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14609-54-2

14609-54-2 Structure

14609-54-2 Structure
IdentificationBack Directory
[Name]

meso-Tetra(4-carboxyphenyl)porphine
[CAS]

14609-54-2
[Synonyms]

Mtcpp
Aids006254
Aids-006254
RARECHEM AS SA 0048
NICKEL IONOPHORE II
tetrakis(benzoic acid)
tetracarboxyphenylporphine
TETRACARBOXYPHENYLPORPHYRIN
Tetrakis(carboxphenyl)porphyrin
TETRAKIS(4-CARBOXYPHENYL)PORPHINE
Tetrakis(4-carboxyphenyl)porphyrin
MESO-TETRA(4-CARBOXYPHENYL)PORPHINE
4,4,4,4-(POrphine-5,10,15,20-tetrayl)
meso-tetrakis(4-carboxyphenyl)porphine
meso-Tetrakis(4-carboxyphenyl)porphyrin
meso-Tetra(4-carboxyphenyl)porphine,98%
In - tetrakis (4-carboxyphenyl) porphine
5,10,15,20-TETRA(4-CARBOXYPHENYL)PORPHYRIN
TCPP [=Tetrakis(4-carboxyphenyl)porphyrin]
(porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)
5,10,15,20-Tetrakis(4-carboxyphenyl)-21H,23H-porphine
5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-21,23H-PORPHYRIN
MESO-TETRAPHENYLPORPHINE-4,4',4'',4'''-TETRACARBOXYLIC ACID
4,4',4'',4'''-(PORPHINE-5,10,15,20-TETRAYL)TETRAKIS(BENZOIC ACID)
4,4',4'',4'''-(21H,23H-Porphyrin-5,10,15,20-tetryl)tetrakis(benzoic acid)
4,4',4'',4'''-(21H,23H-PORPHINE-5,10,15,20-TETRAYL)TETRAKIS(BENZOIC ACID)
4,4',4'',4'''-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid) Dye content 75 %
Meso-tetra(4-carboxyphenyl)porphine 4,4,4,4-(POrphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)
meso-Tetraphenylporphine-4,4μ,4,4μ-tetracarboxylic acid, 4,4μ,4μμ,4μμμ-(Porphine-5,10,15,20-tetrayl)tetrakis(benzoic acid)
TCPP [=Tetrakis(4-carboxyphenyl)porphine] [Ultra-high sensitive spectrophotometric reagent for Cu, Cd] [For the simultaneous determination of metals by HPLC]
MESO-TETRA(4-CARBOXYPHENYL)PORPHINE 98% ULTRA-HIGH SENSITIVE SPECTROPHOTOMETRIC REAGENT FOR CU CD AND USE FOR THE SIMULTANEOUS DETERMINATION OF METALS BY HPLC
TCPP [=Tetrakis(4-carboxyphenyl)porphyrin] [Ultra-high sensitive spectrophotometric reagent for Cu, Cd] [For the simultaneous determination of metals by HPLC]
[Molecular Formula]

C48H30N4O8
[MDL Number]

MFCD00064860
[MOL File]

14609-54-2.mol
[Molecular Weight]

790.77
Chemical PropertiesBack Directory
[Melting point ]

>300 °C
[density ]

1.462±0.06 g/cm3(Predicted)
[storage temp. ]

Keep in dark place,Sealed in dry,Room Temperature
[form ]

Powder
[color ]

purple
[Appearance]

Purple to Black Solid
[λmax]

411 nm
[InChIKey]

HHDUMDVQUCBCEY-LWQDQPMZSA-N
[SMILES]

C1(C2=CC=C(C=C2)C(O)=O)=C2N=C(C(C3=CC=C(C=C3)C(O)=O)=C3NC(=C(C4=CC=C(C=C4)C(O)=O)C4=NC(=C(C5=CC=C(C=C5)C(O)=O)C5NC1=CC=5)C=C4)C=C3)C=C2 |c:24,t:10,27,41|
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P280-P302+P352-P305+P351+P338
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[RTECS ]

DH6488300
[HS Code ]

2933998090
[Storage Class]

11 - Combustible Solids
[Hazardous Substances Data]

14609-54-2(Hazardous Substances Data)
Hazard InformationBack Directory
[Description]

5,10,15,20-(tetra-4-carboxyphenyl)porphyrin is a sensor for Ni2+.

[Uses]

meso-Tetra(4-carboxyphenyl)porphine can be used as organic synthesis intermediates and pharmaceutical intermediates, mainly used in laboratory research and development processes and chemical production processes.
[General Description]

Visit our Sensor Applications portal to learn more.
[Synthesis]

Synthesis_14609-54-2
General procedures for the synthesis of porphyrins 1-5A mixture of the appropriate aromatic aldehyde (0.72 mmol) andpyrrole (0.72 mmol) in DMF (15 mL) was placed into a 50 mL threeneckedflask. The mixture was flushed with nitrogen gas for a coupleof minutes and then heated to 100 C for 10 min. P-toluene sulphonicacid (0.72 mmol, dissolved in DMF) was then added to the reactionmixture. The colorless mixture turned red over the next couple of minutesthen heated at 150 C for 1 h. The reaction mixture was thencooled and poured over ice with stirring for 15 min the residue wascollected, dried under vacuum and purified by column chromatographyusing chloroform/hexane (1.5/1) as eluent).
Spectrum DetailBack Directory
[Spectrum Detail]

meso-Tetra(4-carboxyphenyl)porphine(14609-54-2)IR1
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