| Identification | Back Directory | [Name]
SEC-BUTYLMAGNESIUM CHLORIDE | [CAS]
15366-08-2 | [Synonyms]
25wt%solutioninTHF sec-Butylchloromagnesium 2-Butylmagnesium chloride sec-Butylmagnesiumchlorid SEC-BUTYLMAGNESIUM CHLORIDE chloro(1-methylpropyl)-magnesiu Chloro(1-methylpropyl)magnesium Magnesium, chloro(1-methylpropyl)- sec-butylmagnesium chloride solution 2-Butylmagnesium chloride, 1.0 M in THF 2-Butylmagnesium chloride, 1.0 M in 2-MeTHF s-Butylmagnesium chloride 2M solution in THF s-Butylmagnesium chloride 2M solution in DEE SEC-BUTYLMAGNESIUM CHLORIDE 25 WT% SOLUTION IN THF sec-Butylmagnesium chloride solution 2.0 in diethyl ether sec-Butylmagnesium chloride25 wt% solution in THFAcroSeal§3 SEC-BUTYLMAGNESIUM CHLORIDE SOLUTION, ~2 M IN DIETHYL ETH. sec-ButylMagnesiuM chloride, 2.0 M solution in THF, SpcSeal sec-Butylmagnesium chloride solution 2.0 M in diethyl ether SEC-BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUTI ON IN DIETHYL ETHER sec-Butylmagnesium chloride, 25 wt% solution in THF, AcroSeal sec-ButylMagnesiuM chloride, lithiuM chloride coMplex 1.2M (15wt% 1wt%) in tetrahydrofuran | [EINECS(EC#)]
239-403-3 | [Molecular Formula]
C4H9ClMg | [MDL Number]
MFCD00000467 | [MOL File]
15366-08-2.mol | [Molecular Weight]
116.87 |
| Chemical Properties | Back Directory | [Appearance]
Light to dark-brown solution | [Boiling point ]
66 °C
| [density ]
0.83 g/mL at 20 °C
| [Fp ]
-21 °C
| [storage temp. ]
Flammables + water-Freezer (-20°C)e area | [form ]
liquid | [color ]
dark brown | [Sensitive ]
air sensitive, moisture sensitive | [BRN ]
3600265 | [InChI]
1S/C4H9.ClH.Mg/c1-3-4-2;;/h3H,4H2,1-2H3;1H;/q;;+1/p-1 | [InChIKey]
MJHZUYZQMNONPK-UHFFFAOYSA-M | [SMILES]
CCC(C)[Mg]Cl | [EPA Substance Registry System]
Magnesium, chloro(1-methylpropyl)- (15366-08-2) |
| Hazard Information | Back Directory | [Chemical Properties]
Light to dark-brown solution | [Uses]
sec-Butylmagnesium chloride solution is a Grignard reagent, it can be used in:
- Metal catalyzed cross-coupling reactions with non-activated aryl chlorides.
- The synthesis of various alkoxytrichlorosilanes by reacting with tetrachlorosilane and alcohols.
| [reaction suitability]
reaction type: Grignard Reaction |
| Safety Data | Back Directory | [Hazard Codes ]
F+,C,F | [Risk Statements ]
12-14/15-22-34-66-67-19-11 | [Safety Statements ]
16-26-36/37/39-43-45-7/8 | [RIDADR ]
UN 3399 4.3/PG 1
| [WGK Germany ]
1
| [F ]
1-3-10 | [TSCA ]
TSCA listed | [REACH Registrations]
Active | [HS Code ]
29319090 | [Storage Class]
4.3 - Hazardous materials which set free flammable gases upon contact with water | [Hazard Classifications]
Acute Tox. 4 Oral Eye Dam. 1 Flam. Liq. 2 Skin Corr. 1B STOT SE 3 Water-react 1 |
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