| Identification | More | [Name]
Tetrakis(triphenylphosphine)platinum | [CAS]
14221-02-4 | [Synonyms]
PLATINUM-TETRAKIS(TRIPHENYLPHOSPHINE)
TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM
TETRAKIS(TRIPHENYLPHOSPHINE)PLATINUM(0)
Platinum(0)tetrakis(triphenylphosphine)
Tetrakis(triphenylphosphine)platinum(0),98%
( beta-4)-platinu
Tetrakis-(triphenylphosphino)-platinum
Tetrakis(triphenylphosphine)platinum(0), Pt 15.2% min
Platinum, tetrakis(triphenylphosphine)-, (T-4)- | [EINECS(EC#)]
238-087-4 | [Molecular Formula]
C72H60P4Pt | [MDL Number]
MFCD00010014 | [Molecular Weight]
1244.22 | [MOL File]
14221-02-4.mol |
| Chemical Properties | Back Directory | [Appearance]
yellow powder | [Melting point ]
122 °C | [storage temp. ]
0-6°C | [solubility ]
Soluble in benzene | [form ]
Liquid | [color ]
Clear | [Water Solubility ]
INSOLUBLE | [Sensitive ]
Air Sensitive | [InChI]
1S/4C18H15P.Pt/c4*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;/h4*1-15H; | [InChIKey]
SYKXNRFLNZUGAJ-UHFFFAOYSA-N | [SMILES]
[Pt].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c4ccc(cc4)P(c5ccccc5)c6ccccc6.c7ccc(cc7)P(c8ccccc8)c9ccccc9.c%10ccc(cc%10)P(c%11ccccc%11)c%12ccccc%12 | [CAS DataBase Reference]
14221-02-4(CAS DataBase Reference) | [Storage Precautions]
Air sensitive;Light sensitive;Store under argon gas | [EPA Substance Registry System]
14221-02-4(EPA Substance) |
| Safety Data | Back Directory | [Safety Statements ]
S22:Do not breathe dust .
S24/25:Avoid contact with skin and eyes . | [WGK Germany ]
3
| [F ]
8-10-23 | [TSCA ]
Yes | [HS Code ]
29310099 | [Storage Class]
11 - Combustible Solids |
| Hazard Information | Back Directory | [Chemical Properties]
yellow powder | [Uses]
Tetrakis(triphenylphosphine)platinum(0), Pt is widely used in hydrosilation and oxidation. In Catalysts, Metal & Specialty Catalysts, Products & Industries. | [reaction suitability]
core: platinum
reagent type: catalyst | [Purification Methods]
It forms yellow crystals on adding hexane to a cold saturated solution in *C6H6. It is soluble in *C6H6 and CHCl3 but insoluble in EtOH and hexane. A less pure product is obtained if it is crystallised by adding hexane to a CHCl3 solution. It is stable in air for several hours and completely stable under N2. [Malatesta & Cariello J Am Chem Soc 2323 1958, Beilstein 16 IV 955.] |
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