| Identification | More | [Name]
4-Chlorostyrene | [CAS]
1073-67-2 | [Synonyms]
4-CHLOROSTYRENE
4-VINYLCHLOROBENZENE
CHLOROSTYRENE-4
P-CHLOROSTYRENE
1-chloro-4-ethenyl-benzen
1-chloro-4-ethenylbenzene
1-Chloro-4-vinylbenzene
4-chloro-styren
Benzene, 4-chloro-1-ethenyl-
benzene,1-chloro-4-ethenyl-
Parachlorostyrene
para-chlorostyrene
p-chloro-styren
Styrene, p-chloro-
styrene,p-chloro-
4-Chlorostyrene, stabilized, 99%
4-CHLOROSTYRENE , STABILIZED WITH 0.1% 4-TERT-BUTYLCATECHOL
4-CHLOROSTYRENE Stabilised with 0.1% 4-tert-butylcatechol
4-CHLOROSTYRENE, 99%, STAB.
4-Chlorostyrene (stabilized with TBC) | [EINECS(EC#)]
214-028-8 | [Molecular Formula]
C8H7Cl | [MDL Number]
MFCD00000632 | [Molecular Weight]
138.59 | [MOL File]
1073-67-2.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,F | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
S37/39:Wear suitable gloves and eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
1993 | [WGK Germany ]
3
| [RTECS ]
CZ0533000 | [TSCA ]
T | [HazardClass ]
3 | [PackingGroup ]
III | [HS Code ]
29036990 | [Hazardous Substances Data]
1073-67-2(Hazardous Substances Data) | [Toxicity]
LD50 orally in Rabbit: 5200 mg/kg |
| Hazard Information | Back Directory | [Chemical Properties]
CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID | [Uses]
4-Chlorostyrene was used in the following studies:
- Study of chemical and biochemical properties of the vinyl group of styrene by the development of structure activity relationships (SAR).
- Preparation of new bis(pyrazolyl)borato olefin complexes of copper(I).
- To investigate the regioselectivity in the cationic Heck reaction of 4-substituted styrenes.
| [Uses]
4-Chlorostyrene is used in the preparation of new bis(pyrazolyl)borato olefin complexes of copper(I). It is also employed in the investigation of regioselectivity in the cationic Heck reaction of 4-substituted styrenes. Further, it plays an important role in the preparation of 4-[(4-chloro-phenyl)-thioacetyl]-morpholine. | [Preparation]
Synthesis of 4-chlorostyrene: carry out catalytic dehydration reaction by 4-chlorophenethylalcohol at 280°C, the used catalyst is a modified aluminum silicate catalyst, and the yield is 80%. | [Synthesis Reference(s)]
Journal of the American Chemical Society, 69, p. 852, 1947 DOI: 10.1021/ja01196a033
Tetrahedron Letters, 31, p. 5061, 1990 DOI: 10.1016/S0040-4039(00)97806-7 | [General Description]
4-Chlorostyrene is a para-halogenated styrene derivative. It undergoes graft copolymerization with acrylonitrile (AN) onto ethylene-propylene-diene terpolymer (EPDM) in the presence of benzoyl peroxide (initiator). |
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