| Identification | More | [Name]
Bis(benzonitrile)palladium chloride | [CAS]
14220-64-5 | [Synonyms]
BIS(BENZONITRILE)DICHLOROPALLADIUM(II)
Bis(benzonitrile)palladium chloride
BIS(BENZONITRILE)PALLADIUM(II) CHLORIDE
BIS(BENZONITRILE)PALLADIUM(II) DICHLORIDE
DICHLOROBIS(BENZONITRILE)PALLADIUM(II)
PALLADIUM(II) CHLORIDE BIS(BENZONITRILE) COMPLEX
TRANS-BIS(BENZONITRILE)DICHLOROPALLADATE (II)
TRANS-BIS(BENZONITRILE)DICHLOROPALLADIUM(II)
TRANS-DICHLOROBIS-(BENZONITRILO)-PALLADIUM
TRANS-BIS-(BENZONITRILE)PALLADIUM(II) CHLORIDE
Bis(benzonitrile)palladium(II) chloride, 99+%
Dichlorobis(benzonitrile)palladium(II),99%
Palladium, bis(benzonitrile)dichloro-
Palladium(II)chloro-bis(benzonitrile)
trans-Bis(benzonitrile)dichloropalladium(II), Pd 27.7%
Trans-Bis(benzonitrile)dichloropalladium(II) Can be used to form catalysts in situ by separate addition of ligand
trans-Bis(benzonitrile)dichloropalladium(II), Pd | [EINECS(EC#)]
238-085-3 | [Molecular Formula]
C14H10Cl2N2Pd | [MDL Number]
MFCD00013123 | [Molecular Weight]
383.57 | [MOL File]
14220-64-5.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow powder | [Melting point ]
131 °C(lit.)
| [storage temp. ]
Inert atmosphere,2-8°C | [solubility ]
Soluble in acetone, chloroform | [form ]
Crystalline Powder | [color ]
Orange to brown | [Water Solubility ]
insoluble | [Hydrolytic Sensitivity]
4: no reaction with water under neutral conditions | [Detection Methods]
SPECTRA CHEMICAL ANALYSIS | [BRN ]
3981730 | [Exposure limits]
NIOSH: IDLH 25 mg/m3 | [InChI]
InChI=1S/2C7H5N.2ClH.Pd/c2*8-6-7-4-2-1-3-5-7;;;/h2*1-5H;2*1H;/q;;;;+2/p-2 | [InChIKey]
WXNOJTUTEXAZLD-UHFFFAOYSA-L | [SMILES]
C1(C#N)=CC=CC=C1.C1(C#N)=CC=CC=C1.[Pd](Cl)Cl | [CAS DataBase Reference]
14220-64-5(CAS DataBase Reference) | [Storage Precautions]
Store under nitrogen |
| Questions And Answer | Back Directory | [Reaction]
- Catalyst for the cyclization of δ-acetylenic carboxylic acids to butenolides.
- Catalyst for the aza-Michael reaction of carbamates with enones.
- Catalyst for the rearrangement of allylic imidates to allylic amides.
- Catalyst for the Nazarov cyclization of α-alkoxy dienones.
- Catalyst for the diamination of conjugated dienes.
- Three component Michael addition, cyclization, cross-coupling reaction.
- C-H activation of indoles.
|
| Hazard Information | Back Directory | [Chemical Properties]
yellow powder | [Uses]
Catalyst for greener amine synthesis from terminal olefins by Wacker oxidation followed by transfer hydrogenation of the resultant imine. | [Uses]
suzuki reaction | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here. | [reaction suitability]
core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst | [Synthesis]
Bis(cyanophenyl)dichloropalladium can be prepared by reacting palladium acetate or palladium chloride with benzonitrile.
A mixture of palladium(II) acetate (502 mg, 2.2 mmol), HCl (37% aqueous solution, 0.7 mL, 8.5 mmol), and benzonitrile (15 mL) was |
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