| Identification | More | [Name]
(1S)-(-)-Camphanic acid | [CAS]
13429-83-9 | [Synonyms]
(1R)-(-)-CAMPHANIC ACID
(1S)-3-OXO-4,7,7-TRIMETHYL-2-OXABICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID
(1S)-(-)-CAMPHANIC ACID
4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
(-)-CAMPHANIC ACID
CAMPHANIC ACID
(S)-(-)-1-CAMPHANIC ACID
(−
)-Camphanic acid
(1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
4,7,7-trimethyl(2-oxabicyclo[2.2.1]hept-1-yl)carboxylic acid
(1S)-(-)-OMEGA-Camphanic acid
2-Oxabicyclo2.2.1heptane-1-carboxylic acid, 4,7,7-trimethyl-3-oxo-, (1S,4R)-
(IS) CAMPHANIC ACID
(-)-CAMPHANIC ACID 98+%
(-)-Camphanic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
(1S)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
1,7,7-Trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carboxylic acid
(1S,4R)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
(1S,4R)-4,7,7-Trimethyl-3-oxo-2-oxabicyclo[2.2.1]heptane-1-carboxylic acid
(3R,6S)-2-Oxo-3β,6β-isopropylidene-3-methyltetrahydro-2H-pyran-6-carboxylic acid | [EINECS(EC#)]
236-552-6 | [Molecular Formula]
C10H14O4 | [MDL Number]
MFCD00044948 | [Molecular Weight]
198.22 | [MOL File]
13429-83-9.mol |
| Chemical Properties | Back Directory | [Appearance]
WHITE TO SLIGHTLY BEIGE CRYSTALLINE POWDER | [Melting point ]
201-205 °C
| [alpha ]
-18.5 º (c=1, dioxane) | [Boiling point ]
255.53°C (rough estimate) | [density ]
1.0143 (rough estimate) | [refractive index ]
1.4500 (estimate) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
powder to crystaline | [pka]
3.36±0.60(Predicted) | [color ]
White to Almost white | [Optical Rotation]
[α]20/D 18°, c = 1 in dioxane | [BRN ]
84570 | [InChI]
InChI=1S/C10H14O4/c1-8(2)9(3)4-5-10(8,6(11)12)14-7(9)13/h4-5H2,1-3H3,(H,11,12)/t9-,10+/m0/s1 | [InChIKey]
RKFCLVFAFZYVCG-WDEREUQCSA-N | [SMILES]
[C@@]12(C(O)=O)C(C)(C)[C@@](C)(CC1)C(=O)O2 | [CAS DataBase Reference]
13429-83-9(CAS DataBase Reference) |
| Hazard Information | Back Directory | [Chemical Properties]
WHITE TO SLIGHTLY BEIGE CRYSTALLINE POWDER | [Uses]
(1S)-(-)-Camphanic acid may be used in the preparation of (-)-(1S,4R)-camphanoyl chloride by reacting with thionyl chloride. | [Definition]
ChEBI: (-)-camphanic acid is a delta-lactone. | [General Description]
(1S)-(-)-Camphanic acid is commonly used as a chiral auxiliary for the separation of racemates. | [Purification Methods]
Dissolve it in CH2Cl2, dry (MgSO4), filter, evaporate and the residue is sublimed at 120o/0.5mm or 140o/1mm. [Gerlach Helv Chim Acta 61 2773 1978, Beilstein 18/8 V 101.] |
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