ChemicalBook--->CAS DataBase List--->1142811-12-8

1142811-12-8

1142811-12-8 Structure

1142811-12-8 Structure
IdentificationBack Directory
[Name]

tBuXPhos Pd G1
[CAS]

1142811-12-8
[Synonyms]

tBuXPhos Pd G1
t-BuXPhos precatalyst
t-BuXPhos Palladacycle
Chloro[2-(di-tert-butylphosphi
t-BuXPhos palladium(II) phenethylamine chloride
Chloro(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II)
Chloro(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aMinoethyl)phenyl] palladiuM(II),98%
Chloro[2-(di-tert-butylphosphino)-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl)]palladium(II)
Chloro(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aminoethyl)phenyl] palladium(II), min. 98%
Chloro(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)[2-(2-aMinoethyl)phenyl] palladiuM(II), Min. 98% [t-BuXPhos Palladacycle]
[Molecular Formula]

C37H55ClNPPd
[MDL Number]

MFCD12911909
[MOL File]

1142811-12-8.mol
[Molecular Weight]

686.7
Questions And AnswerBack Directory
[Appearance]

White powder
[Reaction]

  1. Catalyst for cross-coupling reactions of electron-deficient anilines with aryl chlorides.
  2. Catalyst for rapid C-N bond-forming process at low catalyst loading.
  3. Catalyst for C-N cross-coupling reactions, at or below room temperature.
  4. Efficient Pd-catalyzed amination reactions for heterocycle functionization.
Reactions of 1142811-12-8
Chemical PropertiesBack Directory
[Melting point ]

150-159°C
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

Powder
[color ]

white
[InChIKey]

RUCUZUHGBIVUJI-UHFFFAOYSA-N
[SMILES]

P([Pd+2]1(NCCC2=CC=CC=[C-]12)[Cl-])(C1C=CC=CC=1C1C(=CC(C(C)C)=CC=1C(C)C)C(C)C)(C(C)(C)C)C(C)(C)C
[CAS DataBase Reference]

1142811-12-8
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Health Hazard (GHS08)
GHS07,GHS08
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335-H351
[Precautionary statements ]

P201-P302+P352-P305+P351+P338-P308+P313
[Hazard Codes ]

Xn
[Risk Statements ]

36/37/38-40
[Safety Statements ]

26-36/37
[WGK Germany ]

3
[HS Code ]

2843909000
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Carc. 2
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Catalyst for C-C bond and C-N bond formation.
[Application]

tBuXPhos Pd G1has been applied for the catalyst for C-C bond and C-N bond formation and Palladium Catalyzed Cross-Coupling Reactions.
[reaction suitability]

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst
reaction type: Cross Couplings
[storage]

Store in a cool. well ventilated area. Keep container tightly closed. Air sensitive. Storeunder Argon.
Spectrum DetailBack Directory
[Spectrum Detail]

tBuXPhos Pd G1(1142811-12-8)1HNMR
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