| Identification | More | [Name]
Zirconium hydroxide | [CAS]
14475-63-9 | [Synonyms]
ZIRCONIUM HYDROXIDE
ZIRCONIUM(IV) HYDROXIDE
zirconiumhydroxide(zr(oh)4)
zirconium tetrahydroxide
ZIRCONIUM HYDROXIDE X H2O
ZRICONIUM HYDROXIDE
XZO-632/03
Zirconic acid
Zirconium(IV)tetrahydoxide | [EINECS(EC#)]
238-472-7 | [Molecular Formula]
H4O4Zr | [MDL Number]
MFCD00049635 | [Molecular Weight]
159.25 | [MOL File]
14475-63-9.mol |
| Chemical Properties | Back Directory | [Appearance]
White, bulky, amorphous powder.Decomposes to ZrO2 at 550C. Soluble in dilute
mineral acids; insoluble in water and alkalies. | [density ]
3.25 | [solubility ]
insoluble in H2O; soluble in acid solutions | [form ]
white amorphous powder | [color ]
white | [Water Solubility ]
insoluble H2O and alkalies; soluble mineral acids [MER06] [HAW93] | [Merck ]
13,10230 | [InChI]
InChI=1S/4H2O.Zr/h4*1H2;/q;;;;+4/p-4 | [InChIKey]
HAIMOVORXAUUQK-UHFFFAOYSA-J | [SMILES]
[Zr](O)(O)(O)O | [CAS DataBase Reference]
14475-63-9(CAS DataBase Reference) | [EPA Substance Registry System]
14475-63-9(EPA Substance) |
| Hazard Information | Back Directory | [Chemical Properties]
White, bulky, amorphous powder.Decomposes to ZrO2 at 550C. Soluble in dilute
mineral acids; insoluble in water and alkalies. | [Description]
Zirconium hydroxide, often called hydrous zirconia is a water-insoluble, slightly alkaline amphoteric oxide, which is widely used in the preparation of pigments, glass, dyes and other industries, and is also an important intermediate for the preparation of other zirconium compounds. | [Physical properties]
White, bulky amorphous powder; density 3.25 g/cm3; decomposes to oxide at about 500°C; very slightly soluble in water, about 200 mg/L at 20°C; soluble in mineral acids. | [Uses]
Zirconium hydroxide is used in the pigment, dye, and glass colorants. The compound also is used to prepare zirconium oxide, sulfate, phosphate, and other salts. | [Preparation]
Zirconium hydride precipitates on adding sodium hydroxide solution to an aqueous solution of zirconium salt:
ZrCl4 (aq)+ 4NaOH(aq) → Zr(OH)4 (s) + 4NaCl(aq) | [Reactions]
When heated at 550°C the hydroxide decomposes to oxide:
Zr(OH)4 → ZrO2 + 2H2O
Reacitons with mineral acids followed by crystallization forms corresponding zirconium salts. Thus hydrochloric, sulfuric, and phosphoric acids yield chloride, sulfate and phosphate of zirconium respectively. | [Properties and Applications]
Zirconium Hydroxide is a highly water insoluble crystalline Zirconium source for uses compatible with higher (basic) pH environments. |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing . | [WGK Germany ]
3 | [TSCA ]
TSCA listed | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
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