ChemicalBook--->CAS DataBase List--->137349-65-6

137349-65-6

137349-65-6 Structure

137349-65-6 Structure
IdentificationMore
[Name]

BIS(DICYCLOHEXYLPHOSPHINO)METHANE
[CAS]

137349-65-6
[Synonyms]

BIS(DICYCLOHEXYLPHOSPHINO)METHANE
METHYLENEBIS(DICYCLOHEXYLPHOSPHINE)
1,2-Bis(dicyclohexylphosphino)methane
Bis(dicyclohexylphosphino)methane,min.97%
Bis(dicyclohexylphosphino)methane, 97+%
Bis(dicyclohexylphosphino)methane, min. 97%
[Molecular Formula]

C25H46P2
[MDL Number]

MFCD00143763
[Molecular Weight]

408.58
[MOL File]

137349-65-6.mol
Chemical PropertiesBack Directory
[Melting point ]

95-102 °C (lit.)
[Boiling point ]

511.2±20.0 °C(Predicted)
[form ]

crystal
[color ]

white
[Sensitive ]

Air Sensitive
[BRN ]

5340912
[CAS DataBase Reference]

137349-65-6(CAS DataBase Reference)
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

R36/37/38:Irritating to eyes, respiratory system and skin .
[Safety Statements ]

S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
[RIDADR ]

UN1325
[WGK Germany ]

3
[F ]

10-23
[HazardClass ]

4.1
[PackingGroup ]

II
Hazard InformationBack Directory
[Uses]

Catalyst for:
  • Ru/phosphine catalyzed anti-Markovnikov addition reactions
  • Regioselective Suzuki coupling reactions
  • Ru/phosphine catalyzed homogeneous hydrogenation reactons
  • Mediated cross-coupling reactions
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
Well-known Reagent Company Product InformationBack Directory
[Alfa Aesar]

Bis(dicyclohexylphosphino)methane, 97+%(137349-65-6)
[Sigma Aldrich]

137349-65-6(sigmaaldrich)
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