| Identification | More | [Name]
Chlorotripyrrolidinophosphonium hexafluorophosphate | [CAS]
133894-48-1 | [Synonyms]
CHLOROTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE
PYCLOP
Chlorotripyrrolidinophosphoniumhexafluorophosphat
PYCLOP CHLOROTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE
PYCIOP | [EINECS(EC#)]
628-539-2 | [Molecular Formula]
C12H24ClF6N3P2 | [MDL Number]
MFCD00210035 | [Molecular Weight]
421.73 | [MOL File]
133894-48-1.mol |
| Chemical Properties | Back Directory | [Melting point ]
145-148°C | [storage temp. ]
2-8°C
| [solubility ]
soluble in Chloroform, Methanol | [form ]
Crystalline Powder | [color ]
White to yellow | [Sensitive ]
Moisture Sensitive | [BRN ]
6842341 | [InChI]
InChI=1S/C12H24ClN3P.F6P/c13-17(14-7-1-2-8-14,15-9-3-4-10-15)16-11-5-6-12-16;1-7(2,3,4,5)6/h1-12H2;/q+1;-1 | [InChIKey]
BSCYRXJVGSZNKX-UHFFFAOYSA-N | [SMILES]
[P+5]([F-])([F-])([F-])([F-])([F-])[F-].[P+](N1CCCC1)(N1CCCC1)(N1CCCC1)Cl | [CAS DataBase Reference]
133894-48-1(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
Xi,C | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin .
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection . | [RIDADR ]
UN 1759 8/PG 2
| [WGK Germany ]
3
| [F ]
10-21 | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29339900 |
| Hazard Information | Back Directory | [Uses]
Reagent for:
Peptide coupling reactions and synthesis of coupling reagents
Sequence selective peptide recognition
Synthesis of condensing reagents
Synthesis of heterocyclic β-sheet ligands | [Uses]
Celltransmission 20, 2, 2004. | [Uses]
Crystalline reagent for peptide coupling of a-alkylated N-Fmoc and N-Z-amino acids in high yield and without racemization. | [Preparation]
Preparation of chlorotripyrrolidinophosphonium hexafluorophosphate: addition of chlorine to a diethyl ether solution of tripyrrolidinophosphine, then addition of KPF6 in water. Addition of tripyrrolidinophosphine oxide to a DCM solution of phosphoryl trichloride, then addition of KPF6 in water. | [reaction suitability]
reaction type: Coupling Reactions |
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