ChemicalBook--->CAS DataBase List--->12064-62-9

12064-62-9

12064-62-9 Structure

12064-62-9 Structure
IdentificationMore
[Name]

Gadolinium oxide
[CAS]

12064-62-9
[Synonyms]

GADOLINIUM(III) OXIDE
GADOLINIUM OXIDE
GADOLIUM OXIDE
digadoliniumtrioxide
gadolinia
gadolinium(3+)oxide
gadoliniumoxide(gd2o3)
gadoliniumsesquioxide
gadoliniumtrioxide
Gadolinium(III) oxide, 99.9% metals basis
GADOLINIUM(III) OXIDE, NANOPARTICLES, 9&
GADOLINIUM(III) OXIDE, NANPOWDER, <25NM, 99.9+%
GADOLINIUM(III) OXIDE, 99.99+%
GADOLINIUM(III) OXIDE, 99.999% (REO)
GADOLINIUM(III) OXIDE, OPTICAL WINDOW, 1-5MM, 99.9%, 1.8NM '550, 320-15000NM
GADOLINIUM(III) OXIDE, (99.99%-GD) WAFER
GADOLINIUM(III) OXIDE, (99.99%-GD) SPUTTERING TARGET
GADOLINIUM(III) OXIDE, (99.9%-GD) 20-80NM NANOMPOWDER
GADOLINIUM(III) OXIDE, 99.99+% (REO)
GADOLINIUM(III) OXIDE, 99.9+% (REO)
[EINECS(EC#)]

235-060-9
[Molecular Formula]

Gd2O3
[MDL Number]

MFCD00011026
[Molecular Weight]

362.5
[MOL File]

12064-62-9.mol
Chemical PropertiesBack Directory
[Appearance]

white powder
[Melting point ]

2330 °C(lit.)
[density ]

7.407 g/mL at 20 °C(lit.)
[storage temp. ]

no restrictions.
[solubility ]

Aqueous Acid (Slightly)
[form ]

nanopowder
[color ]

White
[Specific Gravity]

7.407
[Water Solubility ]

insoluble
[Specific Heat Capacity]

Cp(crystal):0.294345J/(g·K),at 25℃
[Thermal Conductivity]

10.042 W/(m·K)
[Crystal Structure]

Cubic
[crystal system]

Monoclinic
[Merck ]

14,4326
[Space group]

C2/m
[Lattice constant]

a/nmb/nmc/nmα/oβ/oγ/oV/nm3
1.4080.35710.876490100.03900.4339
[InChI]

1S/2Gd.3O
[InChIKey]

RNYFGGMJZRTZKO-UHFFFAOYSA-N
[SMILES]

O=[Gd]O[Gd]=O
[Uses]

Neutron shields; catalysts; dielectric ceramics; filament coatings; special glasses; TV phosphor activator; lasers, masers, and telecommunication; laboratory reagent.
[CAS DataBase Reference]

12064-62-9(CAS DataBase Reference)
[EPA Substance Registry System]

12064-62-9(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H319
[Precautionary statements ]

P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

R36:Irritating to the eyes.
[Safety Statements ]

S39:Wear eye/face protection .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
[WGK Germany ]

1
[RTECS ]

LW4790000
[TSCA ]

Yes
[REACH Registrations]

Active
[HS Code ]

28469019
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
[Toxicity]

LD50 orally in Rabbit: > 5000 mg/kg
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Rare earth chlorides-->monazite-->MISCH METAL-->NEODYMIUM-->SAMARIUM-->rare earth element ore: rare earth metal ore-->GADOLINIUM-->EUROPIUM CHLORIDE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Digadolinium trioxide(12064-62-9).msds
Questions And AnswerBack Directory
[Description]

Gadolinium oxide (Gd2O3) is an inorganic compound and is one of the most commonly available forms of the rare earth element gadolinium, whose derivative can be used as an injectable contrast agent when complexed with EDTA ligands, for patients undergoing magnetic resonance imaging (MRI) as an enhancer of the scan clarity. It is also applied as a raw material for various fluorescent compounds, absorption material in atomic reactions, nuclear fuels, magnetic bubble material and screen-sensitivity increasing material. 
Besides, as a highly insoluble thermally stable gadolinium source, gadolinium oxide is a suitable component for manufacturing glass, optic, ceramic, filament coatings. It can also used in electronic industry for lasers, masers and telecommunication and as a reaction control agent used in nuclear fuel pellets of rods to limit reactivity and enable longer fuel life. Gadolinium oxide is used in control rods for neutron shielding in nuclear power reactors.The compound also is used as a catalyst.
[Uses]

Gadolinium Oxide, also called Gadolinia, is used for making optical glass and Gadolinium Yttrium Garnets which have microwave applications. High purity of Gadolinium Oxide is used for making phosphors for colour TV tube. Cerium Oxide (in the form of Gadolinium doped ceria) creates an electrolyte with both high ionic conductivity and low operating temperatures that are optimal for cost-effective production of fuel cells. It is one of the most commonly available forms of the rare earth element Gadolinium, derivatives of which are potential contrast agents for magnetic resonance imaging.
[References]

https://en.wikipedia.org/wiki/Gadolinium(III)_oxide
https://www.americanelements.com/gadolinium-oxide-12064-62-9
https://www.alfa.com/zh-cn/catalog/011291/
http://www.solvay.com/en/markets-and-products/featured-products/gadolinium-oxides.html
Hazard InformationBack Directory
[Chemical Properties]

white powder
[Flammability and Explosibility]

Notclassified
[reaction suitability]

reagent type: catalyst
core: gadolinium
Spectrum DetailBack Directory
[Spectrum Detail]

Gadolinium oxide(12064-62-9)IR1
Well-known Reagent Company Product InformationBack Directory
[Acros Organics]

Gadolinium(III) oxide, 99.90%(12064-62-9)
[Alfa Aesar]

Gadolinium(III) oxide, REacton, 99.999% (REO)(12064-62-9)
[Sigma Aldrich]

12064-62-9(sigmaaldrich)
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