| Identification | More | [Name]
Magnesium nitrate hexahydrate | [CAS]
13446-18-9 | [Synonyms]
AQUANAL-PLUS MAGNESIUM
AQUANAL(R)-PLUS MAGNESIUM
ASHING ACID
MAGNESIUM
MAGNESIUM AA/ICP CALIBRATION/CHECK STANDARD
MAGNESIUM AA SINGLE ELEMENT STANDARD
MAGNESIUM, AAS STANDARD SOLUTION
MAGNESIUM AA STANDARD
MAGNESIUM ATOMIC ABSORPTION SINGLE ELEMENT STANDARD
MAGNESIUM ATOMIC ABSORPTION STANDARD
MAGNESIUM ATOMIC ABSORPTION STANDARD SOLUTION
MAGNESIUM ATOMIC SPECTROSCOPY STANDARD
MAGNESIUM CHLORIDE
MAGNESIUM ICP/DCP STANDARD
MAGNESIUM ICP STANDARD
MAGNESIUM ICP TORCH OPTIMIZATION STANDARD
MAGNESIUM IC STANDARD
MAGNESIUM MATRIX MODIFIER
MAGNESIUM METAL
MAGNESIUM METALLO-ORGANIC STANDARD | [EINECS(EC#)]
231-104-6 | [Molecular Formula]
H12MgN2O12 | [MDL Number]
MFCD00085308 | [Molecular Weight]
256.41 | [MOL File]
13446-18-9.mol |
| Chemical Properties | Back Directory | [Appearance]
White colourless crystal | [Melting point ]
89 °C | [Boiling point ]
330 °C | [density ]
1.63 | [vapor density ]
6 (vs air)
| [vapor pressure ]
1 mm Hg ( 621 °C)
| [Fp ]
−26 °F
| [storage temp. ]
2-8°C | [solubility ]
H2O: 1 M at 20 °C, clear, colorless
| [form ]
turnings
| [color ]
White | [Specific Gravity]
1.64 | [PH]
5.0-8.2 (25℃, 50mg/mL in H2O) | [Stability:]
Stable. Strong oxidizer-contact with organic material may lead to fire. Do not store near combustible materials. Incompatible with combustible materials, organics, strong reducing agents. | [Water Solubility ]
420 g/L (20 ºC) | [Sensitive ]
Hygroscopic | [Merck ]
14,5674 | [BRN ]
4948473 | [CAS DataBase Reference]
13446-18-9(CAS DataBase Reference) | [EPA Substance Registry System]
Magnesium (II) nitrate, hexahydrate (13446-18-9) |
| Safety Data | Back Directory | [Hazard Codes ]
C,Xi,O | [Risk Statements ]
R34:Causes burns.
R8:Contact with combustible material may cause fire.
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S7/8:Keep container tightly closed and dry .
S37/39:Wear suitable gloves and eye/face protection .
S36:Wear suitable protective clothing .
S17:Keep away from combustible material .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S23:Do not breathe gas/fumes/vapor/spray (appropriate wording to be specified by the manufacturer) . | [RIDADR ]
UN 2056 3/PG 2
| [WGK Germany ]
-
| [RTECS ]
OM3756000
| [F ]
3-9 | [TSCA ]
Yes | [HazardClass ]
8 | [PackingGroup ]
III | [HS Code ]
28342980 | [Toxicity]
LD50 orally in Rabbit: 5440 mg/kg |
| Hazard Information | Back Directory | [Hazard]
Low toxicity by ingestion. A mild skin and
eye irritant. | [Chemical Properties]
White colourless crystal | [General Description]
Magnesium nitrate hexahydrate is a hydrated magnesium salt. A mixture of magnesium nitrate hexahydrate and magnesium chloride hexahydrate has been reported as a potential phase change material (PCM) for the storage of latent thermal energy. It has been employed as a base material in this mixture to evaluate the storage and effective utilization of urban waste heat from emerged co-generation systems. Its crystals belong to the monoclinic crystal system. | [Purification Methods]
Crystallise the nitrate from water (2.5mL/g) by partial evaporation in a desiccator. It is deliquescent and is soluble in EtOH. After two recrystallisations, ACS grade salt has: metal (ppm) Ca (6.2), Fe (8.4), K (2), Mo (0.6), Na (0.8), Se (0.02). |
| Questions And Answer | Back Directory | [Uses]
Sodium bisulfate is used for pickling metals; bleaching leather; carbonizing
wool; in carbonic acid baths, and manufacturing magnesia cements. | [Production Methods]
Sodium bisulfate is a by-product of sodium sulfate manufacture. One process involves reacting sulfuric acid with sodium nitrate at high temperature to form nitric acid and sodium bisulfate:
NaNO3 + H2SO4 → NaHSO4 + HNO3 (g)
In the above reaction, nitric acid is obtained as vapor. It is purged from the system and collected in water to obtain nitric acid solution of desired concentration. Sodium bisulfate is separated by fractional crystallization.
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