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1066-77-9

1066-77-9 Structure

1066-77-9 Structure
IdentificationBack Directory
[Name]

TETRAKIS(DIMETHYLAMINO)TIN
[CAS]

1066-77-9
[Synonyms]

TIN (IV) DIMETHYLAMIDE
TETRAKIS(DIMETHYLAMINO)TIN
Tetrakis(dimethylamine)tin
OCTAMETHYLSTANNANETETRAAMINE
Tetrakis(dimethylamido)tin(IV)
Tetrakis(dimethylamino)tin,96%
tetrakis-(dimethylamino-)-stannane
Tetrakis(dimethylamino)tin(IV), 99% (99.99%-Sn) TDMASn
Tetrakis(diMethylaMino)tin(IV), 99% (99.99%-Sn) TDMASn PURATREM
Tetrakis(dimethylamino)tin Synonyms Tin(IV) dimethylamide
Tetrakis(diMethylaMino)tin(IV), 99% (99.99%-Sn) TDMASn, 50-1815, contained in 50 Ml Swagelok cylinder (96-1070) for CVD/ALD
Tetrakis(dimethylamino)tin(IV), 99% (99.99%-Sn) TDMASn PURATREM, 50-1815, contained in 50 ml Swagelok(R) cylinder (96-1070) for CVD/ALD
[EINECS(EC#)]

201-131-8
[Molecular Formula]

C8H24N4Sn
[MDL Number]

MFCD00014860
[MOL File]

1066-77-9.mol
[Molecular Weight]

295.01
Chemical PropertiesBack Directory
[Appearance]

clear fuming liquid
[Boiling point ]

53-55 °C (0.1 mmHg)
[density ]

1.17
[Fp ]

-7 °C
[form ]

liquid
[pka]

3.60±0.70(Predicted)
[color ]

colorless to pale-yellow
[Specific Gravity]

1.169
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[Sensitive ]

moisture sensitive
[InChI]

InChI=1S/4C2H6N.Sn/c4*1-3-2;/h4*1-2H3;/q4*-1;+4
[InChIKey]

WHXTVQNIFGXMSB-UHFFFAOYSA-N
[SMILES]

[Sn](N(C)C)(N(C)C)(N(C)C)N(C)C
[CAS DataBase Reference]

1066-77-9
Questions And AnswerBack Directory
[Preparation]

TETRAKIS(DIMETHYLAMINO)TIN can be prepared by the following steps:

(1) Adding a solvent to a metal hydride to obtain a suspension;

(2) Adding anhydrous tin tetrachloride dropwise to the suspension and reacting to obtain a reaction solution;

(3) Passing dimethylamine into the reaction solution and stirring to obtain a mixture;

(4) Subjecting the mixture to reduced pressure to remove low-boiling point, reduced pressure distillation, and rectification to obtain the TETRAKIS(DIMETHYLAMINO)TIN.

[Uses]

ALD precursor for tin
Hazard InformationBack Directory
[Chemical Properties]

clear fuming liquid
[General Description]

Atomic number of base material: 50 Tin
[reaction suitability]

core: tin
Safety DataBack Directory
[Hazard Codes ]

T-F,C,F
[Risk Statements ]

41-36/37/38-23/24/25-11-34-20/21/22
[Safety Statements ]

36/37/39-26-16-45
[RIDADR ]

1993
[WGK Germany ]

3
[TSCA ]

No
[HazardClass ]

3, 8
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