| Identification | More | [Name]
4-BROMOTHIOPHENOL | [CAS]
106-53-6 | [Synonyms]
4-BROMOBENZENETHIOL
4-BROMOTHIOPHENOL
P-BROMOBENZENETHIOL
P-BROMOTHIOPHENOL
4-bromo-benzenethio
Benzenethiol, p-bromo-
p-Bromophenyl thiol
4-Bromothiophenol,98%
4-Bromothiophenol 97%
4-bromobenzene-1-thiol | [EINECS(EC#)]
203-407-3 | [Molecular Formula]
C6H5BrS | [MDL Number]
MFCD00004845 | [Molecular Weight]
189.07 | [MOL File]
106-53-6.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO BEIGE CRYSTALS OR CRYSTALLINE POWDER | [Melting point ]
73-76 °C (lit.) | [Boiling point ]
239 °C (lit.) | [density ]
1.5260 | [Fp ]
239°C | [storage temp. ]
Refrigerator | [Water Solubility ]
Slightly soluble in water | [form ]
Crystals or Crystalline Powder | [pka]
6.08±0.10(Predicted) | [color ]
White to beige | [Sensitive ]
Air Sensitive | [Detection Methods]
HPLC,GC,NMR | [BRN ]
507031 | [InChI]
1S/C6H5BrS/c7-5-1-3-6(8)4-2-5/h1-4,8H | [InChIKey]
FTBCOQFMQSTCQQ-UHFFFAOYSA-N | [SMILES]
Sc1ccc(Br)cc1 | [CAS DataBase Reference]
106-53-6(CAS DataBase Reference) | [NIST Chemistry Reference]
Benzenethiol, 4-bromo-(106-53-6) | [EPA Substance Registry System]
106-53-6(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS06,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H301-H315-H319-H335-H410 | [Precautionary statements ]
P261-P264-P273-P301+P310-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi,T,C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
2923 | [WGK Germany ]
3
| [F ]
10-13-23 | [Hazard Note ]
Irritant | [TSCA ]
T | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29309090 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
4-Bromobenzenesulfonyl chloride-->Phosphorus-->iodine-->4,4'-Dibromodiphenyl disulfide-->Bis(4-bromophenyl)disulfide | [Preparation Products]
4H-Amino-6-bromo-2,3-dihydrothiochromen-1,1-dioxide-->1-Benzothiophene-5-carboxylic acid-->4-Hydroxy-6-bromo-2,3-dihydrothiochromen-1,1-dioxide-->2-(1-Benzothiophen-5-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane-->1-Bromo-4-(methylsulphonyl)-2-nitrobenzene-->(5-Bromo-3-benzo[b]thienyl)methanol-->1-Benzothiophene-5-carbonitrile-->5-Bromobenzo[b]thiophene-3-carboxylic acid-->Benzo[b]thiophen-5-yl-5-boronic acid-->6-bromo-2,3-dihydrothiochromen-1,1-dioxide-4-one-->5-Bromobenzo[c]thiophene-->1-(5-Bromo-1-benzothien-3-yl)ethanone-->4-Bromobenzenesulfonic acid monohydrate-->6-bromo-2,3-dihydrothiochromen-4-one-->4-Mercaptophenylboronic acid-->4-(Ethylthio)benzeneboronic acid-->4-(Methylthio)phenylboronic acid-->4-(Trifluoromethylthio)bromobenzene-->1,2-Pyrrolidinedicarboxylic acid, 4-hydroxy-, 1-(1,1-dimethylethyl) 2-methyl ester, (2R,4R)-rel--->4-[(4-Bromophenyl)sulfonyl]piperidine |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO BEIGE CRYSTALS OR CRYSTALLINE POWDER | [Uses]
4-Bromothiophenol is a reagent used in the synthesis of indolyl-3-ehtanone-α-thioethers which act as non-toxic antimalrial agents. These compounds show anti-malarial activity, with no toxicity to a HeLa cell line. | [Application]
4-Bromobenzenethiol can undergo Suzuki-Miyaura reaction on palladium nanoparticles, whereas on gold nanoparticles it only undergoes a self-coupling reaction, and these two processes are known as hot carrier-induced processes. | [Synthesis]
4-Bromothiophenol can be synthesized via the reduction of 4-bromo-benzenesulfonyl chloride by red phosphorus and iodine in an acidic solution. Hydrogenation of 4,4'-dibromodiphenyl disulfide also produces 4-bromothiophenol. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
|
| Telephone: |
0573-85285100 18627885956 |
| Website: |
https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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