| Identification | More | [Name]
2-Methyl-3-buten-2-ol | [CAS]
115-18-4 | [Synonyms]
1,1-DIMETHYLALLYL ALCOHOL
2-HYDROXY-2-METHYL-3-BUTENE
2-METHYL-3-BUTEN-2-OL
2-METHYL-3-BUTENE-2-OL
3-HYDROXY-3-METHYL-1-BUTENE
3-METHYL-1-BUTEN-3-OL
DIMETHYL VINYL CARBINOL
METHYL-3-BUTEN-2-OL, 2-
1,1-Dimethyl-2-propenol
1-Buten-3-ol, 3-methyl-
2-methyl but-3-ene-2-ol
2-methylbut-
2-methylbut-3-en
2-Methylbut-3-en-2-ol
3-Methyl-1-butene-3-ol
3-Methyl-buten-(1)-ol-(3)
alpha,alpha-Dimethylallyl alcohol
CH2=CHC(CH3)2OH
Dimethylvinylmethanol
Methylbutenol | [EINECS(EC#)]
204-068-4 | [Molecular Formula]
C5H10O | [MDL Number]
MFCD00004470 | [Molecular Weight]
86.13 | [MOL File]
115-18-4.mol |
| Chemical Properties | Back Directory | [Appearance]
clear colourless to very slightly yellow liquid | [Melting point ]
-43 °C | [Boiling point ]
98-99 °C (lit.) | [density ]
0.824 g/mL at 25 °C(lit.)
| [vapor pressure ]
51 mm Hg ( 25 °C)
| [refractive index ]
n20/D 1.416(lit.)
| [Fp ]
56 °F
| [storage temp. ]
Flammables area | [form ]
Liquid | [pka]
14.56±0.29(Predicted) | [color ]
Clear colorless to very slightly yellow | [Odor]
at 10.00 % in dipropylene glycol. herbal earthy oily | [PH]
9-10 (100g/l, H2O, 20℃) | [biological source]
synthetic | [explosive limit]
1.5-9.4%(V) | [Odor Type]
herbal | [BRN ]
1698263 | [Henry's Law Constant]
6.4×10-1 mol/(m3Pa) at 25℃, Iraci et al. (1999) | [Major Application]
flavors and fragrances | [Cosmetics Ingredients Functions]
PERFUMING | [InChI]
1S/C5H10O/c1-4-5(2,3)6/h4,6H,1H2,2-3H3 | [InChIKey]
HNVRRHSXBLFLIG-UHFFFAOYSA-N | [SMILES]
CC(C)(O)C=C | [LogP]
0.66 at 25℃ | [CAS DataBase Reference]
115-18-4(CAS DataBase Reference) | [NIST Chemistry Reference]
3-Buten-2-ol, 2-methyl-(115-18-4) | [EPA Substance Registry System]
115-18-4(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS02,GHS07 | [Signal word ]
Danger | [Hazard statements ]
H225-H302-H315-H319 | [Precautionary statements ]
P210-P301+P312+P330-P302+P352-P305+P351+P338 | [Hazard Codes ]
F,Xn,F++ | [Risk Statements ]
R11:Highly Flammable.
R22:Harmful if swallowed.
R36:Irritating to the eyes. | [Safety Statements ]
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [RIDADR ]
UN 1987 3/PG 2
| [WGK Germany ]
1
| [RTECS ]
EM9472000
| [Autoignition Temperature]
380 °C | [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29052990 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 2
Skin Irrit. 2 | [Toxicity]
LD50 orally in Rabbit: 1800 mg/kg |
| Hazard Information | Back Directory | [General Description]
Colorless liquid. | [Reactivity Profile]
An unsaturated aliphatic/alcohol. The unsaturated aliphatic hydrocarbons are generally much more reactive than the alkanes, which are saturated aliphatic hydrocarbons. Strong oxidizers may react vigorously with them. Reducing agents can react exothermically to release gaseous hydrogen. Flammable and/or toxic gases are generated by the combination of alcohols with alkali metals, nitrides, and strong reducing agents. They react with oxoacids and carboxylic acids to form esters plus water. Oxidizing agents convert them to aldehydes or ketones. Alcohols exhibit both weak acid and weak base behavior. They may initiate the polymerization of isocyanates and epoxides. | [Air & Water Reactions]
Slightly soluble in water. | [Health Hazard]
Harmful if inhaled or swallowed. Material is irritating to mucous membrane and upper respiratory tract. | [Fire Hazard]
Special Hazards of Combustion Products: Vapor may travel considerable distance to a source of ignition and flash back. | [Chemical Properties]
clear colourless to very slightly yellow liquid | [Uses]
2-Methyl-3-buten-2-ol may be used as an analytical reference standard for the determination of the analyte in Humulus Lupulus L. (Hop) and pine-mushroom extracts by chromatography techniques. | [Uses]
2-Methyl-3-buten-2-ol was used to study the kinetics of the gas-phase reaction of OH radicals with 3-methyl-2-butenal. | [Application]
This unsaturated alcohol has found a little
use in perfume compositions, mainly in the
reconstruction of Lavender and Lavandin oils,
etc.
It is occasionally used as a powerful additive in soap and detergent perfumes, but it
needs skilful blending and firm fixation in
order to control its odor to an acceptable level. | [Definition]
ChEBI: 3-hydroxy-3-methylbut-1-ene is a tertiary alcohol that is 3-methylbut-1-ene carrying a hydroxy substituent at position 3. It has a role as a fragrance, a pheromone, a plant metabolite and an animal metabolite. It is a tertiary alcohol and an olefinic compound. It derives from a hydride of a 3-methylbut-1-ene. | [Production Methods]
2-Methyl-3-buten-2-ol can be produced from Vinyl magnesium bromide and
Acetone by Grignard reaction. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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https://www.jkchemical.com |
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Alfa Aesar
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400-6106006 |
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http://chemicals.thermofisher.cn |
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Energy Chemical
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400-0056266 |
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www.energy-chemical.com |
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China Langchem Inc.
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0086-21-58956006 |
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www.chemicalbook.com/ShowSupplierProductsList19141/0_EN.htm |
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Maya High Purity Chemicals
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