| Identification | Back Directory | [Name]
Chlorophyllin | [CAS]
11006-34-1 | [Synonyms]
CI 75810
SODIUM COPPER
CHLOROPHYLLIN
Chlorophylcopper
CHLOROPHYLLIN(P)
SODIUM CHLOROPHYLLIN
[sp-4-2-(2s-trans)]-
sodium-copperchlorine6
coppered trisodium salt
trisodium(2s-trans)-[18-
SodiuM copper chlorophyll
Coppersodiumchlorophyllate
chlorophyllin,trisodiumsalt
CHLOROPHYLLIN WATER SOLUBLE
Chlorophyllin sodiuM-Copper
TRISODIUMCOPPERCHLOROPHYLLINA
CHLOROPHYLLIN SODIUM-COPPER SALT
chlorophyllin,coppersodiumcomplex
potassiumsodiumcopperchlorophyllin
Chlorophyllin Copper Trisodium Salt
chlorinee6,copperderiv.,trisodiumsalt
CHLOROPHYLLIN, COPPERED, TRISODIUM SALT
COPPER (II) CHLOROPHYLIN, TRISODIUM SALT
CHLOROPHYLLIN COPPER COMPLEX, SODIUM SALT
,kappan24)-,trisodium,(sp-4-2-(2s-trans))-
CHLOROPHYLLIN-COPPER COMPLEX FOOD DYE E 141
CHLOROPHYLLIN SODIUM-COPPERCOMMERCIAL GR ADE
trisodium(2s-trans)-[18-carboxy-20-(carboxymethyl)-
chlorophyllin,potassium,sodium,andcoppermetallo-complex
Chlorophyllin sodium copper salt,Chlorophyllin, coppered trisodium salt
17-tetramethyl-21h,23h-porphine-2-propanoato(5-)-n21,n22,n23,n24]-1trisodiu
12,17-tetramethyl-21h,23h-porphine-2-propanoato(5-)-kappan21,kappan22,kappan23
cuprate(3-),(18-carboxy-20-(carboxymethyl)-8-ethenyl-13-ethyl-2,3-dihydro-3,7,
cuprate(3-),[18-carboxy-20-(carboxymethyl)-8-ethenyl-13-ethyl-2,3-dihydro-3,7,
[18-carboxy-20-(carboxymethyl)-8-ethenyl-13-ethyl-2,3-dihydro-3,7,12,17-tetramethyl-21H,23H-porphinCuprate
[18-carboxy-20-(carboxymethyl)-8-ethenyl-13-ethyl-2,3-dihydro-3,7,12,17-tetramethyl-21H,23H-porphinCuprate(3-)
trisodium(2s-trans)-[18-carboxy-20-(carboxymethyl)-13-ethyl-2,3-dihydro-3,7,12,17-tetramethyl-8-vinyl-21h,23h-porphine-2-propionato(5-)-n21,n22,n23,n24]cuprate(3-)
trisodium (2s-trans)-[18-carboxy-20-(carboxymethyl)-13-ethyl-2,3-dihydro-3,7,12,17-tetramethyl-8-vinyl-21h,23h-porphine-2-propionato(5-)-n21,n22,n23,n24]cuprate(3-)
Trisodium (SP-4-2)-[(7S,8S)-3-carboxy-5-(carboxymethyl)-13-ethenyl-18-ethyl-17-formyl-7,8-dihydro-2,8,12-trimethyl-21H,23H-porphine-7-propanoato(5-)-kN21,kN22,kN23,kN24]-cuprate(3-)
Cuprate(3-), [18-carboxy-20-(carboxymethyl)-8-ethenyl-13-ethyl-2,3-dihydro-3,7,12,17-tetramethyl-21H,23H-porphine-2-propanoato(5-)-N21,N22,N23,N24]-, trisodium, [SP-4-2-(2S-trans)]-
Cuprate(3-), [18-carboxy-20-(carboxymethyl) -8-ethenyl-13-ethyl-2,3-dihydro-3,7,12,17-tetramethyl -21H,23H-porphine-2-propanoato(5-)-N21 ,N22,N23,N24]-, trisodium, [SP-4-2-(2S-trans)]-
Cuprate(3-), (7S,8S)-3-carboxy-5-(carboxymethyl)-13-ethenyl-18-ethyl-7,8-dihydro-2,8,12,17-tetramethyl-21H,23H-porphine-7-propanoato(5-)-.kappa.N21,.kappa.N22,.kappa.N23,.kappa.N24-, trisodium, (SP-4-2)- | [EINECS(EC#)]
234-242-5 | [Molecular Formula]
C34H29CuN4Na3O6 | [MDL Number]
MFCD00012149 | [MOL File]
11006-34-1.mol | [Molecular Weight]
722.13 |
| Chemical Properties | Back Directory | [Melting point ]
>300°C | [storage temp. ]
2-8°C
| [solubility ]
DMSO (Slightly), Methanol (Very Slightly) | [form ]
Solid | [color ]
Dark Green to Black | [Water Solubility ]
Soluble in water. | [Exposure limits]
ACGIH: TWA 1 mg/m3
NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3 | [Major Application]
pharmaceutical | [Cosmetics Ingredients Functions]
COLORANT
DEODORANT
ANTIOXIDANT | [InChIKey]
IAHXXLVPAMICDP-FWRKSPLXNA-I | [SMILES]
C(C1=C2C(=C(C)C3=CC4C(CC)=C(C)C5=CC6=C(C=C)C(C)=C7C=C8[C@@H](C)[C@H](CCC(=O)[O-])C1=N8[Cu+2]([N-]67)(N=45)[N-]23)C(=O)[O-])C(=O)[O-].[Na+] |&1:25,27,r| | [LogP]
2.170 (est) | [EPA Substance Registry System]
Cuprate(3-), [(7S,8S)-3-carboxy-5-(carboxymethyl)- 13-ethenyl-18-ethyl-7,8-dihydro- 2,8,12,17-tetramethyl-21H, 23H-porphine-7-propanoato( 5-)-.kappa.N21,.kappa.N22,. kappa.N23,.kappa.N24]-, trisodium, (SP-4-2)-(11006-34-1) |
| Hazard Information | Back Directory | [Chemical Properties]
Dark green solid | [Uses]
Chlorophyllin, coppered trisodium salt is used in the spectrophotometric determination of Ven- lafaxine hydrochloride. A hybrid photoelectrochemical biofuel cell is composed of a TiO 2 film conductive glass electrode sensitized by a copper chlorophyll trisodium salt. Visible light-sensitive gels were prepared by introducing a chromophore (trisodium salt of copper chlorophyllin) to thermosensitive gels. | [Biological Activity]
Chlorophyllin is a water soluble derivative of chlorophyll. It has chemopreventive properties and forms a non-covalent complex with many mutagenic/carcinogenic molecules. The complex formation reduces absorption or allows excretion of the mutagenic/carcinogenic molecules. Chlorophyllin also exhibits antioxidantantiapoptotic and immunostimulatory effects. It provides benefitssuch as prevention of body odor and increased wound healing. | [Synthesis]
The silkworm sand or green tea leaves at 40 a 50 ℃ drying, research fine powder, add 3 times the amount of powder ethanol, acetone mixture ( 1:1 ) at 40 a 50 ℃ extraction 1.5h, filtration, filtrate residue with the same volume of ethanol, acetone mixtu |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H302-H315-H319-H335 | [Precautionary statements ]
P261-P305+P351+P338 | [Risk Statements ]
62 | [Safety Statements ]
22-24/25 | [WGK Germany ]
2
| [RTECS ]
GS2168866
| [TSCA ]
Yes | [HS Code ]
32129000 | [Storage Class]
11 - Combustible Solids | [Toxicity]
mouse,LD50,intraperitoneal,190mg/kg (190mg/kg),Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 43, Pg. 722, 1954. |
| Questions And Answer | Back Directory | [Description]
Chlorophyllin are a group of water-soluble salts being semi-synthetic derivative of chlorophyll. Its major form sodium/copper derivative can be used as a food additive and in alternative medicine. As alternative medicine, it can be used as an aid to reduce the odor of urines or feces (bowel movements). It can also be used to improve the life quality in people who have fecal incontinence due to spinal cord injury, bowel cancer, psychotic disorder, terminal illness, or other disorders. It can also be sold as an herbal supplement. Chlorophyllin can also bind to mutagenic substances such as polycyclic aromatic benzo[a]pyrene and dibenzo{a,i}pyrene. As a topical preparation, it is useful for both treatment and odor control of wounds, injuries, and other skin conditions such as radiation burns.
| [References]
https://en.wikipedia.org/wiki/Chlorophyllin
http://www.everydayhealth.com/drugs/chlorophyllin
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