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12055-62-8

12055-62-8 Structure

12055-62-8 Structure
IdentificationMore
[Name]

HOLMIUM OXIDE
[CAS]

12055-62-8
[Synonyms]

HOLMIUM(+3)OXIDE
HOLMIUM(III) OXIDE
HOLMIUM OXIDE
UV-VIS STANDARD 6
UV-VIS STANDARD 6: HOLMIUM OXIDE SOLUTION
holmiumoxide(ho2o3)
Rare earth
Holmium (III) oxide (99.9%-Ho) (REO)
HolmiumoxideREOwhitepowder
HOLMIUM OXIDE, 99.9%
HOLMIUM(III) OXIDE, NANOPARTICLES, 99.9&
HOLMIUM OXIDE, 99.999%
HOLMIUM(III) OXIDE, NANOPOWDER, <100NM (BET), 99.9+%
Holmia
Holmium(III) oxide, 99.9%,-325 mesh
HOLMIUM OXIDE NANO-DISPERSION
HOLMIUM OXIDE, 99.99%
holmium(iii) oxide preparation
holmium(iii) oxide, reacton
HOLMIUM(III)OXIDE,POWDER
[EINECS(EC#)]

235-015-3
[Molecular Formula]

Ho2O3
[MDL Number]

MFCD00011053
[Molecular Weight]

377.86
[MOL File]

12055-62-8.mol
Chemical PropertiesBack Directory
[Appearance]

slightly beige solid
[Melting point ]

>100 °C(lit.)
[density ]

1.0966 g/mL at 25 °C
[storage temp. ]

no restrictions.
[solubility ]

DMSO (Slightly, Heated), Methanol (Slightly, Heated), Water (Slightly, Heated)
[form ]

nanopowder
[color ]

Light yellow-orange to beige
[Specific Gravity]

8.36
[Stability:]

Stable, but may be air or moisture sensitive. Incompatible with strong acids.
[Water Solubility ]

Insoluble in water. Soluble in perchloric acids.
[Specific Heat Capacity]

Cp(crystal):0.628587J/(g·K),at 25℃
[Crystal Structure]

Sc2O3 type
[crystal system]

Cube
[Merck ]

14,4727
[Space group]

Ia3
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.060831.060831.060839090901.1938
[Cosmetics Ingredients Functions]

NOT REPORTED
[InChI]

1S/2Ho.3O
[InChIKey]

JYTUFVYWTIKZGR-UHFFFAOYSA-N
[SMILES]

O=[Ho]O[Ho]=O
[Uses]

Refractories, special catalyst.
[CAS DataBase Reference]

12055-62-8(CAS DataBase Reference)
[EPA Substance Registry System]

12055-62-8(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H227
[Precautionary statements ]

P501-P210-P280-P370+P378-P403+P235
[Safety Statements ]

S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[F ]

3-10-23
[TSCA ]

Yes
[HS Code ]

28469099
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Holmium(III) nitrate pentahydrate
[Preparation Products]

Dibutyl ether-->Nitrogen phosphorus potassium mixed fertilizer-->naphtha steam reforming catalysts-->Ethyl lactate-->primary natural gas steam reforming catalysts-->medium temperature Shift catalysts-->Y type molecular sieve-->medium(high)temperature Shift catalysts-->Neodymium carbonate octahydrate-->Ethyl L(-)-lactate-->diammonium diuranium heptaoxide-->Nickel-hydrogen battery-->methanation catalysts-->molecular sieve.Rare-earths-->rare earth magnetic polymer-->Rare earth naphthenates-->Cerium(III) chloride anhydrous-->ion-absorbing type rare earths ore-->low-aluminium molecular sieve catalytic cracking catalyst
Questions And AnswerBack Directory
[Description]

Holmium oxide occurs in nature, usually associated with small quantities of other rare-earth oxides. Commercial applications of this compound have not been explored fully. It is used in refractories and as a catalyst. Characteristic spectral emission lines of holmium oxide glass are used to calibrate spectrophotometers.
[Chemical Properties]

Holmium oxide (Ho2O3), also known as Holmia, is a light yellow powder that is one of the most paramagnetic substances known.
Holmium oxide
Holmium oxide glass has been used as a wavelength standard for over four decades. It has a number of desirable features that have made it a commonly used wavelength standard. It does not induce a slit positioning error as atomic emission lamps may. It is also compact, easy to use, and most importantly, stable over long periods of time.the use of filters made of holmium oxide glass allows the calibration of wavelength for a spectrophotometer over a broad range.
[Uses]

Holmium(III) oxide acts as colorants which is used for cubic zirconia and glass, as a calibration standard for optical spectrophotometers, as a specialty catalyst, phosphor and a laser material.
Holmium Oxide, also called Holmia, has specialized uses in ceramics, glass, phosphors and metal halide lamp, and dopant to garnet laser. Holmium can absorb fission-bred neutrons, it is also used in nuclear reactors to keep atomic chain reaction from running out of control. Holmium Oxide is one of the colorants used for cubic zirconia and glass, providing yellow or red coloring.
It is also used in Yttrium-Aluminum-Garnet (YAG) and Yttrium-Lanthanum-Fluoride (YLF) solid-state lasers found in microwave equipment (which are in turn found in a variety of medical and dental settings).
[Preparation]

Holmium oxide is prepared by thermal decomposition of carbonate, oxalate, hydroxide, nitrate, sulfate, or any oxo salt of holmium:
Ho2(CO3)3 →Ho2O3 + 3CO2
Ho2(SO4)3 →Ho2O3 + 3SO3
The oxide may be obtained by direct combination of elements at elevated temperatures. The element in massive form, however, reacts slowly at high temperatures.
Hazard InformationBack Directory
[Physical properties]

Yellow cubic crystal; density 8.41 g.cm3; melts at 2,415°C; insoluble in water; dissolves in acids (with reactions).
[Application]

Holmium Oxide can be used as:
  • A starting material to prepare Ho2O3-PVAfilm for generating stable Q-switching pulses in a thulium-doped fiber laser(TDFL) cavity.
  • A catalyst for oxidative coupling of methane.
It can also be used as a dopant in the preparation of:
  • Cadmium lead borate glasses.
  • Diamond/copper composites to eliminate interfacial defects through the spark plasma sintering (SPS) method.
[reaction suitability]

reagent type: catalyst
core: holmium
Spectrum DetailBack Directory
[Spectrum Detail]

Holmium Oxide(12055-62-8)IR1
Holmium Oxide(12055-62-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Holmium(III) oxide, 99.9%,-325 mesh(12055-62-8)
[Alfa Aesar]

Holmium(III) oxide, REacton, 99.995% (REO)(12055-62-8)
[Sigma Aldrich]

12055-62-8(sigmaaldrich)
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