| Identification | More | [Name]
1,3-Dichloropropane | [CAS]
142-28-9 | [Synonyms]
1,3-DICHLOROPROPANE
AKOS BBS-00004406
PROPYLENE DICHLORIDE
TRIMETHYLENE CHLORIDE
TRIMETHYLENE DICHLORIDE
1,3-dichloro-propan
1,3-Dichlorpropan
1,3-dichlroropropane
1,3-Propylenechloride
CH2ClCH2CH2Cl
propane,1,3,-dichloro-
propane,1,3-dichloro
Propane,1,3-dichloro-
r270fa
1,3-DICHLOROPROPANE PESTANAL, 250 MG
1,3-DICHLOROPROPANE, 1X1ML, MEOH, 5000UG /ML
1,3-dichloropropane solution
propylendichloride
1,3-Dichloropropane (1mg/ml in Methanol) [for Water Analysis]
Dichloropropane, 1,3- | [EINECS(EC#)]
205-531-3 | [Molecular Formula]
C3H6Cl2 | [MDL Number]
MFCD00000999 | [Molecular Weight]
112.99 | [MOL File]
142-28-9.mol |
| Chemical Properties | Back Directory | [Appearance]
CLEAR COLOURLESS LIQUID | [Melting point ]
−99 °C(lit.)
| [Boiling point ]
120-122 °C(lit.)
| [density ]
1.19 g/mL at 25 °C(lit.)
| [vapor pressure ]
24-24.265hPa at 20-25℃ | [refractive index ]
n20/D 1.448(lit.)
| [Fp ]
90 °F
| [storage temp. ]
Refrigerator | [solubility ]
Chloroform (Slightly), Ethyl Acetate (Slightly) | [form ]
Liquid | [color ]
Clear colorless | [Water Solubility ]
0.8 g/L (20 ºC) | [BRN ]
505960 | [Henry's Law Constant]
1.0×10-2 mol/(m3Pa) at 25℃, Burkholder et al. (2019) | [Dielectric constant]
9.5099999999999998 | [InChI]
1S/C3H6Cl2/c4-2-1-3-5/h1-3H2 | [InChIKey]
YHRUOJUYPBUZOS-UHFFFAOYSA-N | [SMILES]
ClCCCCl | [LogP]
2 at 25℃ and pH7 | [CAS DataBase Reference]
142-28-9(CAS DataBase Reference) | [NIST Chemistry Reference]
Propane, 1,3-dichloro-(142-28-9) | [EPA Substance Registry System]
142-28-9(EPA Substance) |
| Safety Data | Back Directory | [Symbol(GHS) ]
 
GHS02,GHS07 | [Signal word ]
Warning | [Hazard statements ]
H226-H315-H319-H335 | [Precautionary statements ]
P210-P302+P352-P305+P351+P338 | [Hazard Codes ]
F,Xn,T | [Risk Statements ]
R11:Highly Flammable.
R20:Harmful by inhalation.
R20/22:Harmful by inhalation and if swallowed .
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment .
R36/37/38:Irritating to eyes, respiratory system and skin .
R39/23/24/25:Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed .
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed .
R36:Irritating to the eyes.
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed . | [Safety Statements ]
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S24:Avoid contact with skin .
S61:Avoid release to the environment. Refer to special instructions safety data sheet .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37:Wear suitable protective clothing and gloves .
S7:Keep container tightly closed . | [RIDADR ]
UN 1993 3/PG 2
| [WGK Germany ]
2
| [RTECS ]
TX9660000
| [TSCA ]
Yes | [REACH Registrations]
Active | [HazardClass ]
3 | [PackingGroup ]
II | [HS Code ]
29031990 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3 | [Safety Profile]
Moderately toxic by
ingestion. Mutation data reported. A very
dangerous fire hazard when exposed to heat
or flame. When heated to decomposition it
emits highly toxic fumes of Cl and
phosgene. See also CHLORINATED
HYDROCARBONS, ALIPHATIC; and
PROPYLENE DICHLORIDE. | [Hazardous Substances Data]
142-28-9(Hazardous Substances Data) | [Toxicity]
dog,LDLo,oral,3gm/kg (3000mg/kg),LIVER: OTHER CHANGESLUNGS, THORAX, OR RESPIRATION: CHRONIC PULMONARY EDEMABLOOD: HEMORRHAGE,American Journal of Hygiene. Vol. 16, Pg. 325, 1932. |
| Hazard Information | Back Directory | [General Description]
Colorless watery liquid with a sweet odor. Sinks in water. Produces irritating vapor. | [Reactivity Profile]
Halogenated aliphatic compounds, such as 1,3-DICHLOROPROPANE(142-28-9), are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. | [Air & Water Reactions]
Highly flammable. | [Health Hazard]
INHALATION: May cause some central nervous system depression. EYES: May cause some pain and irritation. SKIN: Mild irritation. | [Chemical Properties]
CLEAR COLOURLESS LIQUID | [Uses]
1,3-Dichloropropane is used as an intermediate in organic synthesis. It is also used as solvent, detergent and chromatographic analysis. Further, it is used to prepare 3,7-dithia-nonanedioic acid by reacting with mercaptoacetic acid. | [Definition]
ChEBI: 1,3-dichloropropane is a chloroalkane that is propane in which a hydrogen from each of the terminal methyl groups has been replaced by a chlorine. It has a role as an environmental contaminant and a nematicide. It is a chloroalkane and a chlorohydrocarbon. | [Preparation]
1,3-Dichloropropane is obtained by the action of propylene glycol with hydrochloric acid.
1,3-Dichloropropane synthesis: A process for the preparation of 1,3-dichloropropane by reacting bis(3-hydroxypropyl)ether with hydrogen chloride, optionally in the presence of tertiary basic nitrogen compounds or other tertiary aliphatic bases as catalysts, distilling off the 1,3-dichloropropane and the water of reaction and working up the two phases.
Process for the preparation of 1,3-dichloropropane | [Synthesis Reference(s)]
The Journal of Organic Chemistry, 29, p. 194, 1964 DOI: 10.1021/jo01024a045 |
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