| Identification | More | [Name]
Zinc bis dimethyldithiocarbamate | [CAS]
137-30-4 | [Synonyms]
AAVOLEX
CEKUZIRAM
COROZATE(R)
CRITTAM
CUMAN
DIMETHYLDITHIOCARBAMIC ACID ZINC SALT
FUCLASIN
FUCLASINE(R)
FUKLASIN(R)
KARBAM WHITE(R)
METHASAN(R)
METHYL ZIMATE
METHYL ZIMATE PELFORM
MEZENE
MILBAM(R)
POMARSOL Z
POMARSOL Z(R)
THIONIC
TRISCABOL
Tuzet | [EINECS(EC#)]
205-288-3 | [Molecular Formula]
C6H12N2S4Zn1 | [MDL Number]
MFCD00679340 | [Molecular Weight]
305.829 | [MOL File]
137-30-4.mol |
| Chemical Properties | Back Directory | [Appearance]
White and odorless when pure. Almost insoluble inwater; soluble in acetone,
carbon disulfide, chloroform, dilute alkalies,
and concentrated hydrochloric acid. | [Melting point ]
248-257 °C(lit.)
| [Boiling point ]
335.83℃[at 101 325 Pa] | [density ]
1.66 | [vapor pressure ]
<1 x 10-6 Pa | [storage temp. ]
APPROX 4°C
| [solubility ]
DMSO (Sparingly), Methanol (Sparingly) | [form ]
Powder | [color ]
White | [Specific Gravity]
1.71 | [Odor]
odorless when pure | [Water Solubility ]
0.0065 g/100 mL | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [Merck ]
10172 | [BRN ]
3707008 | [Contact allergens]
Ziram is a rubber vulcanization accelerator of the
dithiocarbamate group. Sensitization was reported in
several patients. Ziram is also used as a fungicide and
can cause contact dermatitis in agricultural workers. | [InChIKey]
DUBNHZYBDBBJHD-UHFFFAOYSA-L | [LogP]
1.65 at 20℃ | [CAS DataBase Reference]
137-30-4(CAS DataBase Reference) | [IARC]
3 (Vol. Sup 7, 53) 1991 | [NIST Chemistry Reference]
Zinc, bis(dimethylcarbamodithioato-s,s')-, (t-4)-(137-30-4) | [EPA Substance Registry System]
137-30-4(EPA Substance) |
| Hazard Information | Back Directory | [Uses]
Zinc Dimethyldithiocarbamate is a member of a class of dithiocarbamates, and has been used in agriculture as a fungicide and in the rubber industry as a vulcanization accelerator. | [Definition]
ChEBI: A dithiocarbamate salt that is the zinc salt of dimethyldithiocarbamic acid. It is a broad-spectrum fungicide and bird and animal repellent that is also used to accelerate the vulcanisation of rubber. | [Uses]
Rubber vulcanization accelerator; agricultural fungicide. | [General Description]
Odorless white powder. | [Reactivity Profile]
ZIRAM(137-30-4) is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides. ZIRAM(137-30-4) is corrosive to iron and copper. ZIRAM(137-30-4) is incompatible with strong oxidizing agents and acids. ZIRAM(137-30-4) is also incompatible with mercury. | [Air & Water Reactions]
Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Insoluble in water. | [Fire Hazard]
This chemical is combustible. This compound may form explosive dust-air mixtures. | [Chemical Properties]
White and odorless when pure. Almost insoluble inwater; soluble in acetone,
carbon disulfide, chloroform, dilute alkalies,
and concentrated hydrochloric acid. | [Hazard]
Strong irritant to eyes and mucous membranes. | [Flammability and Explosibility]
Notclassified | [Agricultural Uses]
Fungicide, Microbiocide, Animal repellant: Ziram is an agricultural fungicide registered to
control fungal diseases on a wide range of crops including stone fruits, pome fruits, nut crops, vegetables and
commercially grown ornamentals, and as a soil and seed
treatment. In addition, it is formulated as a bird and rabbit
repellent for outdoor foliar applications to ornamentals.
Registered for use in EU countries
. Registered for use
in the U.S. | [Trade name]
AAPROTECT®; AAVOLEX®; AAZIRA®;
ACCELERATOR®-L; ACCELERATOR® MZ® Powder;
ACETO ZDED®; ACETO ZDMD®; ALCOBAM ZM®;
ANCANZATE ME®; CARBAZINC®; CIRAM®;
CORONA COROZATE®; COROZATE®; CUMAN®;
CUMAN L®; CYMATE®; DRUPINA® 90; EPTAC-1®;
FUCLASIN®; FUCLASIN® ULTRA; FUKLASIN®;
FUNGOSTOP®; HERMAT ZDM®; HEXAZIR®;
KARBAM WHITE®; KYPZIN®; METHASAN®;
METHAZATE®; MEXENE®; MEZENE®; MILBAM®;
MILBAN®; MOLURAME®; MYCRONIL®;
OCTOCURE ZDM-50®; ORCHARD® BRAND ZIRAM;
PERKACIT ZDMC®; POMARSOL® Z FORTE;
PRODARAM®; PROKIL® Ziram; RHODIACID®;
SOXINAL®-PZ; SOXINOL®-PZ; TRICARBAMIX Z®;
TSIMAT®; TSIRAM® (Russian); ULTRA ZINC DMC®;
VANCIDE® MZ-96; VANCIDE® 51Z Dispersion (with
Zinc 2-mercaptobenzothiazolate); VANCIDE® 51Z
Dispersion (with Ziram); ZERLATE®; ZINCMATE®;
ZIMATE®; ZIMATE®; METHYL®; ZIRAMVIS®;
ZIRASAN®; ZIRBERK®; ZIREX 90®; ZIRIDE®;
ZIRTHANE®; ZITOX® | [Safety Profile]
Poison by ingestion,intraperitoneal, and intravenous routes. Moderately toxicby inhalation. Questionable carcinogen with experimentalcarcinogenic and tumorigenic data. An experimentalteratogen. Other experimental reproductive effects.Human mutation d | [Metabolic pathway]
Ziram is one of the metal containing dithiocarbamates which generates
dimethyldithiocarbamic acid by being cleaved in acidic conditions and
in biological media. The resulting acid is conjugated with glucose and
alanine in plants and with glucuronic acid in mammals. Dimethyldithiocarbamic
acid is further degraded to dimethylamine and CS2. An extensive
review of the properties of dithiocarbamate pesticides was published
by the World Health Organisation (WHO, 1988) from which much of the
following information is taken. | [Purification Methods]
Crystallise this herbicide several times from hot toluene or from hot CHCl3 by addition of EtOH. [Beilstein 4 III 149, 4 IV 234.] | [Degradation]
Ziram is decomposed in acidic media and by UV irradiation (PM). Ziram
is stable in alkaline media but unstable in acidic conditions, decomposing
to dimethylamine and carbon disulfide. |
| Safety Data | Back Directory | [Hazard Codes ]
T+,N | [Risk Statements ]
R22:Harmful if swallowed.
R26:Very Toxic by inhalation.
R37:Irritating to the respiratory system.
R41:Risk of serious damage to eyes.
R43:May cause sensitization by skin contact.
R48/22:Harmful: danger of serious damage to health by prolonged exposure if swallowed .
R50/53:Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment . | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S60:This material and/or its container must be disposed of as hazardous waste .
S61:Avoid release to the environment. Refer to special instructions safety data sheet . | [RIDADR ]
UN 2811 6.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
ZH0525000
| [TSCA ]
Yes | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29302000 | [Hazardous Substances Data]
137-30-4(Hazardous Substances Data) | [Toxicity]
LD50 orally in rats: 1.4 g/kg (Hodge) |
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