| Identification | More | [Name]
Di-tert-butylchlorophosphane | [CAS]
13716-10-4 | [Synonyms]
AURORA KA-1319
Bis(1,1-dimethylethyl)-phosphinous chloride
DI-T-BUTYLCHLOROPHOSPHINE
DI-T-BUTYLPHOSPHINOUS CHLORIDE
DI-TERT-BUTYLCHLOROPHOSPHANE
DI-TERT-BUTYLCHLOROPHOSPHINE
DI-TERT-BUTYLPHOSPHORUS CHLORIDE
(tert-C4H9)2PCl
Chlorodi-tert-butylphosphine
Di-tert-Butylphosphinous chloride
Phosphinous chloride, di-tert-butyl-
DI-TERT-BUTYLCHLOROPHOSPHINE (DTBCP)
Di-t-butylchlorophosphine,min.98%
Phosphonous dichloride
Di-tert-B-butylchlorophosphine, 96%
Di-t-butylchlorophosphine, min. 98% | [Molecular Formula]
C8H18ClP | [MDL Number]
MFCD00008815 | [Molecular Weight]
180.66 | [MOL File]
13716-10-4.mol |
| Safety Data | Back Directory | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S25:Avoid contact with eyes . | [RIDADR ]
UN 3265 8/PG 2
| [WGK Germany ]
3
| [TSCA ]
No | [HazardClass ]
8 | [PackingGroup ]
II | [HS Code ]
29310099 |
| Hazard Information | Back Directory | [Chemical Properties]
Colorless to light yellow liqui | [Uses]
Di-tert-butylchlorophosphine is associated with palladium(II) acetate and used in Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. It serves as a ligand and used in the preparation of mono- and bidentate phosphine ligands in metal complexes for catalytic chiral asymmetric hydrogenations. Further, it is used in asymmetric and transition metal coupling reactions. In addition to this, it plays an important role in the preparation of other phosphines in catalytic polymerization reactions.? | [Application]
Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides. | [Precautions]
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and strong reducing agents. |
|
|