| Identification | More | [Name]
NITROSONIUM TETRAFLUOROBORATE | [CAS]
14635-75-7 | [Synonyms]
NITROSONIUM (NITROSYL) TETRAFLUOROBORATE
NITROSONIUM TETRAFLUOROBORATE
NITROSYL TETRAFLUOROBORATE
tetrafluoro-borate(1-nitrosyl
nitrosium tetrafluoroborate
Nitrosonium fluoroborate
Nitrosoniumtetrafluoroborate,min.97%
Borate(1-), tetrafluoro-, nitrosyl
Nitrosonium tetrafluoroborate 98%
Nitrosoniumtetrafluoroborate98%
Nitrosonium tetrafluoroborate, min. 97% | [EINECS(EC#)]
238-679-2 | [Molecular Formula]
BF4NO | [MDL Number]
MFCD00011433 | [Molecular Weight]
116.81 | [MOL File]
14635-75-7.mol |
| Chemical Properties | Back Directory | [Appearance]
white crystals or crystalline powder | [Melting point ]
250 °C | [Boiling point ]
250°C 0,01mm | [density ]
2.185 | [Fp ]
250°C/0.01mm subl. | [storage temp. ]
2-8°C
| [solubility ]
Soluble in acetonitrile. | [form ]
Crystals or Crystalline Powder | [color ]
White | [Specific Gravity]
2.185 | [Sensitive ]
Hygroscopic | [Merck ]
14,6649 | [Stability:]
Hygroscopic, Moisture Sensitive | [InChI]
InChI=1S/BF4.H2NO/c2-1(3,4)5;1-2/h;1H2/q-1;+1 | [InChIKey]
CYLOZTYJBXHMJA-UHFFFAOYSA-N | [SMILES]
[NH2+]=O.[B+3]([F-])([F-])([F-])[F-] | [CAS DataBase Reference]
14635-75-7(CAS DataBase Reference) | [EPA Substance Registry System]
Borate(1-), tetrafluoro-, nitrosyl (14635-75-7) |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS05 | [Signal word ]
Danger | [Hazard statements ]
H314 | [Precautionary statements ]
P260-P280-P301+P330+P331-P303+P361+P353-P304+P340+P310-P305+P351+P338 | [Hazard Codes ]
C | [Risk Statements ]
R34:Causes burns. | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3260 8/PG 2
| [WGK Germany ]
3
| [F ]
1-10 | [Hazard Note ]
Corrosive/Hygroscopic (In Teflon Bottle ) | [TSCA ]
T | [HazardClass ]
6.1 | [PackingGroup ]
III | [HS Code ]
28402000 | [Storage Class]
8A - Combustible corrosive hazardous materials | [Hazard Classifications]
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
white crystals or crystalline powder | [Uses]
Nitrosyl tetrafluoroborate is an efficient nitrosating and diazotizing agent. It reacts with alcohols and secondary amines to yield alkyl nitrites and nitrosamines, respectively. It reacts with primary amines to yield diazonium tetrafluoroborates. NOBF4 is also a mild oxidant and commonly used for single electron transfer oxidation. | [Uses]
In the preparation of diazonium fluoborates. | [Uses]
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate. | [reaction suitability]
reagent type: oxidant |
|
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