| Identification | More | [Name]
TERT-BUTYLMAGNESIUM CHLORIDE | [CAS]
677-22-5 | [Synonyms]
T-BUTYLMAGNESIUM CHLORIDE
TERT-BUTYLMAGNESIUM CHLORIDE
TERT-BUTYLMAGNESIUM CHLORIDE 2.0M &
TERT-BUTYLMAGNESIUM CHLORIDE, 1.0M SOLUT ION IN TETRAHYDROFURAN
TERT-BUTYLMAGNESIUM CHLORIDE, 2.0M SOLUT ION IN DIETHYL ETHER
TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION, ~1 M IN THF
TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION,~2 M IN DIETHYL ETH.
TERT-BUTYLMAGNESIUM CHLORIDE SOLUTION,~20% IN THF
t-Butylmagnesium Chloride 1.0 M In Butyl Diglyme
t-Butylmagnesium Chloride 1.0 M In Tetrahydrofuran
solution~1MinTHF
tert-Butylmagnesium chloride, 1,7M solution in diethyl ether
tert-Butylmagnesium chloride, 1.7M solution in THF
tert-BUTYL MAGNESIUM CHLORIDE, 1 M in TETRAHYDROFURAN
Magnesium, chloro(1,1-dimethylethyl)-
tert-butylmagnesium chloride solution
TERT-BUTYLMAGNESIUM CHLORIDE: (26% IN ETHYL ETHER, CA. 2MOL/L)
TERT-BUTYLMAGNESIUM CHLORIDE: (26% IN TETRAHYDROFURAN, CA. 2MOL/L
tert-Butylmagnesium Chloride (23% in Tetrahydrofuran, ca. 2mol/L)
tert-Butylmagnesium chloride1.7M solution in THFAcroSeal§3 | [EINECS(EC#)]
211-638-6 | [Molecular Formula]
C4H9ClMg | [MDL Number]
MFCD00000465 | [Molecular Weight]
116.87 | [MOL File]
677-22-5.mol |
| Chemical Properties | Back Directory | [Appearance]
clear faint grey to grey, grey-brown or light | [Melting point ]
-108℃ (Tetrahydrofuran) | [density ]
0.931 g/mL at 25 °C
| [Fp ]
34 °F
| [storage temp. ]
2-8°C
| [form ]
Liquid | [color ]
Clear brown to dark brown | [Water Solubility ]
Miscible with alcohol and water. | [Sensitive ]
Air & Moisture Sensitive | [Detection Methods]
TITR | [BRN ]
3535403 | [InChI]
InChI=1S/C4H9.ClH.Mg/c1-4(2)3;;/h1-3H3;1H;/q;;+1/p-1 | [InChIKey]
ZDRJSYVHDMFHSC-UHFFFAOYSA-M | [SMILES]
C(C)(C)(C)[Mg]Cl | [CAS DataBase Reference]
677-22-5(CAS DataBase Reference) | [Storage Precautions]
Store under nitrogen |
| Safety Data | Back Directory | [Symbol(GHS) ]
   
GHS02,GHS05,GHS07,GHS08 | [Signal word ]
Danger | [Hazard statements ]
H333-H225-H250-H260-H302-H314-H336-H335-H351-H224-H361-H371-H372-H261-H318 | [Precautionary statements ]
P210-P231+P232-P280-P305+P351+P338-P370+P378-P422-P201-P202-P223-P233-P240-P241+P242+P243-P260-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P308+P313-P335+P334-P308+P311-P402+P404-P303+P361+P353-P405-P501a | [Hazard Codes ]
F+,C,F | [Risk Statements ]
R12:Extremely Flammable.
R14/15:Reacts violently with water, liberating extremely flammable gases .
R19:May form explosive peroxides.
R22:Harmful if swallowed.
R34:Causes burns.
R66:Repeated exposure may cause skin dryness or cracking.
R67:Vapors may cause drowsiness and dizziness.
R15:Contact with water liberates extremely flammable gases.
R11:Highly Flammable.
R14:Reacts violently with water. | [Safety Statements ]
S9:Keep container in a well-ventilated place .
S16:Keep away from sources of ignition-No smoking .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S29:Do not empty into drains .
S33:Take precautionary measures against static discharges .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S43:In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add-Never use water) .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) . | [RIDADR ]
UN 3399 4.3/PG 1
| [WGK Germany ]
1
| [F ]
1-3-10 | [REACH Registrations]
Active | [HazardClass ]
4.3 | [PackingGroup ]
I | [HS Code ]
29319090 | [Storage Class]
4.2 - Pyrophoric and self-heating hazardous materials | [Hazard Classifications]
Acute Tox. 4 Oral
Carc. 2
Eye Dam. 1
Flam. Liq. 2
Pyr. Liq. 1
Skin Corr. 1B
STOT SE 3
Water-react 1 |
| Hazard Information | Back Directory | [Chemical Properties]
clear faint grey to grey, grey-brown or light | [Uses]
tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides. | [General Description]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product, 1.0 M in 2-methyltetrahydrofuran aligns with "Safer Solvents and Auxiliaries", "Use of Renewable Feedstocks" and "Inherently Safer Chemistry for Accident Prevention". Find details here. | [reaction suitability]
reaction type: Grignard Reaction | [Synthesis]
Preparation of tert-butyl magnesium chloride: remove the oxide film on the surface of the magnesium bar with sandpaper and cut into fine chips. Weigh 3.6 g (0.15 mol) of magnesium chips, added to a four-necked flask equipped with a nitrogen protection dev |
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| Company Name: |
J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Jia Xing Isenchem Co.,Ltd
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| Telephone: |
0573-85285100 18627885956 |
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https://www.chemicalbook.com/ShowSupplierProductsList14265/0_EN.htm |
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