| Identification | More | [Name]
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine | [CAS]
128249-70-7 | [Synonyms]
(+)-2,6-BIS[(4R)-4-PHENYL-2-OXAZOLIN-2-YL]PYRIDINE
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine
2,6-BIS[(4R)-PHENYL-2-(OXAZOLIN-2-YL)]PYRIDINE
(R,R)-2,2'-(2,6-PYRIDINEDIYL)BIS(4-PHENYL-2-OXAZOLINE)
(R,R)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine
(R,R)-2,6-BIS(4-PHENYL-2-OXAZOLIN-2-YL)PYRIDINE
(r,r)-2,6-bis(4-phenyl-2-oxazolinyl)pyridine
[R-(R,R)]-2,6-BIS(4,5-DIHYDRO-4-PHENYL-2-OXAZOLYL)PYRIDINE
(R-(R*,R*))-2,6-bis(4,5-dihydro-4-phenyl-2-oxazol
(R-(R*,R*))-2,6-BIS(4,5-DIHYDRO-4-PHENY&
(+)-2,6-Bis[(4R)-4-phenyl-2-oxazolin-2-yl]pyridine,98+%
(+)-2,6-Bis[(4R)-4-phenyl-2-oxazolin-2-yl]pyridine
(R,R)-2,6-Bis(4-phenyl-2-oxazolinyl)pyridine, (R,R)-2,6-Bis(4,5-dihydro-4-phenyl-2-oxazolyl)pyridine | [Molecular Formula]
C23H19N3O2 | [MDL Number]
MFCD01863585 | [Molecular Weight]
369.42 | [MOL File]
128249-70-7.mol |
| Chemical Properties | Back Directory | [Appearance]
White needles | [Melting point ]
171-175 °C(lit.) | [alpha ]
185 º (c=1, methylene chloride) | [Boiling point ]
600.4±55.0 °C(Predicted) | [density ]
1.28±0.1 g/cm3(Predicted) | [storage temp. ]
Refrigerator | [form ]
crystal | [pka]
3.07±0.70(Predicted) | [color ]
white | [Optical Rotation]
[α]22/D 187°, c = 1 in methylene chloride | [Water Solubility ]
Insoluble | [InChI]
InChI=1S/C23H19N3O2/c1-3-8-16(9-4-1)20-14-27-22(25-20)18-12-7-13-19(24-18)23-26-21(15-28-23)17-10-5-2-6-11-17/h1-13,20-21H,14-15H2/t20-,21-/m0/s1 | [InChIKey]
HLHBIMJNCKZZQO-SFTDATJTSA-N | [SMILES]
C1(C2=N[C@H](C3=CC=CC=C3)CO2)=NC(C2=N[C@H](C3=CC=CC=C3)CO2)=CC=C1 | [CAS DataBase Reference]
128249-70-7(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [WGK Germany ]
3
| [HS Code ]
29339900 | [Storage Class]
11 - Combustible Solids | [Hazard Classifications]
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3 |
| Hazard Information | Back Directory | [Chemical Properties]
White needles | [Uses]
2,6-Bis[(4R)-4-phenyl-2-oxazolinyl]pyridine [Pybox] may be used as a chiral ligand in the copper-catalyzed enatioselective arylation of N-arylated tetrahydroisoquinolines (THIQs) with arylboronic acids in the presence of a photoredox catalyst. |
| Questions And Answer | Back Directory | [Reactions]
- Ligand for Copper catalyzed syn-selective Mukaiyama aldol reaction.
- Ligand for Tin catalyzed anti-selective aldol reaction.
- Ligand for Ytterbuim catalyzed desymmetrization of meso epoxides.
- Ligand for Copper catalyzed enantioselective addition of terminal alkynes to imines.
- Ligand for Scandium catalyzed enantioselective syn-selective ene reactions.
- Ligand for Copper catalysed asymmetric alkynylation of cyclic azomethine Imines.
- Ligand for Europium catalyzed asymmetric alpha amination.
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| Company Name: |
LaaJoo Gold
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021-60702684 18516024827 |
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www.chemicalbook.com/ShowSupplierProductsList20079/0_EN.htm |
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J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Energy Chemical
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400-0056266 |
| Website: |
www.energy-chemical.com |
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