ChemicalBook--->CAS DataBase List--->12014-56-1

12014-56-1

12014-56-1 Structure

12014-56-1 Structure
IdentificationMore
[Name]

Cerium tetrahydroxide
[CAS]

12014-56-1
[Synonyms]

CERIC HYDROXIDE
CERIC OXIDE HYDRATED
CERIUM HYDROXIDE
CERIUM (III) HYDROXIDE
CERIUM (IV) HYDROXIDE
CERIUM (IV) OXIDE HYDRATED
(beta-4)-ceriumhydroxide(ce(oh)4
(T-4)-Ceriumhydroxide
Cerium(IV)hydrate
Ceriumhydroxide,(T-4)-
ceriumperhydroxide
Ceriumhydroxidemin
cerium tetrahydroxide
Cerium(Ⅳ) hydroxide
CERIC HYDROXIDE REAGENT
Cerium(IV)hydroxide,min.85%
Cerium hydroxide (Ce(OH)4), (T-4)-
(beta-4)-cerium hydroxide
ceric hydroxide,cerium hydroxide
Cerium(IV) hydroxide, min. 85%
[EINECS(EC#)]

234-599-7
[Molecular Formula]

CeH4O4
[MDL Number]

MFCD00010927
[Molecular Weight]

208.15
[MOL File]

12014-56-1.mol
Chemical PropertiesBack Directory
[storage temp. ]

Inert atmosphere,Room Temperature
[solubility ]

insoluble in H2O; soluble in concentrated acid solutions
[form ]

Powder or Lump
[color ]

Yellow to pale brown
[Odor]

odorless
[Water Solubility ]

insoluble H2O; soluble conc mineral acids [HAW93]
[Solubility Product Constant (Ksp)]

pKsp: 47.7
[InChI]

InChI=1S/Ce.4H2O/h;4*1H2/q+4;;;;/p-4
[InChIKey]

WTVAYLQYAWAHAX-UHFFFAOYSA-J
[SMILES]

[Ce](O)(O)(O)O
[CAS DataBase Reference]

12014-56-1(CAS DataBase Reference)
[EPA Substance Registry System]

12014-56-1(EPA Substance)
Hazard InformationBack Directory
[Chemical Properties]

white powder(s); used to produce cerium salts, as an opacifier to impart a yellow color to glasses and enamels [HAW93]
[Characteristics]

Cerium hydroxide exists in two stable forms, namely cerium(III) hydroxide (Ce(OH)₃) and cerium(IV) hydroxide (Ce(OH)₄), which can be interconverted through changes in oxidation state. Cerium(III) hydroxide is a weak base; it is readily soluble in strong acids, forming cerium(III) salts, but insoluble in strong bases. Cerium(IV) hydroxide is amphoteric, with predominantly acidic character; it is soluble in both strong acids, forming cerium(IV) salts, and strong bases, forming cerates.
[Uses]

Cerium Hydroxide, also called Cerium Hydrate, is the important raw material for FCC catalyst, auto catalyst, polishing powder, special glass, and water treatment. Cerium is added to the dominant catalyst for the production of styrene from methylbenzene to improve styrene formation. It is used in FCC catalysts containing zeolites to provide both catalytic reactivity in the reactor and thermal stability in the regenerator.
[Preparation]

Cerium (IV) hydroxide was prepared by the precipitation of cerium (IV) from an aqueous solution of armonium hexenitratocerate (IV) with aqueous ammonia.
[reaction suitability]

reagent type: catalyst
core: cerium
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Warning
[Hazard statements ]

H314-H318
[Precautionary statements ]

P260h-P301+P330+P331-P303+P361+P353-P305+P351+P338-P405-P501a
[Hazard Codes ]

Xi
[Risk Statements ]

R36:Irritating to the eyes.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[RIDADR ]

3262
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

28461020
[Storage Class]

11 - Combustible Solids
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Potassium permanganate-->Extractant-->rare earth element ore: rare earth metal ore
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Cerium(IV) oxide, hydrated(12014-56-1)
[Sigma Aldrich]

12014-56-1(sigmaaldrich)
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