| Identification | More | [Name]
4'-Chloroacetophenone | [CAS]
99-91-2 | [Synonyms]
1-(4-CHLOROPHENYL)ETHANONE
1-ACETYL-4-CHLOROBENZENE
4'-CHLOROACETOPHENONE
4-CHLOROACETOPHENONE
4-CHLOROBENZOPHENONE
(4-chlorophenyl)phenyl-methanone
AKOS 90577
AKOS BBS-00003217
CHLOROACETOPHENONE-4
CHLOROBENZOPHENONE (4-)
P'-CHLOROACETOPHENONE
P-CHLOROACETOPHENONE
P-CHLOROBENZOPHENONE
1-(4-chlorophenyl)-ethanon
1-(4-chlorophenyl)ethanone[qr]
4’-chloro-acetophenon
4-acetylchlorobenzene
4-chloroacetophenone[qr]
4-chlorophenylmethylketone
Acetophenone, 4'-chloro- | [EINECS(EC#)]
202-800-7 | [Molecular Formula]
C8H7ClO | [MDL Number]
MFCD00000622 | [Molecular Weight]
154.59 | [MOL File]
99-91-2.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless to yellowish liquid after melting | [Melting point ]
14-18 °C (lit.) | [Boiling point ]
232 °C (lit.) | [density ]
1.192 g/mL at 25 °C(lit.)
| [vapor pressure ]
8 mm Hg ( 90 °C)
| [refractive index ]
n20/D 1.554(lit.)
| [Fp ]
194 °F
| [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
111mg/l (slow decomposition) | [form ]
Liquid After Melting | [color ]
Clear colorless to yellow | [Odor]
at 100.00 %. sweet mild acetophenone hay | [Odor Type]
floral | [Water Solubility ]
111 mg/L (25 ºC) | [Detection Methods]
GC,NMR | [Merck ]
14,2116 | [BRN ]
386014 | [InChI]
1S/C8H7ClO/c1-6(10)7-2-4-8(9)5-3-7/h2-5H,1H3 | [InChIKey]
BUZYGTVTZYSBCU-UHFFFAOYSA-N | [SMILES]
CC(=O)c1ccc(Cl)cc1 | [LogP]
2.32 at 20℃ | [CAS DataBase Reference]
99-91-2(CAS DataBase Reference) | [NIST Chemistry Reference]
Ethanone, 1-(4-chlorophenyl)-(99-91-2) | [EPA Substance Registry System]
99-91-2(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H319-H335 | [Precautionary statements ]
P261-P264-P270-P271-P301+P312-P305+P351+P338 | [Hazard Codes ]
T+,Xn | [Risk Statements ]
R22:Harmful if swallowed.
R26:Very Toxic by inhalation.
R37/38:Irritating to respiratory system and skin .
R41:Risk of serious damage to eyes.
R36/37/38:Irritating to eyes, respiratory system and skin .
R36/37:Irritating to eyes and respiratory system . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S28:After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 3416 6.1/PG 2
| [WGK Germany ]
3
| [RTECS ]
KM5600000
| [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
6.1 | [PackingGroup ]
II | [HS Code ]
29147090 | [Storage Class]
6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Irrit. 2
STOT SE 3 | [Safety Profile]
Poison by
intraperitoneal route. Moderately toxic by
ingestion. A powerful irritant and
lachrymator. Human systemic effects by
inhalation: lachrymation and unspecified
effects on the eye and sense of smell.
Combustible when exposed to heat or
flame. To fight fire, use water, foam, alcohol
foam, dry chemical. When heated to
decomposition or on contact with water or
steam it emits toxic fumes of Cl- | [Hazardous Substances Data]
99-91-2(Hazardous Substances Data) |
| Hazard Information | Back Directory | [Chemical Properties]
clear colourless to yellowish liquid after melting | [Uses]
Chloroacetophenone is used as a tear gas for riot control and as a kind of chemical mace against small groups or individuals | [Definition]
ChEBI: P-chloroacetophenone is an organic molecular entity.
| [Synthesis Reference(s)]
The Journal of Organic Chemistry, 44, p. 2568, 1979 DOI: 10.1021/jo01328a051
Tetrahedron Letters, 42, p. 265, 2001 DOI: 10.1016/S0040-4039(00)01935-3
Synthetic Communications, 25, p. 2261, 1995 DOI: 10.1080/00397919508011781 |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|