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135-77-3

135-77-3 Structure

135-77-3 Structure
IdentificationMore
[Name]

1,2,4-Trimethoxybenzene
[CAS]

135-77-3
[Synonyms]

1,2,4-TRIMETHOXYBENZENE
HYDROXYHYDROQUINONE TRIMETHYL ETHER
1,2,4-trimethoxy-benzen
Benzene, 1,2,4-trimethoxy-
1.2.4-Trimethoxy benzone
1,2,4-Benzenetriol trimethyl ether
TMB 124
1,4,5-Trimethoxybenzene
[EINECS(EC#)]

205-219-7
[Molecular Formula]

C9H12O3
[MDL Number]

MFCD00008360
[Molecular Weight]

168.19
[MOL File]

135-77-3.mol
Chemical PropertiesBack Directory
[Appearance]

clear light yellow to yellow-brown liquid
[Boiling point ]

247 °C(lit.)
[bp ]

247 °C(lit.)
[density ]

1.126 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.533(lit.)
[Fp ]

>230 °F
[storage temp. ]

Sealed in dry,Room Temperature
[Water Solubility ]

Not miscible in water.
[Merck ]

14,1073
[BRN ]

2047579
[CAS DataBase Reference]

135-77-3(CAS DataBase Reference)
[NIST Chemistry Reference]

1,2,4-Trimethoxybenzene(135-77-3)
[EPA Substance Registry System]

135-77-3(EPA Substance)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Safety Statements ]

S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) .
S24/25:Avoid contact with skin and eyes .
[WGK Germany ]

3
[RTECS ]

DC2770000
[Hazard Note ]

Irritant
[TSCA ]

Yes
[HS Code ]

29093090
Raw materials And Preparation ProductsBack Directory
【Raw materials】

Hydrogen peroxide-->Dimethyl sulfate-->Sodium dichromate dihydrate-->Hydroquinone-->Vanillin-->1,2,4-Triacetoxybenzene
【Preparation Products】

2,4,5-Trimethoxynitrobenzene -->BENZENE,1,2,4-TRIMETHOXY-5-(2-PROPENYL)--->METHOXYBENZOQUINONE
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

1,2,4-Trimethoxybenzene (135-77-3).msds
Hazard InformationBack Directory
[Chemical Properties]

clear light yellow to yellow-brown liquid
[Uses]

1,2,4-Trimethoxybenzene is used as a reagent in the synthesis of barbigerone derivatives which can be used as antiproliferative and antiangiogenesis agents. Also used as a reagent in the synthesis of Malvone A (M161525) which is a phytoalexin found in Malva sylvestris.
Spectrum DetailBack Directory
[Spectrum Detail]

1,2,4-Trimethoxybenzene(135-77-3)MS
1,2,4-Trimethoxybenzene(135-77-3)1HNMR
1,2,4-Trimethoxybenzene(135-77-3)13CNMR
1,2,4-Trimethoxybenzene(135-77-3)IR1
1,2,4-Trimethoxybenzene(135-77-3)Raman
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

1,2,4-Trimethoxybenzene, 98%(135-77-3)
[Sigma Aldrich]

135-77-3(sigmaaldrich)
[TCI AMERICA]

1,2,4-Trimethoxybenzene,>97.0%(GC)(135-77-3)
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