| Identification | More | [Name]
cis-Dichlorobis(diethylsulfide)platinum(II) | [CAS]
15442-57-6 | [Synonyms]
CIS-BIS(DIETHYL SULFIDE)PLATINUM(II) CHLORIDE
CIS-DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II)
DICHLOROBIS(DIETHYLSULPHIDE)PLATINATE (II)
TRANS-DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II)
cis-Dichlorobis(diethylsulfide)platinum(II),Pt43.7%
cis-Dichlorobis(diethylsulfide)platinum(II),99%
DICHLOROBIS(DIETHYLSULFIDE)PLATINUM(II)
cis-Dichlorobis-(diethyl sulfide)-platinum | [EINECS(EC#)]
239-454-1 | [Molecular Formula]
C8H20Cl2PtS2 | [MDL Number]
MFCD00050943 | [Molecular Weight]
446.36 | [MOL File]
15442-57-6.mol |
| Chemical Properties | Back Directory | [Appearance]
Yellow-green powder | [Melting point ]
105 °C(lit.) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Soluble in acetone, alcohol and benzene | [form ]
Powder | [color ]
yellow | [Water Solubility ]
slightly soluble | [Exposure limits]
ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3 | [InChI]
InChI=1S/2C4H10S.2ClH.Pt/c2*1-3-5-4-2;;;/h2*3-4H2,1-2H3;2*1H; | [InChIKey]
UHBPKZLROHZYIJ-UHFFFAOYSA-N | [SMILES]
[Pt+2]([Cl-])([Cl-])(S(CC)CC)S(CC)CC | [CAS DataBase Reference]
15442-57-6(CAS DataBase Reference) |
| Questions And Answer | Back Directory | [Uses]
Cis-dichlorodi(diethyl sulfide)platinum(II) is a platinum homogeneous catalyst. Hydrosilylation is an important reaction that produces various organosilicon compounds, and platinum homogeneous catalysts are the most common catalysts for this type of reaction. |
| Safety Data | Back Directory | [Symbol(GHS) ]
GHS07 | [Signal word ]
Warning | [Hazard statements ]
H315-H319-H335 | [Precautionary statements ]
P261-P264-P271-P280-P302+P352-P305+P351+P338 | [Hazard Codes ]
Xi | [Risk Statements ]
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36:Wear suitable protective clothing .
S37/39:Wear suitable gloves and eye/face protection . | [WGK Germany ]
3
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| Hazard Information | Back Directory | [Description]
Cis-Dichlorobis(diethylsulfide)platinum(II) is a chemical reagent that can prepare other platinum compounds. It is a colorless solid with a melting point of 173°C. cis-Dichlorobis(diethylsulfide)platinum(II) has been used in the synthesis of benzenesulfonyl chloride and benzene, which are essential intermediates for the production of pharmaceuticals such as carbapenems and fluoroquinolones. cis-Dichlorobis(diethylsulfide)platinum(II) also has an isomerization reaction with lithium, ether, or sulfide to yield cis-Dichlorobis(ethylsulfide)platinum (II).
| [Chemical Properties]
Yellow-green powder | [reaction suitability]
core: platinum
reagent type: catalyst |
|
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J & K SCIENTIFIC LTD.
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Energy Chemical
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Sigma-Aldrich
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