| Identification | More | [Name]
(1R,2R)-(-)-1,2-Diaminocyclohexane | [CAS]
20439-47-8 | [Synonyms]
(1R,2R)-(-)-1,2-CYCLOHEXANEDIAMINE
(1R,2R)-(-)-1,2-DIAMINOCYCLOHEXANE
(1R,2R)-1,2-DIAMINOCYCLOHEXANE
(1R,2R)-CYCLOHEXANE-1,2-DIAMINE
(1R)-TRANS-1,2-CYCLOHEXANEDIAMINE
(1R)-(-)-TRANS-1,2-DIAMINOCYCLOHEXANE
(1R)-TRANS-1,2-DIAMINOCYCLOHEXANE
R-DACH
(-)-(R,R)-1,2-DIAMINOCYCLOHEXANE
(R,R)-(-)-1,2-DIAMINOCYCLOHEXANE
(R,R)-1,2-DIAMINOCYCLOHEXANE
RR-DAC
(-)-(R,R)-DACH
(R,R)-DACH
RR-DIAMINOCYCLOHEXANE
DiaminocyclohexaneRRDACHwhitepowder
(1R,2R)-(-)-1,2-Diaminocyclohe
(1R,2R)-(-)-1,2-Diaminocyclohexane,99%(R,R)-DACH
(1R,2R)-(-)-1,2-DIAMINOCYCLOHEXANE 99%
(1R,2R)-(-)-1,2-DIAMINOCYCLOHEXANE/(R,R)-DACH | [EINECS(EC#)]
606-556-6 | [Molecular Formula]
C6H14N2 | [MDL Number]
MFCD00062985 | [Molecular Weight]
114.19 | [MOL File]
20439-47-8.mol |
| Chemical Properties | Back Directory | [Appearance]
white to light yellow crystal powder | [Melting point ]
41-45 °C
| [alpha ]
-24.5 º (c=5 1 N HCl 20 º 26.5 ºC) | [Boiling point ]
86-88°C 23mm | [density ]
0.931 | [refractive index ]
-25.5 ° (C=5, 1mol/L HCl) | [Fp ]
169 °F
| [storage temp. ]
2-8°C
| [solubility ]
Aqueous Acid (Slightly), Chloroform (Sparingly), Methanol (Slightly) | [form ]
Crystalline Low Melting Solid | [pka]
10.76±0.70(Predicted) | [color ]
White to pale yellow | [Optical Rotation]
[α]20/D 25°, c = 5 in 1 M HCl | [Water Solubility ]
Soluble in water. | [Sensitive ]
Air Sensitive | [Detection Methods]
GC,HPLC | [BRN ]
4780911 | [Stability:]
Air Sensitive | [InChIKey]
SSJXIUAHEKJCMH-PHDIDXHHSA-N | [CAS DataBase Reference]
20439-47-8(CAS DataBase Reference) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3259 8/PG 2
| [WGK Germany ]
3
| [F ]
10-34 | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
29213000 |
| Raw materials And Preparation Products | Back Directory | [Raw materials]
Acetic acid-->Potassium hydroxide-->tert-Butyl methyl ether-->L(+)-Tartaric acid-->D-(-)-Tartaric Acid-->3-Methylbenzoyl chloride-->(+/-)-trans-1,2-Diaminocyclohexane-->2-Aminocyclohexanol-->cis-1,2-Diaminocyclohexane-->1,2-Diaminocyclohexane-->(1S,2S)-(+)-1,2-Diaminocyclohexane | [Preparation Products]
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl)-->Acetamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-chloro--->Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4,6-bis(1,1-dimethylethyl)--->2(1H)-Quinoxalinone,octahydro-,(4aR-trans)-(9CI)-->Phenol, 2,2'-[(1R,2R)-1,2-cyclohexanediylbis(nitrilomethylidyne)]bis[4-bromo--->1-(pyridin-2-yl)-N-[(1R,2R)-2-{[(pyridin-2-yl)methylidene]amino}cyclohexyl]methanimine |
| Hazard Information | Back Directory | [Chemical Properties]
white to light yellow crystal powder | [Uses]
(1R,2R)-(-)-1,2-Diaminocyclohexane can be used as a building block for chiral ligands.
| [Uses]
suzuki reaction | [Purification Methods]
Distil or recrystallise the diamine from pet ether under N2 or Ar. Store it as above. The 1R,2R-base L-tartrate salt has M 264.3, m 2 7 3o and [ ] D +12.5o (c 4, H2O), and can be used to purfy and/or optically enrich the free base. [Beilstein 13 III 6, and references below.] |
|
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