ChemicalBook--->CAS DataBase List--->1314-28-9

1314-28-9

1314-28-9 Structure

1314-28-9 Structure
IdentificationBack Directory
[Name]

RHENIUM (VI) OXIDE
[CAS]

1314-28-9
[Synonyms]

ReO3
rioxorhenium
trioxorhenium
triketorhenium
RHENIUMM OXIDE
RHENIUM TRIOXIDE
RHENIUM (VI) OXIDE
Rhenium oxide (ReO3)
Rhenium(VI) trioxide
RHENIUM(VI) OXIDE: 99.9%
Rhenium(VI)oxide(99.9%-Re)
Rhenium(VI) oxide, 99.9% (metals basis)
Rhenium(VI) oxide, 99.9% trace metals basis
[EINECS(EC#)]

215-228-8
[Molecular Formula]

O3Re
[MDL Number]

MFCD00016306
[MOL File]

1314-28-9.mol
[Molecular Weight]

234.21
Chemical PropertiesBack Directory
[Melting point ]

400°C (dec.)
[Boiling point ]

400°C
[density ]

6.9-7.4
[Fp ]

400°C
[solubility ]

insoluble in H2O, acid solutions, alkaline solutions
[form ]

Powder
[color ]

Violet
[Water Solubility ]

Insoluble in water.
[Crystal Structure]

ReO3 type
[Sensitive ]

Moisture Sensitive
[crystal system]

Cube
[Merck ]

14,8180
[Space group]

Pm3m
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.37430.37430.37439090900.0524
[InChI]

1S/3O.Re
[InChIKey]

YSZJKUDBYALHQE-UHFFFAOYSA-N
[SMILES]

O=[Re](=O)=O
[EPA Substance Registry System]

Rhenium oxide (ReO3) (1314-28-9)
Hazard InformationBack Directory
[Chemical Properties]

-100mesh with 99.95% purity; red cub crystal(s); green luster imparted by transmitted light; disproportionates in vacuum to Re2O7 and ReO2 [MER06] [CER91]
[Uses]

Rhenium(VI) oxide is involved as a catalyst for the hydrogenation of carboxylic acids and carboxamides. It is involved in the alkene epoxidation reactions.
[Synthesis]

Rhenium trioxide can not be prepared directly from the elements, can be produced by CO at 300 ℃ reduction of dirhenium heptaoxide:

Re2O7 + CO → 2 ReO3 + CO2

[Toxics Screening Level]

The ITSL for rhenium oxide is 0.1 μg/m3 based on an annual averaging time.
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37
[Safety Statements ]

22-26-37/39
[WGK Germany ]

3
[TSCA ]

Yes
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
STOT SE 3
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