ChemicalBook--->CAS DataBase List--->13674-87-8

13674-87-8

13674-87-8 Structure

13674-87-8 Structure
IdentificationMore
[Name]

Fyrol FR 2
[CAS]

13674-87-8
[Synonyms]

Fyrol FR 2
pf 38
PHOSPHORIC ACID TRIS(1,3-DICHLORO-2-PROPYL) ESTER
tri(beta,beta'-dichloroisopropyl)phosphate
TRIS(1,3-DICHLORO-2-PROPYL) PHOSPHATE
TRIS(1,3-DICHLOROISOPROPYL)PHOSPHATE
tris(1-chloromethyl-2-chloroethyl)phosphate
TRIS[2-CHLORO-1-(CHLOROMETHYL)ETHYL]PHOSPHATE
TRIS(BETA,BETA'-DICHLOROISOPROPYL) PHOSPHATE
1,3-Dichloro-2-propanol phosphate (3:1)
1,3-dichloro-2-propanolphosphate(3:1)
1,3-dichloro-2-propanophosphate(3:1)
2-Propanol, 1,3-dichloro-, phosphate (3:1)
2-propanol,1,3-dichloro,phosphate(3:1)
2-Propanol,1,3-dichloro-,phosphate(3:1)
crp(fireproofingagent)
Emulsion 212
emulsion212
Fosforan troj-(1,3-dwuchloroizopropylowy)
fosforantroj-(1,3-dwuchloroizopropylowy)
[EINECS(EC#)]

237-159-2
[Molecular Formula]

C9H15Cl6O4P
[MDL Number]

MFCD00083121
[Molecular Weight]

430.9
[MOL File]

13674-87-8.mol
Chemical PropertiesBack Directory
[Appearance]

colourless viscous liquid
[Melting point ]

-64°C
[Boiling point ]

315°C
[density ]

1.512
[vapor pressure ]

0Pa at 25℃
[refractive index ]

n20/D 1.503
[Fp ]

249°C
[storage temp. ]

Store at -20°C
[solubility ]

Chloroform, Ethyl Acetate (Slightly), Methanol (Slightly)
[form ]

solid
[color ]

Colorless to Almost colorless
[Specific Gravity]

1.518 (20/4℃)
[Stability:]

Stable. Reacts slowly with aqueous acids and alkalies. May soften plastics.
[Water Solubility ]

<0.1 g/100 mL at 24 ºC
[Decomposition ]

240-280 ºC
[Merck ]

9087
[Henry's Law Constant]

3.8×103 mol/(m3Pa) at 25℃, HSDB (2015)
[InChIKey]

ASLWPAWFJZFCKF-UHFFFAOYSA-N
[LogP]

3.69 at 20℃
[CAS DataBase Reference]

13674-87-8(CAS DataBase Reference)
[NIST Chemistry Reference]

Tris(1,3-dichloroisopropyl)phosphate(13674-87-8)
[EPA Substance Registry System]

13674-87-8(EPA Substance)
Safety DataBack Directory
[Symbol(GHS) ]

Health Hazard (GHS08)Environment (GHS09)
GHS08,GHS09
[Signal word ]

Warning
[Hazard statements ]

H351-H410
[Precautionary statements ]

P202-P273-P280-P308+P313-P391-P405
[Hazard Codes ]

Xn,N
[Risk Statements ]

R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin .
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R38:Irritating to the skin.
R20:Harmful by inhalation.
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
[RIDADR ]

UN 3082 9/PG 3
[WGK Germany ]

2
[RTECS ]

UB1473000
[TSCA ]

TSCA listed
[REACH Registrations]

Active
[HazardClass ]

9
[PackingGroup ]

III
[HS Code ]

29199000
[Safety Profile]

Moderately toxic by ingestion. An experimental teratogen. Experimental reproductive effects. Questionable carcinogen with experimental carcinogenic data. Mutation data reported. When heated to decomposition it emits toxic fumes of Cland POx.
[Hazardous Substances Data]

13674-87-8(Hazardous Substances Data)
[Toxicity]

LD50 orally in rats: 1.85 g/kg (Piotrowski)
Hazard InformationBack Directory
[General Description]

Clear colorless viscous liquid. Generally a super-cooled liquid at room temperature but may occasionally solidify when held at low temperatures for prolonged periods.
[Reactivity Profile]

TRIS(1,3-DICHLORO-2-PROPYL)PHOSPHATE(13674-87-8) hydrolyzes slowly when refluxed with an aqueous acid. Under alkaline conditions, TRIS(1,3-DICHLORO-2-PROPYL)PHOSPHATE(13674-87-8) exhibits a slow cleavage. TRIS(1,3-DICHLORO-2-PROPYL)PHOSPHATE(13674-87-8) has plasticizing properties and, as such, may soften or deteriorate certain plastics and elastomers (particularly vinyl-based resin, neoprene and natural rubbers).
[Air & Water Reactions]

Insoluble in water.
[Fire Hazard]

This chemical is combustible.
[Chemical Properties]

Tris(1,3-dichloro-2-propyl)phosphate is a clear colorless viscous liquid with a relatively low molecular weight, low water solubility, and low lipophilicity (as indicated by log Kow).
[Uses]

Tris(1,3-dichloro-2-propyl) Phosphate is a flame retardant present in polyurethane foams.
[Uses]

Tris(1,3-dichloro-2-propyl)phosphate [TDCPP] is a halogenated phosphorus flame retardant used in a variety of sectors, including manufacturing of paints/coatings, furniture and related products, building/construction materials, fabrics/textiles/leather products, and foam seating and bedding products (EPA, 2012).
It is used extensively as an additive to flexible polyurethane foams (PUFs). Its end uses include molded automotive seating foam (e.g., seat cushions and headrests), slabstock foam in furniture, automotive fabric lining, and car roofing (ECHA, 2013). It is a high production volume chemical.
[Definition]

ChEBI: Tris(1,3-dichloropropan-2-yl) phosphate is a trialkyl phosphate.
[Environmental Fate]

A series of studies have been performed to evaluate the environmental fate and bioaccumulation potential of Tris(1,3-dichloro-2-propyl)phosphate (TDCPP).EU concluded that TDCPP is expected to be persistent in water, sediment, sewage sludge, and soil. When emitted to the environment, the EU concluded that TDCPP will likely adsorb to particulate matter, based on its low volatility and relatively high adsorption coefficient. The Henry’s law constant suggests that TDCPP will preferentially partition to water, rather than air. When assessing TDCPP's potential for persistence or bioaccumulation, the EU determined that TDCPP can potentially be persistent or very persistent and that it does not meet the criteria for bioaccumulative or very bioaccumulative compounds.
Material Safety Data Sheet(MSDS)Back Directory
[msds information]

Fyrol FR 2(13674-87-8).msds
Spectrum DetailBack Directory
[Spectrum Detail]

Tris(1,3-dichloro-2-propyl)phosphate(13674-87-8)MS
Tris(1,3-dichloro-2-propyl)phosphate(13674-87-8)1HNMR
Tris(1,3-dichloro-2-propyl)phosphate(13674-87-8)13CNMR
Tris(1,3-dichloro-2-propyl)phosphate(13674-87-8)IR1
Tris(1,3-dichloro-2-propyl)phosphate(13674-87-8)IR2
Tris(1,3-dichloro-2-propyl)phosphate(13674-87-8)Raman
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

13674-87-8(sigmaaldrich)
[TCI AMERICA]

Tris(1,3-dichloro-2-propyl) Phosphate,>95.0%(GC)(13674-87-8)
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