| Identification | More | [Name]
BIS(DIETHYLAMINO)CHLOROPHOSPHINE | [CAS]
685-83-6 | [Synonyms]
AURORA KA-1225
BIS(DIETHYLAMINO)CHLOROPHOSPHINE
Bis-(diethylamino)-chlorphosphin
bis(diethylamino)phosphorochloridite
tetraethyldiamidophosphorousacidchloride
tetraethylphosphorodiamidouschloride
Bis(diethylamino)chlorophosphine,min.97%
chlorobis(diethylamino)phosphine
bis(diethylamino)phosphorchloridite
Bis(diethylamino)chlorophosphine, min. 97%
N,N,N',N'-Tetraethylphosphorodiamidous chloride | [Molecular Formula]
C8H20ClN2P | [MDL Number]
MFCD00015493 | [Molecular Weight]
210.68 | [MOL File]
685-83-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Colorless to light yellow liqui | [Boiling point ]
55-57 °C0.2 mm Hg(lit.) | [density ]
1.002 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.4895(lit.)
| [Fp ]
214 °F
| [solubility ]
Chloroform (Sparingly) | [form ]
Liquid | [pka]
3.96±0.70(Predicted) | [color ]
Clear colorless to light yellow | [Sensitive ]
Air & Moisture Sensitive | [Stability:]
Hygroscopic, Moisture Sensitive | [InChI]
InChI=1S/C8H20ClN2P/c1-5-10(6-2)12(9)11(7-3)8-4/h5-8H2,1-4H3 | [InChIKey]
JVEHJSIFWIIFHM-UHFFFAOYSA-N | [SMILES]
P(N(CC)CC)(N(CC)CC)Cl | [CAS DataBase Reference]
685-83-6(CAS DataBase Reference) |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R14:Reacts violently with water.
R34:Causes burns. | [Safety Statements ]
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29299090 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Eye Dam. 1
Skin Corr. 1B |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Hexane-->Phosphorus trichloride-->Diethylamine-->2-[(1,3-dioxo-1,3-dihydro-2H-isoindol-2-yl)methyl]-1H-isoindole-1,3(2H)-dione-->1,3,2-Oxathiaphosphole, 2-chloro-5-methyl--->Bis(diethylamino)-tert-butoxyphosphine-->1,3,2-Oxazaphospholidine, 2-chloro-3-phenyl--->N-(Chloromethyl)phthalimide-->Trimethylphosphine-->Diethylphosphoramidous dichloride-->Diethylamine hydrochloride | [Preparation Products]
Tris(diethylamino)phosphine-->Propane, 1-[(trichloromethyl)thio]--->Ethane, [(trichloromethyl)thio]--->P,P′-(9,9-Dimethyl-9H-xanthene-4,5-diyl)bis[N,N,N′,N′-tetraethyl-phosphonous diamide] 97%-->Bis(diethylamino)[(diphenylphosphino)ethynyl]phosphine |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
Bis(diethylamino)??chlorophosphine is an intermediate in synthesizing Toldimfos Sodium (T535270), a cattle drug that can be used to investigate the bovine serum paraoxonase 1 (PON1) activity. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling |
|
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Infinity SCI Gold
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400-106-2016 17800804092 |
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http://www.infsci.com |
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J & K SCIENTIFIC LTD.
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Alfa Aesar
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Energy Chemical
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Maya High Purity Chemicals
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Sigma-Aldrich
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021-61415566 800-8193336 |
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https://www.sigmaaldrich.cn |
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