non-combustible corrosive hazardous materials
[Hazard Classifications]

Aquatic Acute 1
Aquatic Chronic 1
Eye Dam. 1
Skin Corr. 1B
[Safety Profile]

Experimental reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Ceric ammonium nitrate-->Cerium tetrahydroxide-->Sulfuric acid-->Ammonium hydroxide
Hazard InformationBack Directory
[Chemical Properties]

yellow odourless solid
[Physical properties]

White crystalline powder; orthogonal crystal system; the tetrahydrate is a yellow-to-orange powder which, on heating at 180°C, loses all molecules of water; density of tetrahydrate 3.91 g/cm3; anhydrous salt decomposes at 350°C forming CeOSO4; soluble in water (decomposes); soluble in dilute H2SO4 and other concentrated mineral acids.
[Uses]

calibrated against sodium oxalate, traceable to NIST SRM
[Uses]

Cerium(IV) sulfate is a redox indicator and is used in analytical chemistry for redox titrations. In ionized form, ceric ion acts as a strong oxidizer under acidic conditions. It is also used to prepare spherical-like nanoparticles CeO2, nanoparticles for NO reductions' reactions.
[Preparation]

Cerium(IV) sulfate is prepared by heating cerium(IV) oxide, CeO2 with concentrated H2SO4. Also it may be obtained by the reaction of H2SO4 with cerium carbonate:
Ce(CO3)2 + 2H2SO4 + H2O → Ce(SO4)2?4H2O + 2CO2.
[General Description]

3S - Safe, Smart, Secure
An intelligent packaging solution protected with originality seal.
Reagent information is transferred via RFID from reagent bottle to titrator.
3S reagents are compatible only with the Metrohm Omnis titration platform.

Please see here SigmaAldrich.com/3S
[Flammability and Explosibility]

Notclassified
[reaction suitability]

reaction type: Redox Reactions
Spectrum DetailBack Directory
[Spectrum Detail]

CERIC SULFATE(13590-82-4)IR1
CERIC SULFATE(13590-82-4)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Cerium(IV) sulfate, anhydrous, 97%(13590-82-4)
[Sigma Aldrich]

13590-82-4(sigmaaldrich)
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