ChemicalBook--->CAS DataBase List--->13057-17-5

13057-17-5

13057-17-5 Structure

13057-17-5 Structure
IdentificationMore
[Name]

Bromomethyl methyl ether
[CAS]

13057-17-5
[Synonyms]

BROMOMETHYL METHYL ETHER
METHOXYMETHYL BROMIDE
Bromo(methoxy)methane
bromomethoxy-methan
Ether, bromomethyl methyl
Methane, bromomethoxy-
BROMOMETHYL METHYL ETHER, TECH., 90%
BMME~Methoxymethylbromide
Methoxybromomethane
Methyl(bromomethyl) ether
[Molecular Formula]

C2H5BrO
[MDL Number]

MFCD00000171
[Molecular Weight]

124.96
[MOL File]

13057-17-5.mol
Chemical PropertiesBack Directory
[Boiling point ]

87 °C (lit.)
[density ]

1.531 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.456(lit.)
[Fp ]

80 °F
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Soluble), Methanol (Slightly)
[form ]

clear liquid
[color ]

Colorless to Light yellow to Light orange
[Specific Gravity]

1.531
[Water Solubility ]

Sparingly soluble in water.
[Sensitive ]

Moisture Sensitive
[BRN ]

1730853
[InChI]

1S/C2H5BrO/c1-4-2-3/h2H2,1H3
[InChIKey]

JAMFGQBENKSWOF-UHFFFAOYSA-N
[SMILES]

COCBr
[CAS DataBase Reference]

13057-17-5(CAS DataBase Reference)
[NIST Chemistry Reference]

Bromomethyl methyl ether(13057-17-5)
[EPA Substance Registry System]

13057-17-5(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS02,GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H226-H312+H332-H315-H319-H335-H351
[Precautionary statements ]

P210-P280-P303+P361+P353-P304+P340+P312-P305+P351+P338-P308+P313
[Hazard Codes ]

Xn
[Risk Statements ]

R10:Flammable.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R40:Limited evidence of a carcinogenic effect.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37:Wear suitable protective clothing and gloves .
[RIDADR ]

UN 1992 3/PG 3
[WGK Germany ]

3
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29091990
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Dermal
Carc. 2
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Chemical Properties]

Colorless liquid
[Uses]

Bromomethyl methyl ether is used as reagent for protection of OH groups as their methoxymethyl (MOM) ethers. It is used in enantiocontrolled synthesis of intermediate containing carbons 18 to 35 of the macrocyclic immunosuppressant FK-506. It was used in the synthesis of 1-methoxymethyl-4-tritylthio-2-azetidinone.
[storage]

Bromomethyl Methyl Ether (BMME) is a lachrymator, possible carcinogen, handle with care. Extremely destructive to tissue of mucous membranes, eyes, and skin. Wear respirator, chemical-resistant gloves, and safety goggles.
Spectrum DetailBack Directory
[Spectrum Detail]

Bromomethyl methyl ether(13057-17-5)1HNMR
Bromomethyl methyl ether(13057-17-5)IR
Bromomethyl methyl ether(13057-17-5)Raman
Bromomethyl methyl ether(13057-17-5)FT-IR
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bromomethyl methyl ether, tech. 90%(13057-17-5)
[Sigma Aldrich]

13057-17-5(sigmaaldrich)
[TCI AMERICA]

Bromomethyl Methyl Ether,>95.0%(GC)(13057-17-5)
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