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14353-88-9

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14353-88-9 Structure

14353-88-9 Structure
IdentificationMore
[Name]

[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE
[CAS]

14353-88-9
[Synonyms]

[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE
IODOPENTAFLUOROBENZENE BIS(TRIFLUOROACETATE)
PENTAFLUORO[BIS(TRIFLUOROACETOXY)IODO]BENZENE
[Bis(trifluoroacetoxy)]iodopentafluorobenzene 95%
[Bis(trifluoroacetoxy)]iodopentafluorobenzene95%
[EINECS(EC#)]

623-272-8
[Molecular Formula]

C10F11IO4
[MDL Number]

MFCD00191612
[Molecular Weight]

519.99
[MOL File]

14353-88-9.mol
Chemical PropertiesBack Directory
[Melting point ]

117-119 °C(lit.)
[solubility ]

soluble in Methanol
[form ]

powder to crystal
[color ]

White to Almost white
[CAS DataBase Reference]

14353-88-9(CAS DataBase Reference)
Safety DataBack Directory
[Symbol(GHS) ]

Corrosion (GHS05)
GHS05
[Signal word ]

Danger
[Hazard statements ]

H314
[Precautionary statements ]

P280-P305+P351+P338-P310-P260-P264-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P405-P501
[Hazard Codes ]

C,Xi
[Risk Statements ]

R34:Causes burns.
[Safety Statements ]

S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S27:Take off immediately all contaminated clothing .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
[RIDADR ]

UN 1759 8/PG 2
[WGK Germany ]

3
[Hazard Note ]

Irritant
[HazardClass ]

8
[PackingGroup ]

III
[HS Code ]

2931900090
Raw materials And Preparation ProductsBack Directory
[Raw materials]

Trifluoroacetic anhydride-->Iodopentafluorobenzene-->Trifluoroperacetic acid-->Benzene, 1,2,3,4,5-pentafluoro-6-iodosyl--->Tris(pentafluorophenyl)borane-->Trifluoroacetic acid
[Preparation Products]

Methyl trifluoroacetate-->Phenyl trifluoroacetate-->2,5-Dichlorobenzotrifluoride-->Isopropyl trifluoroacetate-->Benzotrifluoride
Hazard InformationBack Directory
[Uses]

Reactant or reagent for:
  • Oxidation of organic iodides using oxone and trifluoroacetic acid
  • Base hydrolysis
  • Oxidative cross-coupling of arenes
  • Oxidation of phenolic compounds with organohypervalent iodine
  • Aziridination of alkenes
  • Oxidation of organic compounds
  • Oxidative fragmentation of α-amino acids or β-amino alcohols
  • Oxidative biaryl coupling of thiophenes
[reaction suitability]

reagent type: oxidant
Spectrum DetailBack Directory
[Spectrum Detail]

[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE(14353-88-9)MS
[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE(14353-88-9)13CNMR
[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE(14353-88-9)IR1
[BIS(TRIFLUOROACETOXY)IODO]PENTAFLUOROBENZENE(14353-88-9)IR2
Well-known Reagent Company Product InformationBack Directory
[Sigma Aldrich]

14353-88-9(sigmaaldrich)
[TCI AMERICA]

[Bis(trifluoroacetoxy)iodo]pentafluorobenzene,>95.0%(T)(14353-88-9)
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