| Identification | Back Directory | [Name]
TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE | [CAS]
113978-91-9 | [Synonyms]
[n-Bu3PH]BF4
tributylphosphine tetrafluoroborate
Tributylphosphonium tetrafluoroborate
Tributylphosphine tetrafluoroborate 97%
Tributylphosphine tetrafluoroborate,97%
TRI-N-BUTYLPHOSPHONIUM TETRAFLUOROBORATE
TRI-N-BUTYLPHOSPHINE TETRAFLUOROBORATE,&
Tri-n-butylphosphoniumtetrafluoroborate,99% | [Molecular Formula]
C12H28BF4P | [MDL Number]
MFCD05664257 | [MOL File]
113978-91-9.mol | [Molecular Weight]
290.13 |
| Chemical Properties | Back Directory | [Melting point ]
50-53 °C(lit.)
| [Fp ]
>221 °F
| [storage temp. ]
Inert atmosphere,Room Temperature | [form ]
Powder | [color ]
white | [InChI]
InChI=1S/C12H27P.BF4/c1-4-7-10-13(11-8-5-2)12-9-6-3;2-1(3,4)5/h4-12H2,1-3H3;/q;-1/p+1 | [InChIKey]
NCHAZLRRIGGCER-UHFFFAOYSA-O | [SMILES]
[B-](F)(F)(F)F.[PH+](CCCC)(CCCC)CCCC |
| Questions And Answer | Back Directory | [Reaction]
- Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes.
- Catalyst in Baylis-Hillman reactions.
- Azide reductions.
- Acylation of alcohols by anhydrides.
- Ligand for formate reduction of allyl carbonates.
- Synthesis of aromatic nitriles via Pd C-H functionalization.
|
| Hazard Information | Back Directory | [General Description]
May contain approximately 5% of other butyl isomers. | [reaction suitability]
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling |
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