ChemicalBook--->CAS DataBase List--->102-77-2

102-77-2

102-77-2 Structure

102-77-2 Structure
IdentificationMore
[Name]

2-(Morpholinothio)benzothiazole
[CAS]

102-77-2
[Synonyms]

2-BENZOTHIAZOLYL-N-MORPHOLINOSULFIDE
2-(MORPHOLINOTHIO)BENZOTHIAZOLE
4-(2-Benzothiazolylthio)-morpholine
AMAX
MBS
N-(2-BENZOTHIAZOLYL)THIOMORPHOLINE
NOBS
N-OXYDIETHYLENE-2-BENZOTHIAZOLESULFENAMIDE
N-OXYDIETHYLENE-2-BENZOTHIAZOLYL SULFENAMIDE
n-oxydiethylenebenzothiazole-2-sulfenamide
N-Oxydiethylene-benzothiazolesulfenamide
SANTOCURE(R) MOR
2-(4-Morpholinothio)benzothiazole
2-(4-morpholinothiobenzothiazole
2-(4-Morpholinylmercapto)benzothiazole
2-(4-Morpholinylsulfanyl)-1,3-benzothiazole
2-(4-Morpholinylthio)benzothiazole
2(4-morpholinyl-thio)-benzothiazole
2-(morpholinothio)-benzothiazol
2-(Morpholinthio)-benzothiazole
[EINECS(EC#)]

203-052-4
[Molecular Formula]

C11H12N2OS2
[MDL Number]

MFCD00022870
[Molecular Weight]

252.36
[MOL File]

102-77-2.mol
Chemical PropertiesBack Directory
[Appearance]

Buff to brown flakes; sweet odor. Insoluble in water; solublein benzene, acetone, methanol.
[Melting point ]

78-80°C
[Boiling point ]

413.1±55.0 °C(Predicted)
[density ]

1.34-1.40
[vapor pressure ]

0.001Pa at 25℃
[refractive index ]

1.5650 (estimate)
[storage temp. ]

-20°C
[solubility ]

Acetone (Slightly, Heated, Sonicated), Chloroform (Slightly)
[form ]

Solid
[pka]

1.05±0.10(Predicted)
[color ]

White to Pale Yellow
[Odor]

buff to brn. flakes, sweet odor
[Contact allergens]

This rubber vulcanization accelerator belongs to the mercaptobenzothiazole-sulfenamide group. It is used as a chemical in the rubber industry, especially in the production of synthetic rubber articles. It is contained in “mercapto mix.” As a corrosion inhibitor, it can be found in cutting fluids or in releasing fluids in the pottery industry. It induces mainly delayed-type hypersensitivity, but a case of immediate-type hypersensitivity was reported in a dental assistant.
[LogP]

3.4 at 25℃ and pH7
[Uses]

Delayed-action vulcanization accelerator.
[Dissociation constant]

-6.82-2.65 at 25℃
[CAS DataBase Reference]

102-77-2(CAS DataBase Reference)
[NIST Chemistry Reference]

Morpholine, 4-(2-benzothiazolylthio)-(102-77-2)
[EPA Substance Registry System]

102-77-2(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi,N
[Risk Statements ]

R22:Harmful if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R43:May cause sensitization by skin contact.
R36/38:Irritating to eyes and skin .
[Safety Statements ]

S20/21:When using, do not eat, drink or smoke .
S36:Wear suitable protective clothing .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S37:Wear suitable gloves .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S24:Avoid contact with skin .
[RIDADR ]

3077
[RTECS ]

DL5950000
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29342000
[Hazardous Substances Data]

102-77-2(Hazardous Substances Data)
[Toxicity]

LD50 orl-rat: 1980 mg/kg IPSTB3 3,93,76
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Sodium hydroxide-->Hydrochloric acid-->Chlorine-->Sodium hypochlorite-->Morpholine-->2-Mercaptobenzothiazole-->4-chloromorpholine-->2-Benzothiazolesulfenamide(6CI,7CI,8CI,9CI)-->Sodium sulfite-->2,2'-Dithiobis(benzothiazole)
[Preparation Products]

4-(2-BENZOTHIAZOLYLDITHIO)MORPHOLINE
Hazard InformationBack Directory
[Description]

This rubber vulcanization accelerator is used as a chemical in the rubber industry, especially in the production of synthetic rubber articles. Is contained in the "mercapto mix". As a corrosion inhibitor, it can be found in cutting fluids or in releasing fluids in the pottery industry. It induces mainly delayed-type hypersensitivity, but a case of immediate-type hypersensitivity was reported in a dental assistant.
[Chemical Properties]

Buff to brown flakes; sweet odor. Insoluble in water; solublein benzene, acetone, methanol.
[Safety Profile]

Poison by intraperitoneal route.Moderately toxic by ingestion. Questionable carcinogenwith experimental neoplastigenic data. Experimentalteratogenic effects. An eye irritant. Mutation datareported. When heated to decomposition it emits very toxic fum
Spectrum DetailBack Directory
[Spectrum Detail]

2-(Morpholinothio)benzothiazole(102-77-2)MS
2-(Morpholinothio)benzothiazole(102-77-2)1HNMR
2-(Morpholinothio)benzothiazole(102-77-2)13CNMR
2-(Morpholinothio)benzothiazole(102-77-2)IR1
2-(Morpholinothio)benzothiazole(102-77-2)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

102-77-2(sigmaaldrich)
[TCI AMERICA]

2-(Morpholinothio)benzothiazole(102-77-2)
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