ChemicalBook--->CAS DataBase List--->1599466-87-1

1599466-87-1

1599466-87-1 Structure

1599466-87-1 Structure
IdentificationBack Directory
[Name]

SPhos Palladacycle Gen. 4
[CAS]

1599466-87-1
[Synonyms]

Methanesulfonato(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct
Methanesulfonato(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct min
Methanesulfonato(2-dicyclohexylphosphino-2',6'-dimethoxy-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II) dichloromethane adduct,[SPhos Palladacycle Gen. 4]
[Molecular Formula]

C40H50NO5PPdS
[MDL Number]

MFCD28411857
[MOL File]

1599466-87-1.mol
[Molecular Weight]

794.3
Chemical PropertiesBack Directory
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

Powder
[color ]

off-white to tan
[InChIKey]

BELRILURKPSACB-UHFFFAOYSA-N
[SMILES]

P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1OC)OC)[Pd+2]1(N(C2=CC=CC=C2C2=CC=CC=[C-]12)C)[O-]S(=O)(=O)C
Safety DataBack Directory
[Symbol(GHS) ]

GHS hazard pictograms
GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H315+H320
[WGK Germany ]

WGK 3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

Alternative Catalyst for the Suzuki-Miyaura Cross-Coupling reaction.
Reactions of 1599466-87-1
Hazard InformationBack Directory
[Uses]

SPhos Pd G4 is used as a versatile 4th generation palladium precatalyst developed by Buchwald group. 
[reaction suitability]

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

SPhos Palladacycle Gen. 4(1599466-87-1)1HNMR
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