| Identification | More | [Name]
Vinylbenzyl chloride | [CAS]
30030-25-2 | [Synonyms]
4-(CHLOROMETHYL)STYRENE
4-VINYLBENZYL CHLORIDE
CHLOROMETHYLSTYRENE
VINYLBENZYL CHLORIDE
(chloromethyl)ethenyl-benzen
(chloromethyl)ethenyl-Benzene
vinylbenzylchloride,mixtureofisomers
Chloromethylstyrene (m-and p-mixture) (stabilized with TBC)
(chloromethyl)vinylbenzene
ar-(Chloromethyl)-styrene
VINYLBENZYL CHLORIDE, 97%, MIXTURE OF IS OMERS
Chloromethylstyrene,m-/p-mixture,stabilizedwithTBC88+%
CHLOROMETHYLSTYRENE (M-AND P-MIXTURE)
CHLOROMETHYLSTYRENE (M-P MIXTURE)
Chloromethylstyrene
Vinylbenzyl chloride
vinylbenzene chloride
ar-Vinylbenzyl chloride
α-Chlorovinyltoluene
4-Chloromethyl Styrene(VBC) | [EINECS(EC#)]
216-471-2 | [Molecular Formula]
C9H9Cl | [MDL Number]
MFCD00051362 | [Molecular Weight]
152.62 | [MOL File]
30030-25-2.mol |
| Questions And Answer | Back Directory | [Preparation]
A mixture of geranyl diphenyl phosphate (3.23 g, 8.7 mmol) and lithium chloride (0.64 g, 15.1 mmol) in dimethylformamide (15 ml) was stirred at room temperature. After about 10 minutes, a white precipitate of lithium diphenyl phosphate formed. The mixture was allowed to stand overnight. The mixture was then poured into water (100 ml), and the product was extracted with diethyl ether (3 × 30 ml). The extracts were combined, dried over anhydrous sodium sulfate, and concentrated. The residue was purified by distillation to give the final product, Vinylbenzyl chloride. |
| Chemical Properties | Back Directory | [Melting point ]
-30°C | [Boiling point ]
229 °C(lit.)
| [density ]
1.074 g/mL at 25 °C(lit.) | [vapor density ]
5.3 (vs air)
| [vapor pressure ]
1 mm Hg ( 56.1 °C)
| [refractive index ]
n20/D 1.572(lit.)
| [Fp ]
221 °F
| [storage temp. ]
−20°C
| [solubility ]
Acetonitrile (Slightly), Chloroform (Slightly) | [form ]
Liquid | [Water Solubility ]
24.6mg/L at 20℃ | [FreezingPoint ]
-30 | [BRN ]
2204384 | [Stability:]
Air Sensitive, Light Sensitive | [InChI]
1S/2C9H9Cl/c1-2-8-3-5-9(7-10)6-4-8;1-2-8-4-3-5-9(6-8)7-10/h2*2-6H,1,7H2 | [InChIKey]
SLBOQBILGNEPEB-UHFFFAOYSA-N | [SMILES]
ClCc1ccc(C=C)cc1.ClCc2cccc(C=C)c2 | [LogP]
3.5 at 30℃ | [CAS DataBase Reference]
30030-25-2(CAS DataBase Reference) | [EPA Substance Registry System]
30030-25-2(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS06,GHS09 | [Signal word ]
Danger | [Hazard statements ]
H302-H311+H331-H315-H317-H319-H410 | [Precautionary statements ]
P273-P280-P301+P312-P302+P352+P312-P304+P340+P311-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns.
R43:May cause sensitization by skin contact. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 3
| [WGK Germany ]
3
| [F ]
8-19 | [Autoignition Temperature]
1139 °F | [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29039990 | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Skin Irrit. 2
Skin Sens. 1 |
| Hazard Information | Back Directory | [Chemical Properties]
Vinylbenzyl chloride (VBC) is also called (chloromethyl)ethenylbenzene or α-chloromethylstyrene. It is a difunctional monomer with both a polymerizable double bond and a benzylic chlorine, and is an isomeric mixture made by the chlorination of VT. VBC has a high boiling point(98.9 ℃ at 1.3 kPa) and low flammability. | [Uses]
Vinylbenzyl Chloride can be used for acrylic emulsion pressure-sensitive adhesive composition. | [Toxics Screening Level]
An ITSL of 2 μg/m3 for Vinyl Benzyl Chloride was set based on an unpublished study by DOW. |
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| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|