ChemicalBook--->CAS DataBase List--->109-81-9

109-81-9

109-81-9 Structure

109-81-9 Structure
IdentificationMore
[Name]

N-METHYLETHYLENEDIAMINE
[CAS]

109-81-9
[Synonyms]

2-METHYLAMINOETHYLAMINE
N-METHYL-ETHYLENDIAMINE
N-METHYLETHYLENEDIAMINE
RARECHEM AL BW 0523
2-Aminoethylmethylamine
Ethylenediamine, N-methyl-
n-methyl-1,2-ethanediamine
n-methyl-2-ethanediamine
N-Methyldiaminoethane
N-Methylethanediamine
n-methyl-ethylenediamin
n-methylethylidenediamine
N-Methyl-1,2-diaminoethane
2-Methylaminoethylamine 95%
N-METHYLETHYLENEDIAMINE , STABILIZED WITH KOH
N-Methylethylenediamine, 95%, stab. with KOH
[EINECS(EC#)]

203-707-4
[Molecular Formula]

C3H10N2
[MDL Number]

MFCD00008165
[Molecular Weight]

74.12
[MOL File]

109-81-9.mol
Chemical PropertiesBack Directory
[Appearance]

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
[Boiling point ]

114-117 °C (lit.)
[density ]

0.85 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.4395(lit.)
[Fp ]

106 °F
[storage temp. ]

Flammables area
[form ]

Liquid
[pka]

pK1:6.86(+1);pK2:10.15(+1) (25°C)
[color ]

Clear colorless to slightly yellow
[Sensitive ]

Air Sensitive & Hygroscopic
[BRN ]

878141
[InChI]

InChI=1S/C3H10N2/c1-5-3-2-4/h5H,2-4H2,1H3
[InChIKey]

KFIGICHILYTCJF-UHFFFAOYSA-N
[SMILES]

C(NC)CN
[CAS DataBase Reference]

109-81-9(CAS DataBase Reference)
[EPA Substance Registry System]

1,2-Ethanediamine, N-methyl- (109-81-9)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Corrosion (GHS05)
GHS02,GHS05
[Signal word ]

Danger
[Hazard statements ]

H226-H314
[Precautionary statements ]

P210-P233-P240-P280-P303+P361+P353-P305+P351+P338
[Hazard Codes ]

C
[Risk Statements ]

R10:Flammable.
R34:Causes burns.
R37:Irritating to the respiratory system.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 2734 8/PG 2
[WGK Germany ]

3
[RTECS ]

KV5250500
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

II
[HS Code ]

29212900
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B
[Toxicity]

mouse,LD50,intraperitoneal,50mg/kg (50mg/kg),European Journal of Medicinal Chemistry--Chimie Therapeutique. Vol. 17, Pg. 235, 1982.
Raw materials And Preparation ProductsBack Directory
[Raw materials]

METHYLAMINOACETONITRILE-->Acetamide,N-[2-[(phenylsulfonyl)amino]ethyl]--->Ethylenediamine-->Methanol-->Methylamine-->Ethyleneimine
[Preparation Products]

N-Methylhomopiperazine-->tert-Butyl 2-(methylamino)ethylcarbamate-->Divinyltetramethyldisiloxane-->N,N'-(Iminobisethylene)bismethanamine-->1-Methyl-2-imidazolidinethione-->N-Boc-N-methylethylenediamine-->N,N,N',N'-Tetramethylethylenediamine
Hazard InformationBack Directory
[Chemical Properties]

CLEAR COLOURLESS TO SLIGHTLY YELLOW LIQUID
[Uses]

N-Methylethylenediamine undergoes condensation with pyridine-2-carboxaldehyde to form an imine.
[General Description]

N-Methylethylenediamine undergoes condensation with pyridine-2-carboxaldehyde to form an imine. It reacts with isoquinoline-5-sulfonyl chloride to form N-(2-aminoethyl)-N-methyl-isoquinoline-5-sulfonamide.
Spectrum DetailBack Directory
[Spectrum Detail]

N-METHYLETHYLENEDIAMINE(109-81-9)MS
N-METHYLETHYLENEDIAMINE(109-81-9)1HNMR
N-METHYLETHYLENEDIAMINE(109-81-9)13CNMR
N-METHYLETHYLENEDIAMINE(109-81-9)IR1
N-METHYLETHYLENEDIAMINE(109-81-9)Raman
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

N-Methylethylenediamine, 95%(109-81-9)
[Alfa Aesar]

N-Methylethylenediamine, 95%(109-81-9)
[Sigma Aldrich]

109-81-9(sigmaaldrich)
[TCI AMERICA]

N-Methylethylenediamine,>95.0%(T)(109-81-9)
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